Synthesis of Some Nitrogen Functional Derivatives of 5-substituted-6-azauracil as Biologically Active Compounds

Kabirifard, Hassan; Alimardani, Zeinab; Ataeimehr, Natasha; Rezai, Gisa

Manuscript ID : 516209 Visit : 223 Page: 57 - 63

20.1001.1.20083815.2013.7.1.6.9

Article Type: Original Research

Synthesis of Some Nitrogen Functional Derivatives of 5-substituted-6-azauracil as Biologically Active Compounds

Subject Areas : Polymer

Hassan Kabirifard ¹ , Zeinab Alimardani ² , Natasha Ataeimehr ³ , Gisa Rezai ⁴

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Received: 2015-11-16 Accepted : 2015-11-16 Published : 2013-01-01

Keywords:

Abstract :

3-Arylhydrazono-2,4-dioxo-4-phenylbutanoates have been prepared by the coupling of benzoylpyruvate with aryldiazonium chlorides. Reactions of the 3-arylhydrazono-2,4- dioxo-4-phenylbutanoates with 1-aminoguanidine, semicarbazide, and thiosemicarbazide gave 5-substituted 2-imino-6-azauracil (3a), 6-azauracil (3b), and 2-thio-6-azauracil (3c), respectively. The analytical data of these compounds - IR, 1 H, and 13C NMR spectral data - are reported.

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Synthesis of Some Nitrogen Functional Derivatives of 5-substituted-6-azauracil as Biologically Active Compounds