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        1 - The Effects of Oxide Fluxes on the Penetration Depth of 316L and A516 Steels in A-TIG Welding: a Comparative Study
        Mohammad Emami Seyed Hossein Elahi
        The present work evaluates the mechanisms that cause the weld geometry to change in activating flux TIG (A-TIG) welding. For this purpose, an austenitic 316 stainless steel and ferritic A516 steel in conventional TIG and A-TIG welding were compared and evaluated under t More
        The present work evaluates the mechanisms that cause the weld geometry to change in activating flux TIG (A-TIG) welding. For this purpose, an austenitic 316 stainless steel and ferritic A516 steel in conventional TIG and A-TIG welding were compared and evaluated under the same process parameters. Al2O3, Fe2O3, MnO2, SiO2, and TiO2 powders were used as activating fluxes. The depth of penetration and width of the beads were measured metallographically. In conventional TIG, the welds of carbon steel and stainless steel had a thickness of about 2.2 mm and 1.7 mm, respectively. A-TIG welding of 316 SS using TiO2, MnO2, and Fe2O3 led to a 75% increase in the weld depth. In the case of Al2O3 and SiO2 the weld depth increased 50% and 9%, respectively. However, in A516 steel, less thermodynamically stable oxide fluxes such as MnO2, and Fe2O3 had a smaller effect i.e., 9-22% increases. More stable oxides like Al2O3, SiO2, and TiO2 caused a decrease of about 30% in the weld depth compared to the conventional TIG weld. It was proposed that when the penetration increases, reverse Marangoni is dominant. This mechanism is mainly associated with viscosity and surface tension that vary by the dissolution of oxygen in the melt. Regarding penetration reduction, as in the case of more stable oxides like SiO2, the energy dissipation by the flux through heating and dissociation of the oxide and barrier effect of the undissolved oxide dominate. Manuscript profile
      • Open Access Article

        2 - Effects of Fe and Si Additions on Erosion-Oxidation Behavior of Nickel Alloys in Chlorine-Containing Oxidative Atmospheres
        Mohammad Emami Shigenari Hayashi
        High-temperature erosion-oxidation (E-O) of Ni-20Cr-(0-30)Fe-(0-4)Si was investigated in fluidized bed waste incineration conditions. The specimens were tested in a rig for 250 h, under the collision of hot silica sand contaminated with 0.5 wt.% of NaCl-KCl salt mixture More
        High-temperature erosion-oxidation (E-O) of Ni-20Cr-(0-30)Fe-(0-4)Si was investigated in fluidized bed waste incineration conditions. The specimens were tested in a rig for 250 h, under the collision of hot silica sand contaminated with 0.5 wt.% of NaCl-KCl salt mixture at a temperature of 700 °C. To have a better understanding of the materials’ behavior, the specimens were also oxidized at 560 °C for 100 h in the atmosphere of air + chlorine vapors. The thickness reduction and mass gain of the specimens were used to evaluate the materials under E-O and oxidation conditions, respectively. The specimens were studied using FESEM, EDS, and XRD analysis. At E-O conditions, Ni-20Cr showed the highest material loss (~17.6 mm). The addition of 30 wt.% of Fe to the alloy decreased the wastage to about 6.7 mm. The E-O resistance of Ni-20Cr-30Fe-4Si was about two times lower than the Si-free alloy which indicates that Si had a detrimental effect on the E-O resistance of the alloys. Under oxidation conditions, Ni-20Cr-30Fe showed the highest resistance with a mass gain of about 0.1 mg/cm2. The addition of 4 wt.% Si caused a dramatic decrease in the oxidation resistance of the alloy (mass gain of ~3.8 mg/cm2). The addition of Fe stimulated Cr2O3 scale formation by which the higher E-O and oxidation resistance of the alloy were confirmed. In Ni-20Cr, the formation of a multi-component scale, and in Ni-20Cr-30Fe-4Si, a porous surface scale formed through active oxidation were possibly responsible for the poor performance of these alloys. Manuscript profile