Synthesis of Functionalized Aryl-vinyl Ethers as Building Blocks and Auxiliaries in Organic Synthesis

Mohtat, B.; Pirhadi, L.; Azimzadeh, S.; Djahaniani, H.

Manuscript ID : 516240 Visit : 228 Page: 46 - 52

20.1001.1.20083815.2012.6.3.5.5

Article Type: Original Research

Synthesis of Functionalized Aryl-vinyl Ethers as Building Blocks and Auxiliaries in Organic Synthesis

Subject Areas : Polymer

B. Mohtat ¹ , L. Pirhadi ² , S. Azimzadeh ³ , H. Djahaniani ⁴

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Received: 2015-11-17 Accepted : 2015-11-17 Published : 2012-07-01

Keywords:

Abstract :

5- hydroxyisoquinoline undergoes a smooth reaction with alkyl propiolates in the presence of triphenylphosphine (15 mol%) to produce the corresponding (E)-alkyl 3-(isoquinolin-5-yloxy) acrylate in good yields. When the reaction was performed by 2-methyl 4-hydroxyquinoline and 3-nitro 4-hydroxypyridine, similar aryl vinyl ethers were obtained.

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Synthesis of Functionalized Aryl-vinyl Ethers as Building Blocks and Auxiliaries in Organic Synthesis