Efficient synthesis of trisphenols using reduced sulfonated graphene nanocatalyst under solvent free conditions
محورهای موضوعی : Iranian Journal of Catalysis
Samaneh Behravesh
1
(Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran.|
Department of Chemistry, Science and Research Branch, Islamic Azad University, Iran.)
Reza Fareghi-Alamdari
2
(Department of Chemistry and Chemical Engineering, Malek-Ashtar University of Technology, Tehran 167653454, I.R. Iran.)
Rashid Badri
3
(Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran.|
Department of Chemistry, Science and Research Branch, Islamic Azad University, Iran.)
کلید واژه: Solvent-free conditions, 2, Trisphenol, 6-bis(hydroxymethyl) phenols, Sulfonated reduced graphene oxide,
چکیده مقاله :
This study reports a new methodology for the efficient synthesis of trisphenol compounds using the reaction of 2,6-bis(hydroxymethyl) phenols with phenols under heterogeneous conditions. A sulfonated reduced graphene oxide (RGO-SO3H) nanocatalyst was used to promote the reaction under solvent-free conditions. A range of trisphenol compounds were produced in the presence of this catalyst system in good to excellent yields. In the presence of this catalyst system, a less amount of phenol is required, which improves the environment through its capability in synthesis of trisphenols. The RGO-SO3H catalyst was reusable at least for 8 times in this process without a significant decrease in its catalytic activity.
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