LaCo0.5Fe0.5O3 Nanoparticles as a Highly Efficient Adsorbent for Rapid Removal of Trypan Blue Dye From Aqueous Media

Subject Areas : Polymer

Mojtaba Ershadi ¹ , Haman Tavakkoli ² , Arezoo Ghaemi ³ , Afruz Azarkish ⁴

1 - Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran
2 - Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran
3 - Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran
4 - Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran

Received: 2017-12-24 Accepted : 2017-12-24 Published : 2018-01-01

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Abstract :

Nanoparticles of perovskite-type LaCo0.5Fe0.5O3 (LCFO) were fabricated by sol–gel method.Thermal decomposition process of the complex precursor was examined by means of differentialthermal analysis–thermal gravimetric analysis (DTA/TGA). X-ray diffraction (XRD) resultsshowed that single perovskite phase has been completely formed after calcination at 750 °C. Inaddition, the surface morphology and composition of these nanopowders were also investigatedusing SEM and EDX. These nanoparticles showed the excellent adsorption efficiency towardsTrypan Blue (TB) as a reactive dye in aqueous solution. The adsorption studies were carried outat different pH values, dye concentrations, various adsorbent dosages and contact time in a batchexperiments. LCFO exhibited good dye removal efficiency at acidic pH specially pH 2.Experimental results indicated that the adsorption kinetic data follow a pseudo-second-order ratefor tested dye. The isotherm evaluations revealed that the Freundlich model better fits to theexperimental equilibrium data than Langmuir the model.