PVA and EDTA grafted superparamagnetic Ni doped iron oxide nanoparticles prepared by constant current electrodeposition for biomedical applications

Mustafa Aghazadeh ¹ ( Materials and Nuclear Research School, Nuclear Science and Technology Research Institute (NSTRI), P.O. Box 14395-834, Tehran, Iran )
Isa Karimzadeh ² ( Department of Physics, Faculty of Science, Central Tehran Branch, Islamic Azad University, Tehran, Iran )
Mohammad Reza Ganjali ³ ( Center of Excellence in Electrochemistry, University of Tehran, Tehran, Iran )

Submited date : 2018-10-09 Accepted date : 2019-05-18

Keywords: Iron Oxide, Ni doping, Surface Grafting, Nanoparticles, Electrochemical synthesis,

Abstract :

In this paper, a rapid and room temperature electrochemical method is introduced for preparation of Ni doped iron oxide nanoparticles (Ni-IONs) grafted with ethylenediaminetetraacetic acid (EDTA) and polyvinyl alcohol (PVA). EDTA/Ni-IONs and PVA/Ni-IONs samples were prepared through base electro-generation on the cathode surface from aqueous solution of iron(II) chloride, iron(III) nitrate and nickel chloride salts with EDTA/PVA additive. Uniform and narrow particle size Ni-IONs with an average diameter of 15 nm was achieved. Ni doping into the crystal structure of synthesized IONs and also surface grafting with EDTA/or PVA were established through FT-IR and EDAX analyses. The saturation magnetization values for the resulting EDTA/Ni-IONs and PVA/Ni-IONs were found to be 38.03 emu/g and 33.45 emu/g, respectively, which proved their superparamagnetic nature in the presence of applied magnetic field. The FE-SEM observations, XRD and VSM data confirmed the suitable size, crystal structure and magnetic properties of the prepared samples for uses in biomedical aims