Application of Triphenylphosphine for Facile Synthesis of Several Alkyl Acrylates from Heterocyclic Phenols

Mohtat, Bita; Djahaniani, Hoorieh

Manuscript ID : 518069 Visit : 168 Page: 111 - 115

20.1001.1.20083815.2016.10.1.12.6

Article Type: Original Research

Application of Triphenylphosphine for Facile Synthesis of Several Alkyl Acrylates from Heterocyclic Phenols

Subject Areas : Polymer

Bita Mohtat ¹ , Hoorieh Djahaniani ²

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Received: 2015-12-28 Accepted : 2015-12-28 Published : 2016-01-01

Keywords:

Abstract :

7-Hydroxycoumarine undergoes a smooth reaction with alkyl propiolates in the presence of triphenylphosphine (15 mol%) to produce the corresponding alkyl (E)-3-((2-oxo-2H-chromen- 7-yl)oxy)acrylate in good yields. When the reaction was performed by 3-hydroxyquinoline similar alkyl acrylates were obtained.

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Application of Triphenylphosphine for Facile Synthesis of Several Alkyl Acrylates from Heterocyclic Phenols