تولید فیلم زیست‌تخریب‌پذیر بر پایه نانوذرات اکسید روی-پلی لاکتیک اسید– نشاسته و ارزیابی خواص آن
الموضوعات : کاربرد شیمی در محیط زیستهادی اسلامی 1 , هدا جعفری زاده مالمیری 2 , حسین علی خنکدار 3
1 - گروه مهندسی شیمی، واحد تهران شمال، دانشگاه آزاد اسلامی،تهران،ایران
2 - Department of Chemical Engineering, Sahand University of Technology, Tabriz, Iran
3 - پژوهشکده فرآیند، پژوهشگاه پلیمر و پتروشیمی ایران، تهران، ایران
الکلمات المفتاحية: فیلم‌های زیست‌تخریب‌پذیر, پلی لاکتیک اسید, نشاسته, نانوذرات اکسید روی ,
ملخص المقالة :
امروزه توسعه و ساخت فیلم‌های زیست‌تخریب‌پذیر با استفاده از ترکیبات طبیعی، به‌عنوان جایگزینی مناسب برای پلاستیک‌های مصنوعی میباشد. فیلم‌های زیست‌تخریب‌پذیر حاوی پلی لاکتیک اسید (PLA) و نشاسته (Starch) در سه نسبت وزنی 10/90، 20/80 و 30/70 تهیه و با استفاده از تکنیک‌های طیف‌سنج مادون‌قرمز تبدیل فوریه ، پراش اشعه ایکس، گرماوزن سنجی ، میکروسکوپ الکترونی روبشی - عبوری و طیف سنجی پراش انرژی پرتو ایکس مورد ارزیابی قرار گرفتند. نتایج نشان داد که بیشترین مقدار نشاسته (30 درصد) منجر به شکنندگی و استحکام کمتر لایه‌های Starch/PLA میگردد. همچنین افزودن 5 درصد آنیدرید مالئیک (MA) و نانوذرات اکسیدروی (ZnONPs) به فیلم، چسبندگی بین دوفاز را افزایش داد. علاوه بر این، با افزایش مقدار ZnONPs از 1 به 5 درصد در فرمولاسیون فیلم، ساختار آمورف فیلم به طور معنی داری(0.05P<) افزایش یافته و فیلم های حاوی 1 و 5 درصد ZnONPs دارای اندازه های کریستالی 14/34و 4/28 نانومتر میباشند. نتایج نشان میدهد که با افزایش مقدار ZnONPs در فیلم از 1 به 5 درصد، مقاومت حرارتی آن افزایش و وزن فیلم‌ها از 13/95 به 19/88 درصد کاهش یافت. همچنین درصد تخریب فیلم ها پس از یک ماه از 3/77 به 39/69 درصد کاهش یافت. همچنین نتایج نشان داد که فیلم های بر پایه MA/ZnONPs/Starch/PLA با نسبت 5/5/20/80، دارای کربن، اکسیژن و روی به ترتیب با درصد وزنی 3/70، 1/25 و 6/4 میباشد.
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