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        1 - Employing α-Fe2O3 /Mn2P2O7 as a nano photocatalyst for degradation of toluene in aqueous environment
        Sajjad Mafi Kazem Mahanpoor
        The existence of different resistant organic pollutants especially toxic organic aromatics such as Toluene in aquatic environments has become a significant environmental matter in recent years. In this paper, α-Fe2O3 Nano-spheres are immobilized on the surface of Mangan More
        The existence of different resistant organic pollutants especially toxic organic aromatics such as Toluene in aquatic environments has become a significant environmental matter in recent years. In this paper, α-Fe2O3 Nano-spheres are immobilized on the surface of Manganese Pyrophosphate (Mn2P2O7) support using Forced Hydrolysis and Reflux Condensation (FHRC) method. Products were characterized by FTIR, SEM, BET EDX, and XRD. The photocatalytic activity of α-Fe2O3/Mn2P2O7 was investigated for the removal of Toluene in aqueous solution by UV/H2O2 system. The chemical oxygen demand (COD) measurements were used to determine the amount of Toluene removal. The experiments were designed based on four affecting variables including pH, catalyst content, initial Toluene concentration and H2O2 at three levels using Box-Behnken experimental design. The results of this study showed that α-Fe2O3/Mn2P2O7 as a new photo catalyst has a higher photocatalytic activity than α-Fe2O3 nanoparticles. Based on the achieved results, the maximum degradation efficiency was 97.14% in optimal conditions. Manuscript profile
      • Open Access Article

        2 - Modeling the degradation of Sunset Yellow FCF azo dye by Fe2O3/Bentonite catalyst using artificial neural networks
        Mohammad Ehsan Mosayebian Reza Moradi Kazem Mahanpoor
        In this paper, the precipitation method has been used to stabilize Fe2O3 particleson Bentonite zeolite (BEN). Fe2O3/BEN catalysts have been characterized byscanning electron microscopy (SEM), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET) surface area analysi More
        In this paper, the precipitation method has been used to stabilize Fe2O3 particleson Bentonite zeolite (BEN). Fe2O3/BEN catalysts have been characterized byscanning electron microscopy (SEM), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET) surface area analysis. Artificial neural network (ANN)was used for modeling the photocatalytic degradation of Sunset Yellow FCF(SYF) azo dye in aqueous solution under irradiation in the batch photoreactor.The parameters including pH, catalyst amount, dye concentration and H2O2concentration was applied as input; the output of the network was degradationpercentage. Modeling the results of the photocatalytic degradation of dye using afeed-forward, backpropagation three-layer network, topology (4:7:1) with fourneurons in the input layer, seven neurons in the hidden layer, and one neuron inthe output layer was used. Comparison between data obtained from ANN andexperimental data indicated that the proposed ANN model provides reasonablepredictive performance. The optimum conditions were as follows: pH= 4, catalystamount=60 mg/L, dye concentration =50 ppm and H2O2 concentration =32ppm. The chemical oxygen demand (COD) analysis of the dye under optimumconditions showed a 91% reduction in 80 min period. Manuscript profile
      • Open Access Article

        3 - Employing α-Fe2O3 /Mn2P2O7 as a nano photocatalyst for degradation of toluene in aqueous environment
        Sajjad Mafi Kazem Mahanpoor
        In this study, α-Fe2O3 nano-spheres are immobilized on the surface of manganese pyrophosphate(Mn2P2O7) support using forced hydrolysis and reflux condensation (FHRC) method. The synthesizedα-Fe2O3/Mn2P2O7 were characterized by FTIR, SEM, BET EDX, and XRD. Th More
        In this study, α-Fe2O3 nano-spheres are immobilized on the surface of manganese pyrophosphate(Mn2P2O7) support using forced hydrolysis and reflux condensation (FHRC) method. The synthesizedα-Fe2O3/Mn2P2O7 were characterized by FTIR, SEM, BET EDX, and XRD. The photocatalytic activity fromα-Fe2O3/Mn2P2O7 was investigated for the removal of toluene in aqueous solution by UV/H2O2 system. Thechemical oxygen demand (COD) measurements were used to determine the amount of toluene removal.The experiments were designed based on four affecting variables, including pH, catalyst content, initialtoluene concentration and H2O2 at three levels using Box-Behnken experimental design. The results ofthis study showed that α-Fe2O3/Mn2P2O7 as a new photocatalyst has a higher photocatalytic activity thanα-Fe2O3 nanoparticles. Based on the achieved results, the maximum degradation efficiency was 97.14%in optimal conditions. Manuscript profile