Investigation of the Reduced Graphene Oxide Effect on the Concrete Strength, Impedance and Corrosion Resistance of Rebar Inside
Subject Areas : Applied Chemistryfateme abdi 1 , Houdhyar Eimani Kalesar 2
1 - Department of Enginieering Sciences, Faculty of Advanced Technologies, University of Mohaghegh Ardabili, Namin, Iran
2 - Deptartment of Civil Engineering, Faculty of Engineering, University of Mohaghegh-Ardebili, Ardebil, Iran
Keywords: Reduced graphene oxide, Compressive strength, Corrosion, Impedance, EIS.,
Abstract :
In this work, to investigate the effect of reduced Graphene Oxide nanoparticles on the strength of concrete and the corrosion resistance of rebar inside it, Graphene Oxide nanoparticles were added to the mortar with different weight percentages of cement. The strength of concrete was evaluated by measuring the compressive strength of 7 days and 28 days and comparing with the results of the control sample. To investigate the effect of reduced Graphene Oxide nanoparticles on the corrosion resistance of rebar inside it, polarization and EIS tests were performed in a 3.5% salt solution. The results showed that the addition of reduced Graphene Oxide nanoparticles increases the compressive strength and electrical impedance of the concrete. It was also found that there is an optimal value that the addition of Graphene Oxide nanoparticles more than that value causes a relative decrease in concrete strength and electrical impedance. Finally, by simulating the equivalent circuit, the reason for the decrease in impedance and as a result the corrosion resistance by adding more than the optimal value was investigated.
1. Zhang P, Su J, Guo J, Hu S. Influence of carbon nanotube on properties of concrete: A
review. Construction and Building Materials. 2023 Mar 10;369:130388.
2. Nayak CB, Taware PP, Jagadale UT, Jadhav NA, Morkhade SG. Effect of SiO2 and
ZnO nano-composites on mechanical and chemical properties of modified concrete. Iranian
Journal of Science and Technology, Transactions of Civil Engineering. 2022 Apr;46(2):1237-
47.
3. Bica BO, de Melo JV. Concrete blocks nano-modified with zinc oxide (ZnO) for
photocatalytic paving: Performance comparison with titanium dioxide (TiO2). Construction
and Building Materials. 2020 Aug 20;252:119120.
4. Reshma TV, Manjunatha M, Bharath A, Tangadagi RB, Vengala J, Manjunatha LR.
Influence of ZnO and TiO2 on mechanical and durability properties of concrete prepared with
and without polypropylene fibers. Materialia. 2021 Aug 1;18:101138.
F. Abdi, et al., J. Appl. Chem. Res., 18, 2, 8-26 (2024)
24
5. Nazari A, Riahi S, Riahi S, Shamekhi SF, Khademno A. Benefits of Fe2O3
nanoparticles in concrete mixing matrix. Journal of American Science. 2010;6(4):102-6.
6. Nazari A, Riahi S, Riahi S, Shamekhi SF, Khademno A. The effects of incorporation
Fe2O3 nanoparticles on tensile and flexural strength of concrete. Journal of American Science.
2010;6(4):90-3.
7. Elia H, Ghosh A, Akhnoukh AK, Nima ZA. Using nano-and micro-titanium dioxide
(TiO2) in concrete to reduce air pollution. J. Nanomed. Nanotechnol. 2018;9(3):3-7.
8. Sastry KG, Sahitya P, Ravitheja A. Influence of nano TiO2 on strength and durability
properties of geopolymer concrete. Materials Today: Proceedings. 2021 Jan 1;45:1017-25.
9. Nazari A, Riahi S, Riahi S, Shamekhi SF, Khademno A. Influence of Al2O3
nanoparticles on the compressive strength and workability of blended concrete. Journal of
American Science. 2010;6(5):6-9.
10. Nazari A, Riahi S. Improvement compressive strength of concrete in different curing
media by Al2O3 nanoparticles. Materials Science and Engineering: A. 2011 Jan
25;528(3):1183-91.
11. Nazari A, Riahi S. Effects of CuO nanoparticles on compressive strength of selfcompacting concrete. Sādhanā. 2011 Jun;36(3):371-91.
12. Nazari A, Riahi S, Riahi S, Shamekhi SF, Khademno A. An investigation on the
Strength and workability of cement based concrete performance by using ZrO2 nanoparticles.
Journal of American Science. 2010;6(4):29-33.
13. Najigivi A, Khaloo A, Rashid SA. Investigating the effects of using different types of
SiO2 nanoparticles on the mechanical properties of binary blended concrete. Composites Part
B: Engineering. 2013 Nov 1;54:52-8.
14. Ren J, Lai Y, Gao J. Exploring the influence of SiO2 and TiO2 nanoparticles on the
mechanical properties of concrete. Construction and Building Materials. 2018 Jun 30;175:277-
85.
15. Nazerigivi A, Nejati HR, Ghazvinian A, Najigivi A. Effects of SiO2 nanoparticles
dispersion on concrete fracture toughness. Construction and Building Materials. 2018 May
20;171:672-9.
16. Nazari A, Riahi S. Microstructural, thermal, physical and mechanical behavior of the
self compacting concrete containing SiO2 nanoparticles. Materials Science and Engineering:
A. 2010 Nov 15;527(29-30):7663-72.
F. Abdi, et al., J. Appl. Chem. Res., 18, 2, 8-26 (2024)
25
17. Younis KH, Mustafa SM. Feasibility of using nanoparticles of SiO2 to improve the
performance of recycled aggregate concrete. Advances in Materials Science and Engineering.
2018 May 24;2018.
18. Jalal M, Mansouri E, Sharifipour M, Pouladkhan AR. Mechanical, rheological,
durability and microstructural properties of high performance self-compacting concrete
containing SiO2 micro and nanoparticles. Materials & Design. 2012 Feb 1;34:389-400.
19. Nazari A, Riahi S. The role of SiO2 nanoparticles and ground granulated blast furnace
slag admixtures on physical, thermal and mechanical properties of self compacting concrete.
Materials Science and Engineering: A. 2011 Feb 25;528(4-5):2149-57.
20. Nejad FM, Tolouei M, Nazari H, Naderan A. Effects of calcium carbonate
nanoparticles and fly ash on mechanical and permeability properties of concrete. Advances in
Civil Engineering Materials. 2018 Nov 27;7(1):651-68.
21. Devi SC, Khan RA. Effect of graphene oxide on mechanical and durability performance
of concrete. Journal of Building Engineering. 2020 Jan 1;27:101007.
22. Mypati S, Sellathurai A, Kontopoulou M, Docoslis A, Barz DP. High concentration
graphene nanoplatelet dispersions in water stabilized by graphene oxide. Carbon. 2021 Apr
15;174:581-93.
23. Liao K, Ren Z, Fu L, Peng F, Jiang L, Gu W, Zhang X, Bai J, He Y. Effects of
surfactants on dispersibility of graphene oxide dispersion and their potential application for
enhanced oil recovery. Journal of Petroleum Science and Engineering. 2022 Jun 1;213:110372.
24. Devi SC, Khan RA. Effect of graphene oxide on mechanical and durability performance
of concrete. Journal of Building Engineering. 2020 Jan 1;27:101007.
25. Kumar TN, Vardhan KV, Krishna MH, Nagaraja PV. Effect of graphene oxide on
strength properties of cementitious materials: A review. Materials Today: Proceedings. 2021
Jan 1;46:2157-60.
26. Bagheri A, Negahban E, Asad A, Abbasi HA, Raza SM. Graphene oxide-incorporated
cementitious composites: a thorough investigation. Materials Advances. 2022;3(24):9040-51.
27. Kedir A, Gamachu M, Alex AG. Cement-Based Graphene Oxide Composites: A
Review on Their Mechanical and Microstructure Properties. Journal of Nanomaterials. 2023
Apr 28;2023.
28. Zeng H, Qu S, Tian Y, Hu Y, Li Y. Recent progress on graphene oxide for nextgeneration concrete: Characterizations, applications and challenges. Journal of Building
Engineering. 2023 Mar 5:106192.
F. Abdi, et al., J. Appl. Chem. Res., 18, 2, 8-26 (2024)
26
29. Meng S, Ouyang X, Fu J, Niu Y, Ma Y. The role of graphene/graphene oxide in cement
hydration. Nanotechnology Reviews. 2021 Aug 5;10(1):768-78.
30. Kudžma A, Škamat J, Stonys R, Krasnikovs A, Kuznetsov D, Girskas G, Antonovič V.
Study on the effect of graphene oxide with low oxygen content on Portland cement based
composites. Materials. 2019 Mar 8;12(5):802.
31. Devasena M, Karthikeyan J. Investigation on strength properties of graphene oxide
concrete. Int. J. Eng. Sci. Invent. Res. Dev. 2015 Feb;1:307-10.
32. Akarsh PK, Shrinidhi D, Marathe S, Bhat AK. Graphene oxide as nano-material in
developing sustainable concrete–A brief review. Materials Today: Proceedings. 2022 Jan
1;60:234-46.
33. Qureshi TS, Panesar DK. Impact of graphene oxide and highly reduced graphene oxide
on cement based composites. Construction and Building Materials. 2019 May 10;206:71-83.
34. Jyothimol P, Hazeena R, Issac MT, Mathiazhagan A. Effect of reduced graphene oxide
on the mechanical properties of concrete. InIOP Conference Series: Earth and Environmental
Science 2020 Jun 1 (Vol. 491, No. 1, p. 012038). IOP Publishing.
35. Gholampour A, Valizadeh Kiamahalleh M, Tran DN, Ozbakkaloglu T, Losic D. From
graphene oxide to reduced graphene oxide: impact on the physiochemical and mechanical
properties of graphene–cement composites. ACS applied materials & interfaces. 2017 Dec
13;9(49):43275-86.
36. Wang X, Feng D, Zhong J, Shi X. Reinforcement of cement paste by reduced graphene
oxide: Effect of dispersion state. Materials and Structures. 2022 Jan;55(1):25.
37. Abdi F. Multi-layer structures including zigzag sculptured thin films for corrosion
protection of AISI 304 stainless steel. Chinese Physics B. 2021 Mar 1;30(3):038106.