Characterization of Electro Synthesized Perovskites Structured Ybmno3 Nanoparticles

Subject Areas :

hamid mohmmad shiri ¹ , Saab Sadeghi ² , Reza Safari ³ , Ali Ehsani ⁴ , Hamid Reza Ebrahimi ⁵ , hamid hadi ⁶

1 - Assistant Prof. Department of Chemistry, Payame Noor University, Iran.
2 - Ph.D. Student, Department of Chemistry, Payame Noor University, Iran.
3 - Assistant Prof. Department of Chemistry, Faculty of science, University of Qom, Qom, Iran.
4 - Department of Chemistry, Faculty of Science, University of Qom, Qom, I.R. Iran
5 - Associated Prof. Center for Advanced Engineering Research, Majlesi Branch, Islamic Azad University, Isfahan, Iran.
6 - Ph.D. Student, Department of Chemistry, Faculty of Science, Lorestan University, KhorramAbad, Iran Iran.

Received: 2021-03-16 Accepted : 2021-07-25 Published : 2022-02-20

Keywords: Electrosynthesis Perovskite Nanostructure Williamson, Hall YbMnO3,

Abstract :

Prosciuttoes are compounds that have the general formula ABO3, such as YbMnO3. In this research, YbMnO3 nanostructure has been synthesized by electrochemical deposition technique which is the green simple and new method. Then, XRD, DSC, SEM and EDS characterization tests were performed on the synthetic sample and the obtained results were analyzed. In addition, the morphological and structural properties of the synthetic nanomaterial showed that the main product was YbMnO3, with a nanoscale agglomerated structure with a particle size estimated at 35.5 nm. Also, some mechanical quantities, such as stress, strain, lattice constants and particle size of the synthetic perovskite compound, are calculated using the Scherer equation and the Williamson-Hall method, and the results were obtained with the results (values) obtained from the XRD spectra. And SEM were compared. It is predicted that the result of this research can open new horizons in the low-cost synthesis of eco-friendly (green Chemistry) nanomaterials and nanoparticles.

References:

[1] I. A. Wani, S. Khatoon, A. Ganguly, J. Ahmed, A. K. Ganguli & T. Ahmad," Silvernanopartices: Large Scale Solvothermal Synthesis and Optical Properties", Materials Research Bulletin, vol. 45, no. 8, pp. 1033-103, 2010.

 

[2] M. Torabi, S. H. Razavi & S. Sanjabi, "Electrochemical Evaluation of PbO Nanoparticles as Anode for Lithum Ion Batteries", International Journal of Engineering, vol. 24, no. 4, pp. 351- 355, 2011.

 

[3] M. Bin Ahmad, J. J. Lim, K. Shameli, N. A. Ibrahim & M. Y. Tay, "Synthesis of Silver Nanoparticles in Chitosan, Gelatin and Chitosan/Gelatin Bionanocomposites by a Chemical Reducing Agent and Their Characterization", Molecules, vol. 16, no. 9, pp. 7237-7248, 2011.

 

[4] J. T. Mefford, W. G. Hardin, S. Dai, K. P. Johnston & K. J. Stevenson, "Anion Charge Storage Through Oxygen Intercalation in LaMnO3 Perovskite Pseudocapacitor Electrodes", Nature Materials, vol. 7, no. 13, pp. 726-732, 2014.

 

[5] T. Hyodo, M. Hayashi, N. Miura & N. Yamazoe, "Catalytic Activities of Rare-Earth Manganites for Cathodic Reduction of Oxygen in Alkaline Solution", Journal of Electrochemical Society, vol. 143, no. 11, pp. 266, 1996.

 

[6] T. Mori, N. Kamegashira, K. Aoki, T. Shishido & T. Fukuda, "Crystal Growth and Crystal Structures of the LnMnO3 Perovskites: Ln = Nd, Sm, Eu and Gd", Materials Letter, vol. 54, no. 2-3, pp. 238–243, 2002.

 

[7] K. Uusi-Esko & Espoo, "Synthesis and Characterization of Ternary Manganese Oxides, Doctoral Dissertation", Aalto University publication series, 2011.

 

[8] H. M. Shiri & A. Ehsani, "Electrochemical Synthesis of Sm2O3 Nanoparticles: Application in Conductive Polymer Composite Films for Supercapacitors", Journal of Colloid Interface Science, vol. 505, pp. 940-946, 2017.

 

[9] J. F. M. Ibrahima, A. E. Mergena, I. Sahina & H. S. Basheerb, "The Effect of Europium Doping on the Structural and Magnetic Properties of GdMnO3 Multiferroic Ceramics", Advanced Ceramics Progress, vol. 3, no. 4, pp. 1-5, 2017.

 

[10] Z. Rajaee, M. R. Mohammadi & A. Saatchi, "Synthesis of Nanocrystalline Sr0.895Y0.07TiO3±δ by Sol-Gel Method", Journal of Advanced Materials and Technologies, vol, 4, no.13, pp. 11-18, 2014.

 

[11] S. Xing, S. Song & J. Xiang, "Study on Magnetic, Optical and Photocatalytic Activities of TbMnO3@CeO2 Composite Multiferroic Materials", Optik, vol. 220, pp. 165144, 2020.

 

[12] N. F. Atta, A. Gala & E. H. El-Ads, "Perovskite Nanomaterials- Synthesis, Characterization and Application", ExLi4EvA, Vol. 4, pp. 627-723, 2016.

2011. U. Esko, "Synthesis and Characterization of Ternary Manganese Oxides", Chemical Materials, vol. 23, no. pp 1835-1840, 2011.

 

[13] M. Chandrasekhar, D. V. Sunitha, H. Nagabhushana & Sc. Sharma, "One-Pot Synthesis of Dysprosium Oxide Nano-Sheets: Antimicrobial Potential and Cytotoxicity on A549 Lung Cancer Cells", Journal of Cluster Science, vol. 28, no. 1, pp. 621–635, 2016.

 

[14] G. Singla, K. Singh & O. P. Pandey, "Williamson–Hall Study on Synthesized Nanocrystalline Tungsten Carbide (WC), Applied Physics A, vol. 113, no. 1, pp. 237-242, 2013.

 

[15] P. Bindu & S. Thomas, "Estimation of Lattice Strain in ZnO Nanoparticles: X-ray Peak Profile Analysis", Journal of Theoretical and Applied Physics A, vol. 8, no. 4, pp. 123–134, 2014.

 

[16] M. Shiri & A. Ehsani,"A Simple and Innovative Route to Electrosynthesis of Eu2O3 Nanoparticles and Its Nanocomposite with p-type Conductive Polymer: Characterization and Electrochemical Properties", Journal of Colloid Interface Science, vol. 473, pp. 126-131, 2016.

 

[17] M. Aghazadeha, H. M. Shiri & A. A. Malek Barmia, "Uniform Co (OH)2 Disc-Like Nanostructures Prepared by Low-Temperature Electrochemical Rout as an Electrode Material for Supercapacitors", Applied Surface Science, vol. 273, pp. 237– 242, 2013.

 

[18] M. Aghazadeh, A. A. MalekBarmi, H. M. Shiri & S. Sedaghat, "Cathodic Electrodeposition of Y(OH)3 and Y2O3 Nanostructures from Chloride Bath. Part II: Effect of the Bath Temperature on the Crystal Structure", Composition and Morphology, Ceramics International, vol. 39, no. 2, pp. 1045–1055, 2013.

 

[19] M. Karppinen, H. Yamauchi, N. Imamura, J. Malm & K. Uusi-Esko, "Characterization of RMnO3 (R = Sc, Y, Dy-Lu): High-Pressure Synthesized Metastable Perovskites and Their Hexagonal Precursor Phases", Materials Chemistry and Physics, vol. 112, no. 3, pp.1029-1034, 2008.

 

[20] K. Pourzare, Y. Mansourpanah, S. Farhadi, M. M. H. Sadrabadi, I. Frost & M. Ulbricht, "Improving the Efficiency of Nafion-Based Proton Exchange Membranes Embedded with Magnetically Aligned Silica-Coated Co3O4 Nanoparticles", Solid State Ionics, vol. 351, pp. 115343, 2020.

 

[21] Y. H. Huang, H. Fjellvag, M. Karppinen, B. C. Hauback & H. J. B. Yamauchi, "Crystal and Magnetic Structure of the Orthorhombic Perovskite YbMnO3", Chemistry Materials, vol. 18, no.8, pp. 2130-2134, 2006.

 

[22] A. M. Fathi Dehkharghani, M. R. Rahimipour & M. Zakeri, "Crystal Structure and Lattice Parameter Investigation of La3+ Substituted CeO2 in LaxCe1-xO2-X/2 Synthesized by Solid-State Method", Advanced Ceramics Progress, vol. 6, no. 1, pp. 43-48, 2020.

 

[23] M. R. Dadfar, M. R. Rahimipour, M. R. Vaezia & A. Gholamzadeh, "Characterization and Phase Transformation of Spherical YSZ Powders Fabricated Via Air Plasma Spray Method", Advanced Ceramics Progress, vol. 2, no. 4, pp. 32-38, 2016.

 

[24] R. M. Chellab, & K. H. Harbbi, "The Correction of the Line Profiles for X- Ray Diffraction Peaks by Using Three Analysis Methods, Technologies and Materials for Renewable Energy, Environment and Sustainability", AIP Conference Proceedings 2123, vol. 21, pp. 020044-1-020044-8, 2019.

 

[25] R. Yazdani Ra & A. H. Pakseresht,  The Effect of Volume Percent of SiC Reinforcement Phase on the Morphology and Microstructure of Nano Aluminum Composite Powders Made by Mechanical Alloying", Journal of Advanced Materials and Technologies, vol. 83-86, pp. 764-770, 2010.

[26] Y. T. Prabhu & K. V. Rao, "X-Ray Analysis by Williamson-Hall and Size-Strain Plot Methods of ZnO", World Journal of Nano Science and Engineering, vol. 4, no. 1, pp. 21-28, 2014.

 

[27] ا. ح. امامی، س. ک. حسینی و د. داودی، "تولید نانو پودر کامپوزیتی نیکل-کاربید وانادیم از مواد اولیه اکسیدی به روش مکانوشیمیایی"، فرآیندهای نوین در مهندسی مواد، دوره 12، شماره 4، صفحه 39-29، 1397.

 

[28] ا. نجفی، م. خوئینی و م. امانی، "سنتز و مشخصه‌یابی خواص نانوذرات مزومتخلخل سیلیکاتی توخالی با استفاده از قالب پلی استایرن". فرآیندهای نوین در مهندسی مواد، دوره 14، شماره 1، صفحه 45-54، 1399.

 

[29] م. تحریری، م. مهدوی و ح. فرخ پور، "بررسی اثر پوشش دهی نانو استیل استونات منگنز بر روی مکانیسم تجزیه حرارتی آمونیوم پرکلرات". فرآیندهای نوین در مهندسی مواد، دوره 14، شماره 2، صفحه 67-78، 1399.