در این پژوهش، به بررسی اثر مقادیر متفاوت (5/1، 1، 5/0، 0 درصد وزنی) از نانوذرات الاستومری بر مدلسازی سینتیک پخت رزین اپوکسی پرداخته شده است. در ابتدا برای بررسی پراکنش نانوذرات در رزین اپوکسی از آزمون SEM استفاده شد. برای برهمکنش احتمالی از FTIR استفاده شد و همچنین برای بررسی ویسکوزیته کمپلکس از آزمون رئومتری (Rheometry) در شرایط همدما 65، 70 و C° 75 استفاده شد. از آزمون DSC برای ارزیابی خواص حرارتی و مدلسازی سینتیک پخت در سه دمای متفاوت 65، 70 و C° 75 در شرایط همدما استفاده شد. بررسی ریخت‌شناسی نانوکامپوزیت‌های اپوکسی نشان داد که ظاهر نانوذرات الاستومری به صورت شکل کروی بوده و اندازه ذرات بین 40 تا nm 70 می‌باشد. نتایج طیف‌سنج مادون قرمز فوریه نشان داد که که با ایجاد نانوکامپوزیت اپوکسی، طول موج گروه هیدروکسیل (O-H) افزایش می‌یابد که نشان از پیوند هیدروژنی بین رزین اپوکسی و نانوذرات الاستومری می‌باشد. نتایج آزمون رئومتری نشان داد که در دمای C° 70، ویسکوزیته کمپلکس نانوکامپوزیت 1 و 5/1 درصد رفتار مشابه یکدیگر را دارند و در این دما ویسکوزیته کمپلکس نانوکامپوزیت‌های اپوکسی در مقایسه با دیگر دماها، کاهش پیدا کرده است. مدلسازی سینتیک پخت نانوکامپوزیت‌های اپوکسی بوسیله مدل‌های درج nام، کمال، و هوری مورد ارزیابی قرار گرفت و نتایج نشان داد که مدل درجه nام توافق بهتری با داده‌های آزمایشگاهی دارد و همچنین حضور 5/0 و 1 درصد وزنی از نانوذرات الاستومری در رزین اپوکسی انرژی فعال‌سازی رزین اپوکسی را کاهش می‌دهد. پرونده مقاله

AbstractThermal and antimicrobial properties of hybrid synthesized compounds were evaluated in the present study. Hybrid structures were synthesized via two main organic and inorganic components, namely: 2-Mercaptobenzothiazole (MBT) and sodium Montmorillonite clay (Na+-MMT). The synthesis process took place in a direct reaction, intercalation; and the resulting material was characterized. Results of scanning electron microscope (SEM), Energy dispersive X-ray spectroscopy (EDS), transmission electron microscope (TEM), small-angle X-ray scattering (SAXS) and Fourier transform infrared spectroscopy (FTIR) confirmed MBT penetration of particles into the inner space of the clay layers and interaction between the two organic and inorganic phases. Also, thermal properties of the resulting compounds were evaluated by thermo gravimetric analysis (TGA) and differential thermal gravimetric (DTG). It was found that while MBT sample had relatively low degradation temperature (about 250°C), the MBT-modified clay compound showed superior thermal stability, and in high temperatures, less weight loss as compared to MBT. Antimicrobial properties of the hybrid nanocompound against five types of bacteria, two types of fungus and one type of yeast were examined using well diffusion agar method and minimum inhibitory concentration (MIC). The diameter of inhibition zone was measured and their antimicrobial potential was compared with two common antibiotics: gentamicin and rifampin. The concentration of about 1000 μg/mL of MBT-MMT showed antibacterial performance equal to 250 μg/mL of rifampin. Also, 1000 μg/mL of this material was required to inhibit the growth for important bacteria. پرونده مقاله

Thermal and antimicrobial properties of hybrid synthesized compounds were evaluated in thepresent study. Hybrid structures were synthesized via two main organic and inorganic components,namely: 2-Mercaptobenzothiazole (MBT) and sodium Montmorillonite clay (Na+-MMT). The synthesis process took place in a direct reaction, intercalation; and the resultingmaterial was characterized. Results of scanning electron microscope (SEM), Energy dispersiveX-ray spectroscopy (EDS), transmission electron microscope (TEM), and small-angle X-ray scattering(SAXS) and Fourier transform infrared spectroscopy (FTIR) confirmed MBT penetrationof particles into the inner space of the clay layers and interaction between the two organicand inorganic phases. Also, thermal properties of the resulting compounds were evaluated bythermo gravimetric analysis (TGA) and differential thermalgravimetric (DTG). It was found thatwhile MBT sample had relatively low degradation temperature (about 250°C), the MBT-modifiedclay compound showed superior thermal stability, and in high temperatures, less weightloss as compared to MBT. Antimicrobial properties of the hybrid nano compound against fivetypes of bacteria, two types of fungus and one type of yeast were examined using well diffusionagar method and minimum inhibitory concentration (MIC). The diameter of inhibitionzone was measured and their antimicrobial potential was compared with two common antibiotics:gentamicin and rifampin. The concentration of about 1000 μg/mL of MBT-MMT showedantibacterial performance equal to 250 μg/mL of rifampin. Also, 1000 μg/mL of this materialwas required to inhibit the growth of important bacteria. پرونده مقاله