اندازه گیری مس و روی در کیوی به روش میکرواستخراج امولسیون سازی با کمک امواج مافوق صوت
محورهای موضوعی : میکروبیولوژی مواد غذایی
لیلا حاجی آقابابائی
1
,
شهره معماری
2
,
سعید سوزنگرزاده
3
,
سیده اعظم عقیلی
4
1 - دانشیار شیمی تجزیه، گروه شیمی، واحد یادگار امام خمینی (ره) شهر ری، دانشگاه آزاد اسلامی، تهران، ایران
باشگاه پژوهشگران جوان و نخبگان، دانشگاه آزاد اسلامی واحد یادگار امام خمینی (ره) شهر ری، تهران، ایران
2 - کارشناس ارشد شیمی تجزیه، گروه شیمی، واحد یادگار امام خمینی (ره) شهر ری، دانشگاه آزاد اسلامی، تهران، ایران
3 - استادیار شیمی آلی، گروه شیمی، واحد یادگار امام خمینی (ره) شهر ری، دانشگاه آزاد اسلامی، تهران، ایران
4 - کارشناس ارشد شیمی تجزیه، گروه شیمی، واحد یادگار امام خمینی (ره) شهر ری، دانشگاه آزاد اسلامی، تهران، ایران
کلید واژه: امولسیون سازی با امواج مافوق ص, روی, کیوی, مس 3- ((6- متیل-5- اکسو-3- تیو, 2- دی هیدرو- 1, 2, 4 - تری آزین-4 (3اچ) - ایل) ای,
چکیده مقاله :
مقدمه: میکرواستخراج امولسیون سازی باکمک امواج مافوق صوت دنبال شده با طیف سنجی جذب اتمی کوره گرافیتی، جهت اندازه گیری کاتیون هایCu2+ و Zn2+ گزارش شده است. مواد و روش ها: جهت میکرواستخراج امولسیون سازی باکمک امواج مافوق صوت، محلول نمونه در ظروف سانتریفوژ با انتهای مخروطی ریخته شد و مقدار مشخصی از محلول لیگاند و حلال استخراجی با استفاده ازیک سرنگ در حمام اولتراسونیک تزریق شد. جداسازی دو فاز با سانتریفوژ انجام شد و فاز آلی ته نشین شده، جهت اندازه گیری یون های مس و روی، مستقیما به طیف سنج جذب اتمی کوره گرافیتی منتقل گردید. یافته‌ها: 3- ((6- متیل-5- اکسو-3- تیوکسو-5،2- دی هیدرو- 1، 2، 4 - تری آزین-4 (3اچ) - ایل) ایمینو) ایندولین -2-اونبه عنوان یک معرف کمپلکس دهنده جدید و گزینش پذیر معرفی شد. پارامترهای مختلف موثر بر کارایی استخراج از جمله نوع و حجم حلال استخراج کننده، حجم معرف کیلیت دهنده، pH نمونه، زمان استخراج بهینه سازی شدند. کلروفرم بعنوان حلال استخراجی بهترین نتیجه را نشان داد. تحت شرایط بهینه، منحنی های کالیبراسیون در محدوده μg L-1 5/1 - 05/0 از یون ها خطی بودند. انحراف استاندارد نسبی برای چهار اندازه گیری محلول نمونه μg L-1 1/0 Cu2+ و Zn2+ به ترتیب 9/2 و 5/3 بود. حد تشخیص روش μg L-1 043/0 برای مس و μg L-1 045/0 برای روی بود. اثر حضور سایر یون ها بررسی شد. نتیجه‌گیری: نتایج یک روش موفق برای اندازه گیری کمی وگزینشی مقادیر جزئی یون هایCu2+ و Zn2+ در نمونه آبی و غذایی را تایید کردند.
Introduction: Ultrasound assisted emulsification microextraction is one of the sample preparation techniques which have minimal exposure to organic solvent. In this study, the applicability of ultrasound assisted emulsification microextraction was explored as a simple and fast method for the preconcentration and determination of Cu2+ and Zn2+ ions. Materials and Methods: One aliquot of sample solution was poured in a screw cap glass tube with a conical bottom. Then, the chelating agent and extraction solvent were injected into the sample solution using a syringe in the ultrasonic bath. Disruption of the emulsion was carried out by centrifugation, and the sedimented organic phase was transferred directly to the graphite furnace atomic absorption spectrometry for determination of Cu2+ and Zn2+ ions. Results: 3-((6-methyl-5-oxo-3-thioxo-2,5-dihydro-1,2,4-triazin-4(3H)-yl)imino) indolin-2-one was introduced as a new and selective chelating agent. Parameters that affect the extraction efficiency, such as the kind and volume of the extraction solvent, volume of chelating agent, sample pH, extraction time are optimized. Chloroform as extraction solvent give the best results. Under the optimum conditions, the calibration curves were linear in the range of 0.05-1.5 μg L-1 ions. Relative standard deviations were 2.9 and 3.5 for five analysis of sample solution containing 0.1 mg L−1 Cu2+ and Zn2+, respectively. The detection limit of method was 0.043 for Cu2+ and 0.045 μg L-1 for Zn2+. The effect of presence of other ions was investigated. Conclusion: The results demonstrate a successful method for quantitative and selective determination of trace amount of Cu2+ and Zn2+ ions in water and food samples.
Arab, R., Hajiaghababaei, L., Badiei, A., Karimi, M., Ganjali, M. R. & Mohammadi Ziarani, G. (2019). 8-Hydroxyquinoline grafted nanoporous SBA-15 as a novel solid phase extractor for preconcentration of trace amount of Copper. International Journal of Nano Dimension, 10, 340-349.
Blanco, A. & Blanco, G. (2017). Essential minerals, In medical biochemistry, Academic Press, Elsevier, Chapter 29. pp. 715-743.
Ebrahimi-Najafabadi, H., Pasdaran, A., Rezaei Bezenjani, R. & Bozorgzadeh, E. (2019). Determination of toxic heavy metals in rice samples using ultrasound assisted emulsification microextraction combined with
inductively coupled plasma optical emission spectroscopy. Food Chemistry, 289, 26-32.
Elkins, H.B. (1959). The Chemistry of Industrial Toxicology, Wiley, New York, 2nd, Ed.
Ghasemi, E. & Kaykhaii, M. (2017). Determination of zinc, copper, and mercury in water samples by using novel micro cloud point extraction and UV-Vis spectrophotometry. Eurasian Journal of Analytical Chemistry, 12(4), 313-324. DOI:10.12973/ejac.2017.00172a
Grochowski, C., Blicharska, E., Krukow, P., Jonak, K., Maciejewski, M., Szczepanek, D., Jonak, K., Flieger, J. & Maciejewski, R. (2019). Analysis of trace elements in human brain: Its aim, methods, and concentration levels. Frontiers in Chemistry, 7, 115. DOI: 10.3389/fchem.2019.00115
Hamida, S., Ouabdesslam, L., Ladjel, A. F., Escudero, M. & Anzano, J. (2018). Determination of cadmium, copper, lead, and zinc in pilchard sardines from the bay of boumerdés by atomic absorption spectrometry. Analytical Letters, 51(16), 2501-2508. DOI:10.1080/00032719.2018.1434537
Hajiaghababaei, L., Badiei, A., Shojaan, M., Ganjali, M. R., Khaniani, Y., Mohammadi Ziarani, G. & Zarabadi-Poor, P. (2012). A novel method for the simple and simultaneous preconcentration of Pb2+, Cu2+ and Zn2+ ions with aid of diethylenetriamine functionalized SBA-15 nanoporous silica compound. International Journal of Environmental Analytical Chemistry, 92(12), 1352-1364.
Hajiaghababaei, L., Tajmiri, T., Badiei, A., Ganjali, M.R., Khaniani, Y. & Mohammadi Ziarani, G. (2013). Heavy metals determination in water and food samples after preconcentration by a new nanoporous adsorbent. Food Chemistry, 141, 1916-1922.
Hajiaghababaei, L., Zandinejad, S., Berijani, S. & Suzangarzadeh, S. (2016). Ultrasound assisted emulsification microextraction for selective determination of trace amount of mercury (II). Indian Journal of Chemistry, 55A, 423-428.
Jeffery, J., Frank, A. R., Hockridge, S., Stosnach, H. & Costelloe, S. J. (2019). Method for measurement of serum copper, zinc and selenium using total reflection X-ray fluorescence spectroscopy on the PICOFOX analyser: Validation and comparison with atomic absorption spectroscopy and inductively coupled plasma mass spectrometry.Annals of Clinical Biochemistry, 56(1), 170-178. DOI: 10.1177/0004563218793163.
Kolyaee, N., Shahdousti, P. & Aghamohammadi, M. (2017). Determination of ofloxacin using ultrasound-assisted emulsification microextraction by high performance liquid chromatography. Journal of Applied Researches in Chemistry, 11(1), 79-86 [In Persian].
Ma, J. J., Du, X., Zhang, J. W., Li, J. C. & Wang, L. Z. (2009). Ultrasound-assisted emulsification-microextraction combined with flame atomic absorption spectrometry for determination of trace cadmium in water samples. Talanta, 80(2), 980-984.
Matong, J., Mpupa, A. & Nomngongo, P. N. (2018). Ultrasound assisted-homogeneous liquid-liquid phase microextraction based on deep eutectic solvents and ethyl acetate for preconcentration of selected organochlorine pesticides in water samples. Eurasian Journal of Analytical Chemistry, 13(5), em59. DOI: 10.29333/ejac/97219
Ozcan, S., Tor, A. & Aydin, M. E. (2009). Application of ultrasound-assisted emulsification-micro-extraction for the analysis of organochlorine pesticides in waters. Water Research, 43(17), 4269-4277.
Patty, F. A. (1967). Industrial Hygiene and Toxicology, Wiley, New York, 2nd. Ed.
Płotka-Wasylka, J., Frankowski, M., Simeonov, V., Polkowska, Z. & Namieśnik, J. (2018). Determination of metals content in wine samples by inductively coupled plasma-mass spectrometry. Molecules, 23(11), 2886. DOI: 10.3390/molecules23112886
Ramachandra, N. & Narayana, B. (1999). Synthesis and characterization of yttrium and lanthanide perchlorate complexes of 4- salicylideneamino-3-mercapto-6-methyl -1,2,4-triazin (4H)-5-one. Indian Journal of Chemistry- Section A, 38(12), 1297-1299.
Regueiro, J., Liompart, M., Garcia-Jares, C., Garcia-Monteagudo, J. C. & Cela, R. (2008). Ultrasound-assisted emulsification-microextraction of emergent contaminants and pesticides in environmental waters. Journal of Chromatogrphy A, 1190(1-2), 27-38. DOI: 10.1016/j.chroma.2008.02.091
Saleh, A., Yamini, Y., Faraji, M., Rezaee, M. & Ghambarian, M., (2009). Ultrasound-assisted emulsification microextraction method based on applying low density organic solvents followed by gas chromatography analysis for the determination of polycyclic aromatic hydrocarbons in water samples. Journal of Chromatography A, 1216(39), 6673-6679.
Shabab, M., Rismanchian, M., Karimi Zeverdegani, S. & Rangkooy, H. A. (2018). Feasibility evaluation of trace amount of zinc in urine samples using atomic absorption solidified floating organic drop micro-extraction technique. Journal of Occupational Health and Epidemiology, 7(1), 11-19.
Sharifi, A., Hajiaghababaei, L., Suzangarzadeh, S. & Jalali Sarvestani, M. R. (2017). Synthesis of 3-((6-methyl-5-oxo-3-thioxo-2,5-dihydro-1,2,4-triazin-4(3H)-yl) imino) indolin-2-one as an excellent ionophore to the construction of a potentiometric membrane sensor for rapid determination of zinc. Analytical and Bioanalytical Electrochemistry, 9(7), 888-903.
Thanh, N. M., Hop, N. V., Luyen, N. D., Phong, N. H., & Toan, T. T. T. (2019). Simultaneous determination of Zn(II), Cd(II), Pb(II), and Cu(II) using differential pulse anodic stripping voltammetry at a bismuth film-modified electrode. Advances in Materials Science and Engineering, Volume 2019, Article ID 1826148, 11 pages. DOI:10.1155/2019/1826148
Wani, A. L., Parveen, N., Ansari, M. O., Ahmad, M. F., Jameel, S. & Shadab, G. G. H. A. (2017). Zinc: an element of extensive medical importance. Current Medicine Research and Practice, 7(3), 90-98.
Wu, C., Liu, N., Wu, Q., Wang, C. & Wang, Z. (2010). Application of ultrasound-assisted surfactant-enhanced emulsification microextraction for the determination of some organophosphorus pesticides in water samples. Analytical Chimica Acta, 679, 56-62.
_||_Arab, R., Hajiaghababaei, L., Badiei, A., Karimi, M., Ganjali, M. R. & Mohammadi Ziarani, G. (2019). 8-Hydroxyquinoline grafted nanoporous SBA-15 as a novel solid phase extractor for preconcentration of trace amount of Copper. International Journal of Nano Dimension, 10, 340-349.
Blanco, A. & Blanco, G. (2017). Essential minerals, In medical biochemistry, Academic Press, Elsevier, Chapter 29. pp. 715-743.
Ebrahimi-Najafabadi, H., Pasdaran, A., Rezaei Bezenjani, R. & Bozorgzadeh, E. (2019). Determination of toxic heavy metals in rice samples using ultrasound assisted emulsification microextraction combined with
inductively coupled plasma optical emission spectroscopy. Food Chemistry, 289, 26-32.
Elkins, H.B. (1959). The Chemistry of Industrial Toxicology, Wiley, New York, 2nd, Ed.
Ghasemi, E. & Kaykhaii, M. (2017). Determination of zinc, copper, and mercury in water samples by using novel micro cloud point extraction and UV-Vis spectrophotometry. Eurasian Journal of Analytical Chemistry, 12(4), 313-324. DOI:10.12973/ejac.2017.00172a
Grochowski, C., Blicharska, E., Krukow, P., Jonak, K., Maciejewski, M., Szczepanek, D., Jonak, K., Flieger, J. & Maciejewski, R. (2019). Analysis of trace elements in human brain: Its aim, methods, and concentration levels. Frontiers in Chemistry, 7, 115. DOI: 10.3389/fchem.2019.00115
Hamida, S., Ouabdesslam, L., Ladjel, A. F., Escudero, M. & Anzano, J. (2018). Determination of cadmium, copper, lead, and zinc in pilchard sardines from the bay of boumerdés by atomic absorption spectrometry. Analytical Letters, 51(16), 2501-2508. DOI:10.1080/00032719.2018.1434537
Hajiaghababaei, L., Badiei, A., Shojaan, M., Ganjali, M. R., Khaniani, Y., Mohammadi Ziarani, G. & Zarabadi-Poor, P. (2012). A novel method for the simple and simultaneous preconcentration of Pb2+, Cu2+ and Zn2+ ions with aid of diethylenetriamine functionalized SBA-15 nanoporous silica compound. International Journal of Environmental Analytical Chemistry, 92(12), 1352-1364.
Hajiaghababaei, L., Tajmiri, T., Badiei, A., Ganjali, M.R., Khaniani, Y. & Mohammadi Ziarani, G. (2013). Heavy metals determination in water and food samples after preconcentration by a new nanoporous adsorbent. Food Chemistry, 141, 1916-1922.
Hajiaghababaei, L., Zandinejad, S., Berijani, S. & Suzangarzadeh, S. (2016). Ultrasound assisted emulsification microextraction for selective determination of trace amount of mercury (II). Indian Journal of Chemistry, 55A, 423-428.
Jeffery, J., Frank, A. R., Hockridge, S., Stosnach, H. & Costelloe, S. J. (2019). Method for measurement of serum copper, zinc and selenium using total reflection X-ray fluorescence spectroscopy on the PICOFOX analyser: Validation and comparison with atomic absorption spectroscopy and inductively coupled plasma mass spectrometry.Annals of Clinical Biochemistry, 56(1), 170-178. DOI: 10.1177/0004563218793163.
Kolyaee, N., Shahdousti, P. & Aghamohammadi, M. (2017). Determination of ofloxacin using ultrasound-assisted emulsification microextraction by high performance liquid chromatography. Journal of Applied Researches in Chemistry, 11(1), 79-86 [In Persian].
Ma, J. J., Du, X., Zhang, J. W., Li, J. C. & Wang, L. Z. (2009). Ultrasound-assisted emulsification-microextraction combined with flame atomic absorption spectrometry for determination of trace cadmium in water samples. Talanta, 80(2), 980-984.
Matong, J., Mpupa, A. & Nomngongo, P. N. (2018). Ultrasound assisted-homogeneous liquid-liquid phase microextraction based on deep eutectic solvents and ethyl acetate for preconcentration of selected organochlorine pesticides in water samples. Eurasian Journal of Analytical Chemistry, 13(5), em59. DOI: 10.29333/ejac/97219
Ozcan, S., Tor, A. & Aydin, M. E. (2009). Application of ultrasound-assisted emulsification-micro-extraction for the analysis of organochlorine pesticides in waters. Water Research, 43(17), 4269-4277.
Patty, F. A. (1967). Industrial Hygiene and Toxicology, Wiley, New York, 2nd. Ed.
Płotka-Wasylka, J., Frankowski, M., Simeonov, V., Polkowska, Z. & Namieśnik, J. (2018). Determination of metals content in wine samples by inductively coupled plasma-mass spectrometry. Molecules, 23(11), 2886. DOI: 10.3390/molecules23112886
Ramachandra, N. & Narayana, B. (1999). Synthesis and characterization of yttrium and lanthanide perchlorate complexes of 4- salicylideneamino-3-mercapto-6-methyl -1,2,4-triazin (4H)-5-one. Indian Journal of Chemistry- Section A, 38(12), 1297-1299.
Regueiro, J., Liompart, M., Garcia-Jares, C., Garcia-Monteagudo, J. C. & Cela, R. (2008). Ultrasound-assisted emulsification-microextraction of emergent contaminants and pesticides in environmental waters. Journal of Chromatogrphy A, 1190(1-2), 27-38. DOI: 10.1016/j.chroma.2008.02.091
Saleh, A., Yamini, Y., Faraji, M., Rezaee, M. & Ghambarian, M., (2009). Ultrasound-assisted emulsification microextraction method based on applying low density organic solvents followed by gas chromatography analysis for the determination of polycyclic aromatic hydrocarbons in water samples. Journal of Chromatography A, 1216(39), 6673-6679.
Shabab, M., Rismanchian, M., Karimi Zeverdegani, S. & Rangkooy, H. A. (2018). Feasibility evaluation of trace amount of zinc in urine samples using atomic absorption solidified floating organic drop micro-extraction technique. Journal of Occupational Health and Epidemiology, 7(1), 11-19.
Sharifi, A., Hajiaghababaei, L., Suzangarzadeh, S. & Jalali Sarvestani, M. R. (2017). Synthesis of 3-((6-methyl-5-oxo-3-thioxo-2,5-dihydro-1,2,4-triazin-4(3H)-yl) imino) indolin-2-one as an excellent ionophore to the construction of a potentiometric membrane sensor for rapid determination of zinc. Analytical and Bioanalytical Electrochemistry, 9(7), 888-903.
Thanh, N. M., Hop, N. V., Luyen, N. D., Phong, N. H., & Toan, T. T. T. (2019). Simultaneous determination of Zn(II), Cd(II), Pb(II), and Cu(II) using differential pulse anodic stripping voltammetry at a bismuth film-modified electrode. Advances in Materials Science and Engineering, Volume 2019, Article ID 1826148, 11 pages. DOI:10.1155/2019/1826148
Wani, A. L., Parveen, N., Ansari, M. O., Ahmad, M. F., Jameel, S. & Shadab, G. G. H. A. (2017). Zinc: an element of extensive medical importance. Current Medicine Research and Practice, 7(3), 90-98.
Wu, C., Liu, N., Wu, Q., Wang, C. & Wang, Z. (2010). Application of ultrasound-assisted surfactant-enhanced emulsification microextraction for the determination of some organophosphorus pesticides in water samples. Analytical Chimica Acta, 679, 56-62.
