Polymer-Assisted Synthesis and Characterization of Nickel Aluminate Nanoparticles for Photodegradation of Methylene Blue

الموضوعات :

Sogol Bakhtiarvand ¹ , Seyed Ali Hassanzadeh Tabrizi ²

1 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran
2 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran

تاريخ الإرسال : 18 الخميس , محرم, 1443 تاريخ التأكيد : 06 الأحد , ربيع الأول, 1444 تاريخ الإصدار : 26 الإثنين , ربيع الأول, 1443

الکلمات المفتاحية: Nanopowders, Photocatalytic Activity, Wet chemical method, NiAl2O4,

ملخص المقالة :

A simple polymer-assisted wet chemical method was used to synthesize NiAl2O4 nanopowder. The photocatalytic properties of synthesized powders were investigated for the degradation of methylene blue. For this aim, metal salts and polymeric precursors were dissolved in water, and then a crosslinker was added till a gel was formed. The product was calcined to produce nanopowders. XRD results confirmed the formation of nickel aluminate with spinel structure. In addition, the findings showed that the produced NiAl2O4 nanopowders have a particle size range between 35 to 100 nm with a uniform particle size distribution. The optical properties of the samples showed that the bandgap energy of NiAl2O4 is about 3.44 eV. The nickel aluminate nanopowders demonstrated high photocatalytic activity for photodegradation of methylene blue, which could be attributed to their small particle sizes. It seems that the polymer-assisted wet chemical synthesis may open up an effective route for the production of ceramic photocatalyst nanopowders with high quality.

المصادر:

[1]        Z. Mengting, T.A. Kurniawan, S. Fei, T. Ouyang, M.H.D. Othman, M. Rezakazemi, S. Shirazian, Applicability of BaTiO₃/graphene oxide (GO) composite for enhanced photodegradation of methylene blue (MB) in synthetic wastewater under UV–vis irradiation, Environ. Pollut. 255 (2019) 113182.

[2]        A.A. Shah, M.A. Bhatti, A. Tahira, A.D. Chandio, I.A. Channa, A.G. Sahito, E. Chalangar, M. Willander, O. Nur, Z.H. Ibupoto, Facile synthesis of copper doped ZnO nanorods for the efficient photo degradation of methylene blue and methyl orange, Ceram. Int. 46 (2020) 9997–10005.

[3]        M. Saleem, J. Iqbal, A. Nawaz, B. Islam, I. Hussain, Synthesis, characterization, and performance evaluation of pristine and cerium‐doped WO₃ nanoparticles for photodegradation of methylene blue via solar irradiation, Int. J. Appl. Ceram. Technol. 17 (2020) 1918–1929.

[4]        K.K. Chenab, B. Sohrabi, A. Jafari, S. Ramakrishna, Water treatment: Functional nanomaterials and applications from adsorption to photodegradation, Mater. Today Chem. 16 (2020) 100262.

[5]        S. Yu, Y. Wang, F. Sun, R. Wang, Y. Zhou, Novel mpg-C₃N₄/TiO₂ nanocomposite photocatalytic membrane reactor for sulfamethoxazole photodegradation, Chem. Eng. J. 337 (2018) 183–192.

[6]        X. Hu, G. Wang, J. Wang, Z. Hu, Y. Su, Step-scheme NiO/BiOI heterojunction photocatalyst for rhodamine photodegradation, Appl. Surf. Sci. 511 (2020) 145499.

[7]        M.H. Aghaali, S. Firoozi, Enhancing the catalytic performance of Co substituted NiAl₂O₄ spinel by ultrasonic spray pyrolysis method for steam and dry reforming of methane, Int. J. Hydrogen Energy. 46 (2021) 357–373.

[8]        A. Morales-Marín, J.L. Ayastuy, U. Iriarte-Velasco, M.A. Gutiérrez-Ortiz, Biohydrogen production by glycerol Aqueous-Phase Reforming: Effect of promoters (Ce or Mg) in the NiAl₂O₄ spinel-derived catalysts, J. Environ. Chem. Eng. 9 (2021) 106433.

[9]        M.R.I. Faruque, E. Ahamed, M.A. Rahman, M.T. Islam, Flexible nickel aluminate (NiAl₂O₄) based dual-band double negative metamaterial for microwave applications, Results Phys. 14 (2019) 102524.

[10]      N.M.D. Vitorino, A. V Kovalevsky, M.C. Ferro, J.C.C. Abrantes, J.R. Frade, Design of NiAl₂O₄ cellular monoliths for catalytic applications, Mater. Des. 117 (2017) 332–337.

[11]      C. Chen, M. Xu, K. Zhang, H. An, G. Zhang, B. Hong, J. Li, Y. Lai, Atomically ordered and epitaxially grown surface structure in core-shell NCA/NiAl₂O₄ enabling high voltage cyclic stability for cathode application, Electrochim. Acta. 300 (2019) 437–444.

[12]      S.G. Menon, H.C. Swart, Microwave-assisted synthesis of blue-green NiAl₂O₄ nanoparticle pigments with high near-infrared reflectance for indoor cooling, J. Alloys Compd. 819 (2020) 152991.

[13]      R. Pournajaf, S.A. Hassanzadeh-Tabrizi, Polyacrylamide synthesis of nanostructured copper aluminate for photocatalytic application, J. Adv. Mater. Process. 5 (2018) 12–19.

[14]      S. Wang, D. Li, C. Yang, G. Sun, J. Zhang, Y. Xia, C. Xie, G. Yang, M. Zhou, W. Liu, A novel method for the synthesize of nanostructured MgFe₂O₄ photocatalysts, J. Sol-Gel Sci. Technol. 84 (2017) 169–179.

[15]      S. Wang, S. Tang, H. Gao, L. Fang, Q. Hu, G. Sun, X. Chen, C. Yu, H. Liu, X. Pan, Modified polyacrylamide gel synthesis of CeO₂ nanoparticles by using cerium sulfate as metal source and its optical and photoluminescence properties, J. Mater. Sci. Mater. Electron. 32 (2021) 10820–10834.

[16]      M. Ahmadyari-Sharamin, S.A. Hassanzadeh-Tabrizi, Polyacrylamide gel synthesis, characterization, and optical properties of Co_1-xNixCr₂O₄ spinel nanopigment, J. Sol-Gel Sci. Technol. 99 (2021) 534–545.

[17]      X. Su, G. Bai, J. Zhang, J. Zhou, Y. Jia, Preparation and flash sintering of MgTiO₃ nanopowders obtained by the polyacrylamide gel method, Appl. Surf. Sci. 442 (2018) 12–19.

[18]      M.A.R. Miranda, J.M. Sasaki, The limit of application of the Scherrer equation, Acta Crystallogr. Sect. A Found. Adv. 74 (2018) 54–65.

[19]      M. Łączka, K. Cholewa-Kowalska, K. Kulgawczyk, M. Klisch, W. Mozgawa, Structural examinations of gel-derived materials of the CaO–P₂O₅–SiO₂ system, J. Mol. Struct. 511 (1999) 223–231.

[20]      R. Balasubramanian, R. Srinivasan, J. Lee, Barrier, rheological, and antimicrobial properties of sustainable nanocomposites based on gellan gum/polyacrylamide/zinc oxide, Polym. Eng. Sci. 61 (2021) 2477–2486.

[21]      F. Majid, J. Rauf, S. Ata, I. Bibi, A. Malik, S.M. Ibrahim, A. Ali, M. Iqbal, Synthesis and characterization of NiFe₂O₄ ferrite: Sol–gel and hydrothermal synthesis routes effect on magnetic, structural and dielectric characteristics, Mater. Chem. Phys. 258 (2021) 123888.

[22]      J.J.H. McCallister, M.D. Gammage, J.W. Keto, M.F. Becker, D. Kovar, Influence of agglomerate morphology on micro cold spray of Ag nanopowders, J. Aerosol Sci. 151 (2021) 105648.

[23]      C. Hu, Z. Zhang, H. Liu, P. Gao, Z.L. Wang, Direct synthesis and structure characterization of ultrafine CeO₂ nanoparticles, Nanotechnology. 17 (2006) 5983.

[24]      U.Z.M. Zaidi, A.R. Bushroa, R.R. Ghahnavyeh, R. Mahmoodian, Crystallite size and microstrain: XRD line broadening analysis of AgSiN thin films, Pigment Resin Technol. 48 (2019) 473-480.

[25]      C. Ragupathi, J.J. Vijaya, L.J. Kennedy, Preparation, characterization and catalytic properties of nickel aluminate nanoparticles: A comparison between conventional and microwave method, J. Saudi Chem. Soc. 21 (2017) S231–S239.

[26]      V. Elakkiya, R. Abhishekram, S. Sumathi, Copper doped nickel aluminate: Synthesis, characterisation, optical and colour properties, Chinese J. Chem. Eng. 27 (2019) 2596–2605.

[27]      F.Z. Akika, M. Benamira, H. Lahmar, A. Tibera, R. Chabi, I. Avramova, Ş. Suzer, M. Trari, Structural and optical properties of Cu-substitution of NiAl₂O₄ and their photocatalytic activity towards Congo red under solar light irradiation, J. Photochem. Photobiol. A Chem. 364 (2018) 542–550.

[28]      P.R. Jubu, F.K. Yam, V.M. Igba, K.P. Beh, Tauc-plot scale and extrapolation effect on bandgap estimation from UV–vis–NIR data–a case study of β-Ga₂O₃, J. Solid State Chem. 290 (2020) 121576.

[29]      C. Venkataramana, S.M. Botsa, P. Shyamala, R. Muralikrishna, Photocatalytic degradation of polyethylene plastics by NiAl₂O₄ spinels-synthesis and characterization, Chemosphere. 265 (2021) 129021.

[30]      M. Arunkumar, A.S. Nesaraj, One pot chemical synthesis of ultrafine NiAl₂O₄ nanoparticles: physico-chemical properties and photocatalytic degradation of organic dyes under visible light irradiation, Inorg. Nano-Metal Chem. 51 (2021) 910–917.

[31]      V. Elakkiya, Y. Agarwal, S. Sumathi, Photocatalytic activity of divalent ion (copper, zinc and magnesium) doped NiAl₂O₄, Solid State Sci. 82 (2018) 92–98.

[32]      M. Arunkumar, A. Samson Nesaraj, Photocatalytic degradation of malachite green dye using NiAl₂O₄ and Co doped NiAl₂O₄ nanophotocatalysts prepared by simple one pot wet chemical synthetic route, Iran. J. Catal. 10 (2020) 235–245.

[33]      A. Iben Ayad, D. Luart, A. Ould Dris, E. Guénin, Kinetic analysis of 4-nitrophenol reduction by “water-soluble” palladium nanoparticles, Nanomaterials. 10 (2020) 1169