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مقاله
1 - Sulfonated polystyrene/montmorillonite nanocomposite as a new and efficient catalyst for the solvent-free Mannich reactionIranian Journal of Catalysis , شماره 1 , سال 2 , زمستان 2012Sulfonated polystyrene/montmorillonite nanocomposite (OMMT/PS-SO3H) was prepared and used as a novel, efficient and inexpensive heterogeneous acid catalyst in the one-pot reaction three-component Mannich reaction of ketones, aromatic aldehydes and amines under solvent-f چکیده کاملSulfonated polystyrene/montmorillonite nanocomposite (OMMT/PS-SO3H) was prepared and used as a novel, efficient and inexpensive heterogeneous acid catalyst in the one-pot reaction three-component Mannich reaction of ketones, aromatic aldehydes and amines under solvent-free conditions. The catalyst was characterized by XRD, SEM, TG, BET and FT-IR techniques. This method has advantages of high yield, moderate to excellent diasteroselectivity, mild condition, catalyst recyclability, and simple work-up procedure. پرونده مقاله -
مقاله
2 - BaO/TiO2-ZrO2 as a green and efficient basic catalyst for Knoevenagel condensation reactionIranian Journal of Catalysis , شماره 5 , سال 1 , بهار 2011A simple and green synthetic strategy to prepare BaO/TiO2-ZrO2 as a solid base catalyst was reported. These materials with various amounts of BaO were prepared by the adsorption method. The physical and chemical properties of BaO/TiO2-ZrO2 were investigated by X-ray dif چکیده کاملA simple and green synthetic strategy to prepare BaO/TiO2-ZrO2 as a solid base catalyst was reported. These materials with various amounts of BaO were prepared by the adsorption method. The physical and chemical properties of BaO/TiO2-ZrO2 were investigated by X-ray diffraction, X-ray fluorescence, specific surface area and BJH pore size distribution, FT-IR spectroscopy, scanning electron microscopy and energy dispersive spectra techniques. The catalytic performance of catalyst was determined for the Knoevenagel condensation reaction between carbonyl compounds and ethyl cyanoacetate in the presence of water as a solvent. The catalyst used for this synthetically useful transformation showed considerable level of reusability besides very good activity. پرونده مقاله