Sulfonated polystyrene/montmorillonite nanocomposite as a new and efficient catalyst for the solvent-free Mannich reaction

محورهای موضوعی : Iranian Journal of Catalysis

Ahmad Reza Massah ¹ , Roozbeh Kalbasi ² , Mitra Toghyani ³

1 - Department of Chemistry, Shahreza Branch, Islamic Azad University, Shahreza, Isfahan, 86145-311, Iran.
2 - Department of Chemistry, Shahreza Branch, Islamic Azad University, Shahreza, Isfahan, 86145-311, Iran. Razi Chemistry Research Center, Shahreza Branch, Islamic Azad University Shahreza, Isfahan, 86145-311, Iran
3 - Department of Chemistry, Shahreza Branch, Islamic Azad University, Shahreza, Isfahan, 86145-311, Iran.

تاریخ دریافت : 1391/02/28 تاریخ پذیرش : 1391/04/03 تاریخ انتشار : 1390/10/11

کلید واژه: Solvent-free, Mannich reaction, β-amino carbonyl compound, OMMT/PS-SO3H, Nano composite,

چکیده مقاله :

Sulfonated polystyrene/montmorillonite nanocomposite (OMMT/PS-SO3H) was prepared and used as a novel, efficient and inexpensive heterogeneous acid catalyst in the one-pot reaction three-component Mannich reaction of ketones, aromatic aldehydes and amines under solvent-free conditions. The catalyst was characterized by XRD, SEM, TG, BET and FT-IR techniques. This method has advantages of high yield, moderate to excellent diasteroselectivity, mild condition, catalyst recyclability, and simple work-up procedure.

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