Investigation of Parameters Effect on the Size and Morphology of Copper Nanoparticles using Various Reducing Agents
محورهای موضوعی : Journal of NanoanalysisMaryam Mohammadpour 1 , Samad Sabbaghi 2 , Zahra Manafi 3
1 - Faculty of advanced technologies, Nano-chemical Eng. Department, Shiraz University, Shiraz, Iran
2 - Faculty of advanced technologies, Nano-chemical Eng. Department, Shiraz University, Shiraz, Iran
3 - Research and Development Centre, Sarcheshmeh Copper Complex, National Iranian Copper Industries Company, Iran
کلید واژه: Ascorbic acid, glycerol, chemical reduction, Copper nanoparticle synthesis, Reducing agent,
چکیده مقاله :
Copper nanoparticles are widely used in various industries and products. Size and morphology are two important parameters to determine nanoparticle properties. In this study, copper nanoparticles were synthesized without an inert environment using two different reducing agents namely ascorbic acid and sodium hypophosphite. Various capping agents (PVP 105, PVP 4×104, PEG 6000, SDS, CTAB and glycerol) were used as stabilizers. Effect of several parameters including reducing agent concentration, type and amount of stabilizer and precursor concentration on the size and stability of the resulting nanoparticles have been investigated. The synthesis experiments resulted in a 25-60 nm average size of nanoparticles based on the synthesis conditions and the stabilizer type and concentration. Also this research provides a fast and simple way for the synthesis of stable pure colloidal copper nanoparticles in polyol, which is accomplished by decreasing CuSO4.5H2O using sodium hypophosphite in glycerol and without inert medium and homogeneous and non-agglomerated, 25 nm copper nanoparticles were obtained. The as synthesized copper nanoparticles are characterized using scanning and transmission electron microscopy, X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and dynamic light scattering techniques.
[1] M Sahooli, S Sabbaghi, R Saboori. (2012). Synthesis and characterization of mono sized CuO nanoparticles. Materials Letters, 81,169-172.
https://doi.org/10.1016/j.matlet.2012.04.148
[2] Zhou, R., Wu, X., Hao, X., Zhou, F., Li, H., & Rao, W. (2008). Influences of surfactants on the preparation of copper nanoparticles by electron beam irradiation. Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 266(4), 599-603.
https://doi.org/10.1016/j.nimb.2007.11.040
[3] Lisiecki, I., & Pileni, M. P. (1993). Synthesis of copper metallic clusters using reverse micelles as microreactors. Journal of the American Chemical Society, 115(10), 3887-3896.
https://doi.org/10.1021/ja00063a006
[4] Wu, S. H., & Chen, D. H. (2004). Synthesis of high-concentration Cu nanoparticles in aqueous CTAB solutions. Journal of Colloid and Interface Science, 273(1), 165-169.
https://doi.org/10.1016/j.jcis.2004.01.071
[5] Reverberi, A. P., Salerno, M., Lauciello, S., & Fabiano, B. (2016). Synthesis of Copper Nanoparticles in Ethylene Glycol by Chemical Reduction with Vanadium (+2) Salts. Materials, 9(10), 809.
https://doi.org/10.3390/ma9100809
[6] Begletsova, Nadejda, A. Shinkarenko, Oksana, I. Selifonova, Ekaterina, Tsvetkova, Olga and M. Zakharevich, Andrey, K. Chernova, Rimma, A. Kletsov, Aleksey, Glukhovskoy, Evgeny.(2017). Synthesis of copper nanoparticles stabilized with cetylpyridinium chloride micelles. Journal of Advanced Materials Letters, Vol.8, pp. 404-409.
https://doi.org/10.5185/amlett.2017.1423
[7] Solanki, Jignasa & Sengupta, R & Murthy, Z.V.P.. (2010). Synthesis of copper sulphide and copper nanoparticles with microemulsion method. Solid State Sciences - SOLID STATE SCI. 12. 1560-1566. 10.1016/j.solidstatesciences.2010.06.021.
https://doi.org/10.1016/j.solidstatesciences.2010.06.021
[8] Zhou, L. , Wang. S, Ma,H., Ma, S,. Xu, D., Guo, Y.(2015). Size-controlled synthesis of copper nanoparticles in supercritical water. Chemical Engineering Research and Design. 98. 36-43.
https://doi.org/10.1016/j.cherd.2015.04.004
[9] Sreeju.N. Alex Rufus, Daizy Philip. (2016). Microwave-assisted rapid synthesis of copper nanoparticles with exceptional stability and their multifaceted applications. Journal of Molecular Liquids. 221. 1008-1021.
https://doi.org/10.1016/j.molliq.2016.06.080
[10] Umer, A., Naveed, S., Ramzan, N., & Rafique, M. S. (2012). Selection of a suitable method for the synthesis of copper nanoparticles. Nano, 7(05), 1230005.
https://doi.org/10.1142/S1793292012300058
[11] Song, X., Sun, S., Zhang, W., & Yin, Z. (2004). A method for the synthesis of spherical copper nanoparticles in the organic phase. Journal of colloid and interface science, 273(2), 463-469.
https://doi.org/10.1016/j.jcis.2004.01.019
[12] Mott, D., Galkowski, J., Wang, L., Luo, J., & Zhong, C. J. (2007). Synthesis of size-controlled and shaped copper nanoparticles. Langmuir, 23(10), 5740-5745.
https://doi.org/10.1021/la0635092
[13] Kapoor, S., & Mukherjee, T. (2003). Photochemical formation of copper nanoparticles in poly (N-vinylpyrrolidone). Chemical physics letters, 370(1), 83-87.
https://doi.org/10.1016/S0009-2614(03)00073-3
[14] Cheng, X., Zhang, X., Yin, H., Wang, A., & Xu, Y. (2006). Modifier effects on chemical reduction synthesis of nanostructured copper. Applied surface science, 253(5), 2727-2732.
https://doi.org/10.1016/j.apsusc.2006.05.125
[15] Liu, Q., Zhou, D., Nishio, K., Ichino, R., & Okido, M. (2010). Effect of reaction driving force on copper nanoparticle preparation by aqueous solution reduction method. Materials transactions, 51(8), 1386-1389.
https://doi.org/10.2320/matertrans.M2010067
[16] Khatoon, U. T., Nageswara Rao, G. V. S., & Mohan, M. K. (2013, July). Synthesis and characterization of copper nanoparticles by chemical reduction method. In Advanced Nanomaterials and Emerging Engineering Technologies (ICANMEET), 2013 International Conference on (pp. 11-14). IEEE.
https://doi.org/10.1109/ICANMEET.2013.6609221
[17] Ong, H. R., Khan, M. M. R., Ramli, R., Du, Y., Xi, S., & Yunus, R. M. (2015). Facile synthesis of copper nanoparticles in glycerol at room temperature: formation mechanism. RSC Advances, 5(31), 24544-24549.
https://doi.org/10.1039/C4RA16919K
[18] Rahimi, P., Hashemipour, H., Ehtesham Zadeh, M., & Ghader, S. (2010). Experimental Investigation on the Synthesis and Size Control of Copper Nanoparticle via Chemical Reduction Method. International Journal of Nanoscience and Nanotechnology, 6(3), 144-149.
[19] Dang, T. M. D., Le, T. T. T., Fribourg-Blanc, E., & Dang, M. C. (2011). Synthesis and optical properties of copper nanoparticles prepared by a chemical reduction method. Advances in Natural Sciences: Nanoscience and Nanotechnology, 2(1), 015009.
https://doi.org/10.1088/2043-6262/2/1/015009
[20] Zhang, Q. L., Yang, Z. M., Ding, B. J., Lan, X. Z., & Guo, Y. J. (2010). Preparation of copper nanoparticles by chemical reduction method using potassium borohydride. Transactions of Nonferrous Metals Society of China, 20, s240-s244.
https://doi.org/10.1016/S1003-6326(10)60047-7
[21] Lignier, P., Bellabarba, R., & Tooze, R. P. (2012). Scalable strategies for the synthesis of well-defined copper metal and oxide nanocrystals. Chemical Society Reviews, 41(5), 1708-1720.
https://doi.org/10.1039/C1CS15223H
[22] Cheng, X., Zhang, X., Yin, H., Wang, A., & Xu, Y. (2006). Modifier effects on chemical reduction synthesis of nanostructured copper. Applied surface science, 253(5), 2727-2732.
https://doi.org/10.1016/j.apsusc.2006.05.125
[23] Dang, T. M. D., Le, T. T. T., Fribourg-Blanc, E., & Dang, M. C. (2011). Synthesis and optical properties of copper nanoparticles prepared by a chemical reduction method. Advances in Natural Sciences: Nanoscience and Nanotechnology, 2(1), 015009.
https://doi.org/10.1088/2043-6262/2/1/015009
[24] Obraztsova, I. I., Simenyuk, G. Y., & Eremenko, N. K. (2009). Effect of various factors on the dispersity of copper nanopowders produced by reduction of copper salts with glycerol. Russian Journal of Applied Chemistry, 82(6), 981-985.
https://doi.org/10.1134/S1070427209060093
[25] Carroll, K. J., Reveles, J. U., Shultz, M. D., Khanna, S. N., & Carpenter, E. E. (2011). Preparation of elemental Cu and Ni nanoparticles by the polyol method: an experimental and theoretical approach. The Journal of Physical Chemistry C, 115(6), 2656-2664.
https://doi.org/10.1021/jp1104196
[26] Ong, H. R., Khan, M. R., Ramli, R., & Yunus, R. M. (2014, March). Synthesis of copper nanoparticles at room temperature using hydrazine in glycerol. In Applied Mechanics and Materials (Vol. 481, pp. 21-26).
https://doi.org/10.4028/www.scientific.net/AMM.481.21
[27] Khatoon, U. T., Nageswara Rao, G. V. S., & Mohan, M. K. (2013, July). Synthesis and characterization of copper nanoparticles by chemical reduction method. In Advanced Nanomaterials and Emerging Engineering Technologies (ICANMEET), 2013 International Conference on (pp. 11-14). IEEE.
https://doi.org/10.1109/ICANMEET.2013.6609221
[28] Liu, Q., Zhou, D., Nishio, K., Ichino, R., & Okido, M. (2010). Effect of reaction driving force on copper nanoparticle preparation by aqueous solution reduction method. Materials transactions, 51(8), 1386-1389.
https://doi.org/10.2320/matertrans.M2010067
