Evaluation of tribological properties of (Ti,Al)CN/DLC composite coatings deposited by cathodic arc method.
محورهای موضوعی : Surface EngineeringLaleh Zahiri 1 , Moahammad saeri 2 , Shahram Alirezaee 3 , Alireza Afkhami 4
1 - Dep. of Mater. Eng.,
Fac. of Eng., Shahrekord Uni.,
Shahrekord, Iran
2 - Department Of Materials Eng., Faculty Of Eng., Shahrekord Uni., Shahrekord, Iran. Email: Saeri_Mohammad@Yahoo.com
3 - Naghsh-E- Jahan University, Baharestan, Isfahan, Iran. Email:
4 - M.Sc. in Materials Engineering, Researcher, Marine Industry,-Department of Subsurface Vessels, Shahin Shahr, Isfahan, Iran.
کلید واژه: Wear, friction, composite coating, DLC, cathodic arc,
چکیده مقاله :
In this study, Ti, Al and N doped DLC – referred to here after as “(Ti,Al)CN/DLC composite”- coating and pure diamond-like coating (DLC) were produced by cathodic arc deposition technique and the effects of the coating thickness on their tribological properties were evaluated. The coatings were characterized, using scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray diffraction (XRD) and Raman spectroscopy methods. The Raman and XRD patterns indicated that cathodic arc deposition method can potentially generate a composite coating consisting of TiC, Ti3AlN, Ti2N and Al2Ti crystalline phases dispersed in the amorphous carbon matrix. Moreover, friction and wear of the coatings were investigated, using pin-on-disc wear test method in ambient air. The results of wear test showed a desired tribological behavior of the (Ti,Al)CN/DLC composite coatings with low amounts of the mean coefficients of friction (0.2) and wear rate (9×10-8 mm3/N.m). In contrast with DLC coatings, it was also found that friction coefficient of the composite coated samples did not change significantly, when the thickness of the coating was increased from 1.5 to 3 μm.
[1] T. Fu, Z.F. Zhou, Y.M. Zhou, X.D. Zhu, Q.F. Zeng, C.P. Wang, K.Y. Li and J. Lu, “Mechanical properties of DLC coating sputter deposited on surface nanocrystallized 304 stainless steel”, J Surf. Coat. Tech., Vol.207, 2012, pp. 555-564.
[2] A.M. Ladwig, R.D. Koch, E.G. Wenski and R.F. Hicks, “Atmospheric plasma deposition of diamond-like carbon coatings”, J. Diamond Related Mater., Vol. 18, 2009, pp.1129-1133.
[3] C. Donnetand and A. Erdemir, “Tribology of DlC film Fundamentals and applications”, 2008, Springer, pp. 243-316.
[4] M. Moseler, P. Gumbsch, C. Casiraghi, A.C. Ferrari, J. Robertson, “The Ultrasmoothness of Diamond-like Carbon Surfaces” Surf. Sci., Vol. 309, 2005, pp. 1545-1548.
[5] J. Choi, K. Soejima, T. Kato, M. Kawaguchi and W. Lee. “Nitriding of high speed steel by bipolar PBII for improvement in adhesion strength of DLC films” Nuclear Instrum. Methods. Phy. Res. Sec. B, Vol.272, 2012, pp. 357-360.
[6] S. Zhang, Y. Fu, H. Du, X.T. Zeng and Y.C. Liu, “Magnetron sputtering of nanocomposite (Ti,Cr)CN/DLC coatings”, J Surf. Coat. Tech., Vol. 162, 2002, pp. 42-48.
[7] C.F. Borges, E. Pfender and J. Heberlein, “Influence of nitrided and carbonitrided interlayers on enhanced nucleation of diamond on stainless steel 304”, J Diamond Relat Mater., Vol. 10, 2001, pp.1983-1990.
[8] S. Kukiełka, W. Gulbiñski, Y. Pauleau, S.N. Dub, J.J. Grob, “Composition, mechanical properties and friction behavior of nickel/hydrogenated amorphous carbon composite films”, Surf. Coat. Technol., Vol. 200, 2006, pp. 6258-6262.
[9] D.Y. Wang, K.W. Weng, Ch.L. Chang, X.J. Guo, “Tribological performance of metal doped diamond-like carbon films deposited by cathodic arc evaporation.”, Diam. Relat. Mater., Vol. 9, 2000, pp. 831-837.
[10] X.M. He, M. Hakovirta, M. Nastasi, “Hardness, hydrophobic and optical properties of fluorine and boron co-alloyed diamond-like carbon films.” Mat. Lett., Vol. 59, 2005, pp. 1417-1421.
[11] K. Kato, “Wear In Relation To Friction — A Review”, J Wear, Vol. 241, 2000, pp. 151-157.
[12] W.P. Hsieh, “Characterization of the Ti-doped diamond-like carbon coatings on a type 304 stainless steel”, J vacuum sci. tech., Vol. 17, 1999, pp. 1053-1058.
[13] L. Wang, J.F. Su and X. Nie, “Corrosion and tribological properties and impact fatigue behaviors of TiN- and DLC-coated stainless steels in a simulated body fluid environment”, J Sur. Coat. Tech., Vol. 205, 2010, pp. 1599-1605.
[14] G. Cheng, D. Han, C. Liang, X. Wu and R. Zheng, “Influence of residual stress on mechanical properties of TiAlN thin films” J Surf. Coat. Tech., Vol. 228, 2013, pp. 328-330.
[15] J. Lapin, “TiAl-based alloys: Present status and future perspectives”, J Metal., Vol.5, 2009, pp. 19-30.
[16] C. Ruseta, E. Grigorea, G.A. Collinsb, K.T. Shortb, F. Rossic, N. Gibsonc, H. Dongd and T. Belld, “Characteristics of the Ti2N layer produced by an ion assisted deposition Method” J Surf. Coat. Tech., Vol. 174, 2003, pp. 698-703.
[17] J. C. Sánchez-López, M. Belin, C. Donnet, C. Quiros and E. Elizalde, “Friction mechanisms of amorphous carbon nitride films under variable environments: a triboscopic study”, Surf. coat tech., Vol. 16, 2002, pp.138-144.
[18] R.A. Singh and E.S. Yoon, “Friction behaviour of diamond-like carbon films with varying mechanical properties”, J Surf. Coat. Tech., Vol. 201, 2006, pp, 4348-4351.
[19] M. Sedlacek, B. Podornik, J. Vižintin, “Tribological properties of DLC coatings and comparison with test results: Development of a database”, Mater. Charact., vol. 59, 2008, pp. 151-161.
[20] K. Adachi, N. Sodeyama and K. Kato, “Effect of humidity on friction of carbonnitride coatings under N2 gas lubrication”, Proc. WTC II, WTC2005-64275, Sep.12-16, 2005, Washington, D.C., USA.
[21] R. Hauert, L. Knoblauch-Meyer, G. Francz, A. Schroeder, E. Wintermantel, “Tailored aC: H coatings by nanostructuring and alloying”, Surf. Coat. Technol., Vol. 120-121, 1999, pp. 291-296.
[22] J. Robertson, “Diamond-like amorphous carbon”, Mater. Sci. Eng. Report, Vol. 37, 2002, pp. 129-281.
[23] J. Neidhardt, Z. Czigany, I.F. Brunell, L. Hultman, “Growth of fullerene-like carbon nitride thin solid films by reactive magnetron sputtering; role of low-energy ion irradiation in determining microstructure and mechanical properties.”, J Appl. Phys., Vol. 93, 2003, pp. 3002-3015.
[24] I.A. Garcia, E. Berasategui, S.J. Bull, T.F. Page, J. Neidhardt, L. Hultman, N. Hellgren, “How hard is fullerene-like CNx Some observations from the nanoindentation response of a magnetron-sputtered coating.”, Philos. Mag. A , Vol. 82, 2002, pp., 2133-2147.
[25] R. Gilmore, R. Hauert, “Control of the tribological moisture sensitivity of diamond-like carbon films by alloying with F, Ti or Si.” Thin Solid Films, Vol. 398, 2001, pp. 199-204.
K.P. Shaha, Y.T. Pei, C.Q. Chen, J.Th.M. De Hosson, “Synthesis of ultra-smooth and ultra-low friction DLC based nanocomposite films on rough substrates, Thin Solid Films”, Vol. 519, 2010, pp. 1618-1622.