امکان پذیری جذب فلزات سنگین نیکل، مس و کادمیوم با نانوزئولیت
محورهای موضوعی :
فلزات سنگین
حسین کامران حقیقی
1
,
مهدی ایران نژاد
2
1 - دانشکده مهندسی معدن، دانشگاه صنعتی امیرکبیر، تهران، ایران.*(مسوول مکاتبات)
2 - دانشکده مهندسی معدن، دانشگاه صنعتی امیرکبیر، تهران، ایران
تاریخ دریافت : 1402/08/11
تاریخ پذیرش : 1402/09/22
تاریخ انتشار : 1402/10/01
کلید واژه:
فلزات سنگین,
آسیای سیاره‌ای,
نانوزئولیت,
جذب,
چکیده مقاله :
زمینه و هدف: در این مقاله تهیه نانو ذرات زئولیت با استفاده از آسیای سیاره‌ای در زمان‌های مختلف انجام شد. همچنین از سدیم هگزا متا فسفات به عنوان متفرق کننده در خردایش زئولیت استفاده شد. در ادامه، نانوذرات زئولیت تهیه شده برای حذف فلزات سنگین نیکل، مس و کادمیوم از پساب‌های مصنوعی در سیستم ناپیوسته بکار گرفته شد.
روش بررسی: در مطالعه حاضر، نخست تغییرات اراضی جنگلی منطقه گرگان در بازه زمانی 20 ساله تعیین و سپس، مدل سازی این تغییرات با استفاده از مدل Geomod اجرا گردید. به این منظور، نقشه های کاربری زمین بازه های مطالعاتی با استفاده از تصاویر ماهواره ای تهیه و آشکارسازی تغییرات با روش مقایسه پس از طبقه‌بندی انجام شد. سپس، مدل Geomod برای مدل سازی تغییرات اراضی جنگلی اجرا گردید.
روش بررسی: در این مقاله به کمک آسیای گلوله‌ای و سیاره‌ای اقدام به تولید نانوزئولیت کرده و در ادامه در آزمایش‌های جذب امکان بهبود حذف یون‌ها توسط ماده تولیدی بررسی می‌شود. آزمایش‌های جذب به صورت ناپیوسته در شرایط آزمایشی متغیر مورد مطالعه قرار گرفته و در نهایت اثر سدیم هگزا متا فسفات بر جذب فلزات سنگین نیکل، مس و کادمیوم نشان داده می‌شود.
یافته ها: بررسی تاثیر سدیم هگزا متا فسفات بر خردایش و جذب فلزات سنگین توسط نانوزئولیت نشان داد که استفاده از سدیم هگزامتا فسفات منجر به کاهش مصرف انرژی در خردایش شده و تاثیر مثبت بر حذف فلزات نیکل و کادمیوم توسط نانوزئولیت داشته است.
بحث و نتیجه گیری: تاثیر سدیم هگزا متا فسفات سدیم بر روی جذب فلزات نیکل، کادمیوم و مس نشان داد که این ماده تاثیر مثبت بر جذب یون‌های نیکل و کادمیوم بر ذرات نانوزئولیت داشته اما هیچ گونه تاثیری بر جذب یون مس نداشته است.نانو‌زئولیت‌ها بدلیل داشتن ذرات با اندازه نانو دارای مساحت سطح خارجی بزرگتر بوده و طول نفوذ کمتری برخوردارند بنابراین ظرفیت جذب آن‌ها بسیار بالا می‌باشد.
چکیده انگلیسی:
Background and Objective: In this paper, the preparation of nano zeolite was carried out at different grinding times using a dry planetary ball mill. Sodium Hexa Meta Phosphate (SHMP) was introduced as the dispersant in the milling of natural zeolite adsorbent. In the next step, to remove and adsorb heavy metal ions such as nickel, copper, and cadmium, the application of nano zeolite was studied in batch mode.
Material and Methodology: In this paper, zeolite nanoparticles were produced using planetary and ball mills. Adsorption experiments were conducted to investigate the adsorption of nickel, copper, and cadmium using new nano zeolite adsorbent.
Findings: The effect of Sodium Hexa Meta Phosphate (SHMP) on grinding and adsorption of ion metals by nano zeolite was investigated and results showed that the application of SHMP led to lower energy consumption in grinding and had a positive effect on nickel and cadmium removal from aqueous solution by nano zeolite particles.
Discussion and Conclusions: The effect of sodium hexametaphosphate on the absorption of nickel, cadmium, and copper metals showed that this reagent had a positive effect on the absorption of nickel and cadmium ions on nanozeolite particles, but it did not affect the absorption of copper ions. Nano-zeolites have a larger external surface area and a shorter diffusion path length due to having nano-sized particles, so their absorption capacity is very high.
منابع و مأخذ:
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Misihairabgwi JM, Kasiyamhuru A, Anderson P, Cunningham CJ, Peshkur TA, Ncube I. Adsorption of heavy metals by agroforestry waste derived activated carbons applied to aqueous solutions. African Journal of Biotechnology. 2015; 13(14).
Maheshwari U, Gupta S. A novel method to identify optimized parametric values for adsorption of heavy metals from waste water. Journal of Water Process Engineering. 2016; 9 21-26.
Kushwaha AK, Gupta N, Chattopadhyaya M. Adsorption behavior of lead onto a new class of functionalized silica gel. Arabian Journal of Chemistry. 2012.
Kalantari K, Ahmad MB, Fard Masoumi HR, Shameli K, Basri M, Khandanlou R. Rapid and high capacity adsorption of heavy metals by Fe3O4/montmorillonite nanocomposite using response surface methodology: Preparation, characterization, optimization, equilibrium isotherms, and adsorption kinetics study. Journal of the Taiwan Institute of Chemical Engineers. 2015;49:192-198.
Asokbunyarat V, van Hullebusch ED, Lens PN, Annachhatre AP, editors. Adsorption of Heavy metals from Acid Mine Drainage by Coal Bottom Ash. 4th International Conference on Research Frontiers in Chalcogen Cycle Science & Technology; 2015.
Amadou I, Faucon M-P, Houben D. New insights into sorption and desorption of organic phosphorus on goethite, gibbsite, kaolinite and montmorillonite. Applied Geochemistry. 2022;143:105378.
Zhou K, Liu Y, Yang Z, Xie T, Liu H, Zhong C. Adsorptive removal of heavy metals by a bio-based polymeric material PAO-CI from wastewater. Journal of the Taiwan Institute of Chemical Engineers. 2016;61:342-50.
Wen J, Yi Y, Zeng G. Effects of modified zeolite on the removal and stabilization of heavy metals in contaminated lake sediment using BCR sequential extraction. Journal of environmental management. 2016;178:63-69.
Kim IH, Choi J-H, Joo JO, Kim Y-K, Choi J-W, Oh B-K. Development of a Microbe-Zeolite Carrier for the Effective Elimination of Heavy Metals from Seawater. Journal of microbiology and biotechnology. 2015;25(9):1542-146.
Andrejkovičová S, Sudagar A, Rocha J, Patinha C, Hajjaji W, da Silva EF, et al. The effect of natural zeolite on microstructure, mechanical and heavy metals adsorption properties of metakaolin based geopolymers. Applied Clay Science. 2016;126:141-152.
Kim HS, Kim YH, Baek KT, Lim WT. Characterization of Natural Zeolite and Study of Adsorption Properties of Heavy Metal Ions for Development of Zeolite Mine. Journal of the Mineralogical Society of Korea. 2015;28(4):299-308.
Ltaief OO, Siffert S, Fourmentin S, Benzina M. Synthesis of Faujasite type zeolite from low grade Tunisian clay for the removal of heavy metals from aqueous waste by batch process: Kinetic and equilibrium study. Comptes Rendus Chimie. 2015;18(10):1123-1133.
Mehdipourghazi M, Moheb A, Kazemian H. Incorporation of boron into nano-size MFI zeolite structure using a novel microwave-assisted two-stage varying temperatures hydrothermal synthesis. Microporous and Mesoporous Materials. 2010;136(1–3):18-24.
Jarosz R, Szerement J, Gondek K, Mierzwa-Hersztek M. The use of zeolites as an addition to fertilisers–A review. Catena. 2022;213:106125.
Wang L, Yang W, Xin C, Ling F, Sun W, Fang X, et al. Synthesis of nano-zeolite IM-5 by hydrothermal method with the aid of PEG and CTAB. Materials Letters. 2012;69:16-19.
Charkhi A, Kazemian H, Kazemeini M. Optimized experimental design for natural clinoptilolite zeolite ball milling to produce nano powders. Powder Technology. 2010;203(2):389-396.
Visa M. Synthesis and characterization of new zeolite materials obtained from fly ash for heavy metals removal in advanced wastewater treatment. Powder Technology. 2016;294:338-347.
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Jo C, Lee S, Cho SJ, Ryoo R. Inside Back Cover: Synthesis of Silicate Zeolite Analogues Using Organic Sulfonium Compounds as Structure‐Directing Agents (Angew. Chem. Int. Ed. 43/2015). Angewandte Chemie International Edition. 2015;54(43):12823.
Hernández-Rodríguez M, Jordá JL, Rey F, Corma A. Synthesis and structure determination of a new microporous zeolite with large cavities connected by small pores. Journal of the American Chemical Society. 2012;134(32):13232-13235.
Irannajad M, Kamran Haghighi H. Removal of Heavy Metals from Polluted Solutions by Zeolitic Adsorbents: a Review. Environmental Processes. 2021;8(1):7-35.
Šiljeg M, Stefanović ŠC, Mazaj M, Tušar NN, Arčon I, Kovač J, et al. Structure investigation of As(III)- and As(V)-species bound to Fe-modified clinoptilolite tuffs. Microporous and Mesoporous Materials. 2009;118(1–3):408-415.
Mukhtar N, Borhan M, Rusop M, Abdullah S, editors. Effect of Milling Time on Particle Size and Surface Morphology of Commercial Zeolite by Planetary Ball Mill. Advanced Materials Research; 2013: Trans Tech Publ.
Burris LE, Juenger MC. Milling as a pretreatment method for increasing the reactivity of natural zeolites for use as supplementary cementitious materials. Cement and Concrete Composites. 2016;65:163-170.
Kamran Haghighi H, Irannajad M, MohammadJafari A. Thermodynamic and kinetic studies of heavy metal adsorption by modified nano-zeolite. Geosystem Engineering. 2021; 24(2): 101-113.
Akçay K, Sirkecioğlu A, Tatlıer M, Savaşçı ÖT, Erdem-Şenatalar A. Wet ball milling of zeolite HY. Powder Technology. 2004;142(2–3):121-128.
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Bhattacharyya KG, Gupta SS. Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite: A review. Advances in Colloid and Interface Science. 2008;140(2):114-131.
Yang J, Wei W, Pi S, Ma F, Li A, Wu D, et al. Competitive adsorption of heavy metals by extracellular polymeric substances extracted from Klebsiella sp. J1. Bioresource technology. 2015;196:533-539.
Wang X, Pei Y, Lu M, Lu X, Du X. Highly efficient adsorption of heavy metals from wastewaters by graphene oxide-ordered mesoporous silica materials. Journal of Materials Science. 2015;50(5):2113-2121.
Misihairabgwi JM, Kasiyamhuru A, Anderson P, Cunningham CJ, Peshkur TA, Ncube I. Adsorption of heavy metals by agroforestry waste derived activated carbons applied to aqueous solutions. African Journal of Biotechnology. 2015; 13(14).
Maheshwari U, Gupta S. A novel method to identify optimized parametric values for adsorption of heavy metals from waste water. Journal of Water Process Engineering. 2016; 9 21-26.
Kushwaha AK, Gupta N, Chattopadhyaya M. Adsorption behavior of lead onto a new class of functionalized silica gel. Arabian Journal of Chemistry. 2012.
Kalantari K, Ahmad MB, Fard Masoumi HR, Shameli K, Basri M, Khandanlou R. Rapid and high capacity adsorption of heavy metals by Fe3O4/montmorillonite nanocomposite using response surface methodology: Preparation, characterization, optimization, equilibrium isotherms, and adsorption kinetics study. Journal of the Taiwan Institute of Chemical Engineers. 2015;49:192-198.
Asokbunyarat V, van Hullebusch ED, Lens PN, Annachhatre AP, editors. Adsorption of Heavy metals from Acid Mine Drainage by Coal Bottom Ash. 4th International Conference on Research Frontiers in Chalcogen Cycle Science & Technology; 2015.
Amadou I, Faucon M-P, Houben D. New insights into sorption and desorption of organic phosphorus on goethite, gibbsite, kaolinite and montmorillonite. Applied Geochemistry. 2022;143:105378.
Zhou K, Liu Y, Yang Z, Xie T, Liu H, Zhong C. Adsorptive removal of heavy metals by a bio-based polymeric material PAO-CI from wastewater. Journal of the Taiwan Institute of Chemical Engineers. 2016;61:342-50.
Wen J, Yi Y, Zeng G. Effects of modified zeolite on the removal and stabilization of heavy metals in contaminated lake sediment using BCR sequential extraction. Journal of environmental management. 2016;178:63-69.
Kim IH, Choi J-H, Joo JO, Kim Y-K, Choi J-W, Oh B-K. Development of a Microbe-Zeolite Carrier for the Effective Elimination of Heavy Metals from Seawater. Journal of microbiology and biotechnology. 2015;25(9):1542-146.
Andrejkovičová S, Sudagar A, Rocha J, Patinha C, Hajjaji W, da Silva EF, et al. The effect of natural zeolite on microstructure, mechanical and heavy metals adsorption properties of metakaolin based geopolymers. Applied Clay Science. 2016;126:141-152.
Kim HS, Kim YH, Baek KT, Lim WT. Characterization of Natural Zeolite and Study of Adsorption Properties of Heavy Metal Ions for Development of Zeolite Mine. Journal of the Mineralogical Society of Korea. 2015;28(4):299-308.
Ltaief OO, Siffert S, Fourmentin S, Benzina M. Synthesis of Faujasite type zeolite from low grade Tunisian clay for the removal of heavy metals from aqueous waste by batch process: Kinetic and equilibrium study. Comptes Rendus Chimie. 2015;18(10):1123-1133.
Mehdipourghazi M, Moheb A, Kazemian H. Incorporation of boron into nano-size MFI zeolite structure using a novel microwave-assisted two-stage varying temperatures hydrothermal synthesis. Microporous and Mesoporous Materials. 2010;136(1–3):18-24.
Jarosz R, Szerement J, Gondek K, Mierzwa-Hersztek M. The use of zeolites as an addition to fertilisers–A review. Catena. 2022;213:106125.
Wang L, Yang W, Xin C, Ling F, Sun W, Fang X, et al. Synthesis of nano-zeolite IM-5 by hydrothermal method with the aid of PEG and CTAB. Materials Letters. 2012;69:16-19.
Charkhi A, Kazemian H, Kazemeini M. Optimized experimental design for natural clinoptilolite zeolite ball milling to produce nano powders. Powder Technology. 2010;203(2):389-396.
Visa M. Synthesis and characterization of new zeolite materials obtained from fly ash for heavy metals removal in advanced wastewater treatment. Powder Technology. 2016;294:338-347.
Li J, Corma A, Yu J. Synthesis of new zeolite structures. Chemical Society Reviews. 2015;44(20):7112-7127.
Jo C, Lee S, Cho SJ, Ryoo R. Inside Back Cover: Synthesis of Silicate Zeolite Analogues Using Organic Sulfonium Compounds as Structure‐Directing Agents (Angew. Chem. Int. Ed. 43/2015). Angewandte Chemie International Edition. 2015;54(43):12823.
Hernández-Rodríguez M, Jordá JL, Rey F, Corma A. Synthesis and structure determination of a new microporous zeolite with large cavities connected by small pores. Journal of the American Chemical Society. 2012;134(32):13232-13235.
Irannajad M, Kamran Haghighi H. Removal of Heavy Metals from Polluted Solutions by Zeolitic Adsorbents: a Review. Environmental Processes. 2021;8(1):7-35.
Šiljeg M, Stefanović ŠC, Mazaj M, Tušar NN, Arčon I, Kovač J, et al. Structure investigation of As(III)- and As(V)-species bound to Fe-modified clinoptilolite tuffs. Microporous and Mesoporous Materials. 2009;118(1–3):408-415.
Mukhtar N, Borhan M, Rusop M, Abdullah S, editors. Effect of Milling Time on Particle Size and Surface Morphology of Commercial Zeolite by Planetary Ball Mill. Advanced Materials Research; 2013: Trans Tech Publ.
Burris LE, Juenger MC. Milling as a pretreatment method for increasing the reactivity of natural zeolites for use as supplementary cementitious materials. Cement and Concrete Composites. 2016;65:163-170.
Kamran Haghighi H, Irannajad M, MohammadJafari A. Thermodynamic and kinetic studies of heavy metal adsorption by modified nano-zeolite. Geosystem Engineering. 2021; 24(2): 101-113.
Akçay K, Sirkecioğlu A, Tatlıer M, Savaşçı ÖT, Erdem-Şenatalar A. Wet ball milling of zeolite HY. Powder Technology. 2004;142(2–3):121-128.
