Adsorption Features Remove a Toxic Dye from an Aqueous Solution by a Cost-effective Palm Leaf Activated Carbon (PLAC)

Subject Areas : Journal of Chemical Health Risks

Ali M. Mohammed ¹ , Aseel M. Aljeboree ² , Ahmed B. Mahdi ³ , Yasir Salam Karim ⁴ , Mohammed Abed Jawad ⁵ , Ayad F. Alkaim ⁶

1 - Department of Chemistry, College of Sciences for Girls, University of Babylon, Hilla, Iraq
2 - Department of Chemistry, College of Sciences for Girls, University of Babylon, Hilla, Iraq
3 - Anesthesia Techniques Department, Al-Mustaqbal University College, Babylon, Iraq
4 - Al-Manara College For Medical Sciences, Maysan, Iraq
5 - Al-Nisour University College, Baghdad, Iraq
6 - Department of Chemistry, College of Sciences for Girls, University of Babylon, Hilla, Iraq

Received: 2021-09-10 Accepted : 2022-01-05 Published : 2022-09-01

Keywords: Activated Carbon, Kinetics, Adsorption, Isotherm, Thermodynamics, Dye,

Abstract :

This research addressed the elimination of the dye Congo red (CR) from an aqueous solution utilizing dried palm leaf activated carbon (PLAC). Therefore, we performed batch experiments for isotherms and sorption kinetics. According to the experimental data, the adsorption method largely depends on the equilibrium time, initial concentration of dye, pH solution, and adsorbent amount. We observed sorption equilibrium for the dye Congo red via PLAC in 60 min and an adsorption capacity of 52.1 mg g-1. A pseudo-first-order kinetic model was followed by sorption kinetics, whereas the Langmuir isotherm has been proposed to be help reache the equilibrium factor. The above data demonstrated that PLAC is an effective, low-cost, and environmentally friendly biomaterial for removing the dye from the aqueous solution.

References:

1. Gouamid M., Bensaci M.B., 2013 Adsorption Equilibrium, Kinetics and Thermodynamics of Methylene Blue from Aqueous Solutions using Date Palm Leaves. Energy Procedia. 36, 898-907.


2. Heloise B. , Quesada A., Fernando C., Daiana S., Charleston B., 2019. Surface water pollution by pharmaceuticals and an alternative of removal by low-cost adsorbents: A review. Chemosphere. 222,766e780.


3. Hoppen M.I., Carvalho K. Q., Ferreira R.C., Passig F.H., Pereira I.C., Rizzo-Domingues R.C.P., Lenzi M.K., Bottini R.C.R., 2019. Adsorption and desorption of acetylsalicylic acid onto activated carbon of babassu coconut mesocarp. Journal of Environmental Chemical Engineering. 7, 102862.


4. Hadi Z.A., Aljeboree A.M., Alkaim A.F., 2014. Adsorption of a cationic dye from aqueous solutions by using waste glass materials: Isotherm and thermodynamic studies. International Journal of Chemical Sciences. 12, 1273-1288.


5. Karimi S., Tavakkoli Y., Karri R., 2019. A comprehensive review of the adsorption mechanisms and factors influencing the adsorption process from the perspective of bioethanol dehydration. Renewable and Sustainable Energy Reviews. 107, 535-553.


6. Aljeboree A.M., Alkaim A.F., 2019. Removal of Antibiotic Tetracycline (TCs) from aqueous solutions by using Titanium dioxide (TiO₂) nanoparticles as an alternative material. Journal of Physics: Conf. Series 1294 052059.


7. Kamil A.M., Mohammed H.T., Alkaim A.F., Hussein F.H., 2016 Adsorption of Congo red on multiwall carbon nanotubes: Effect of operational parameters. Journal of Chemical and Pharmaceutical Sciences. 9, 1128-1133.


8. Aljeboree A.M., Alkaim A.F., 2019. Role of plant wates as an ecofriendly for pollutants (crystal violet dye) removal from aqueous solutions. Plant Archives. 19, 902-905.


9. Kamil A.M., Mohammed H.T., Alkaim A.F., Hussein F.H., 2016. Adsorption of Congo red on multiwall carbon nanotubes: Effect of operational parameters. Journal of Chemical and Pharmaceutical Sciences. 9, 1128-1133.


10. Aljeboree A.M., Alshirifi A.N., Alkaim A.F., 2019. Activated carbon (as a waste plant source) – clay micro/nanocomposite as effective adsorbent: process optimization for ultrasound-assisted adsorption removal of amoxicillin drug. Plant Archives. 19, 915-919.


11. Enas M.A., Abrar M.A., Aseel M.A., Ayad F.A., Falah H.H., 2017 .Investigation of photocatalytic removal and photonic efficiency of maxilon blue dye GRL in the presence of TiO₂ nanoparticles. Particulate Science and Technology. 35, 14-20.


12. Mohammed A.J., Abed J.K., Nadher D.R., 2021 .Role of Sodium Alginate-g-poly (Acrylic acid-fumaric acid) Hydrogel for Removal of Pharmaceutical Paracetamol from Aqueous Solutions by Adsorption. International Journal of Pharmaceutical Quality Assurance. 12, 202-205.


13. Gecgel U., 2012 Adsorption of Remazol Brilliant Blue R on activated carbon prepared from a pine cone. Nat Prod Res. 26, 659-664.


14. Yahya A.F., Nadher D.R., 2021. Removal of Metformin hydrochloride from Aqueous Solutions by using Carboxymethyl cellulose-g-poly(acrylic acid-co-acrylamide) Hydrogel: Adsorption and Thermodynamic Studies. IOP Conf. Series: Earth and Environmental Science. 790, 012062.


15. Aseel M.A, Ayad F.A., Ali loay, Hanadi M.A., 2019 .Photocatalytic Degradation of Textile Dye Cristal Violet Wastewater using Zinc Oxide as a Model of Pharmaceutical Threat Reductions. Journal of Global Pharma Technology. 11, 138-143.


16. LiQ., Yue Q., Su Y., Gao B., SunH., 2010. Equilibrium, thermodynamics and process design to minimize adsorbent amount for the adsorption of acid dyes onto cationic polymer-loaded bentonite. Chem Eng J. 158, 489-497.


17. Banerjee S., Chattopadhyaya M.C., 2017 .Adsorption characteristics for the removal of a toxic dye, tartrazine from aqueous solutions by a low cost agricultural by-product. Arabian Journal of Chemistry. 10, S1629-S1638.


18. Aljeboree A.M., Alshirifi A.N., Alkaim A.F., 2020. Removal of amoxicillin drug onto nano composites surface using ultrasound assistance. Plant Archives. 20, 3135-3140.


19. Layth S.J., Aljeboree M.A., 2021. Removal of Heavy Metals by Using Chitosan/ Poly (Acryl Amide-Acrylic Acid)Hydrogels: Characterization and Kinetic Study . Neuro Quantology. 19, 31-37.


20. Langmuir I., 1918 Adsorption of gases on plain surfaces of glass mica platinum. J Am Chem Soc. 40. 1361-1403.


21. Adeyemo A.A., Adeoye I.O., Bello O.S., 2017. Adsorption of dyes using different types of clay: a review. Appl Water Sci. 7, 543-568.


22. Ayad F.A., Aseel M.A., 2020 White Marble as an Alternative Surface for Removal of Toxic Dyes (Methylene Blue) from Aqueous Solutions. International Journal of Advanced Science and Technology. 29, 5470 - 5479.


23. Luo X., 2019. Facile synthesis and low concentration tylosin adsorption performance of chitosan/cellulose nanocomposite microspheres. Carbohydrate Polymers. 206, 633-640.


24. Ahmed M.J., 2020. Adsorption of quinolone, tetracycline, and penicillin antibiotics from aqueous solution using activated carbons: Review. Environmental Toxicology and Pharmacology. 50, 1-10.