Aminolysis of selected methylpyrimidines in protic solvents
محورهای موضوعی : Journal of Chemical Reactivity and Synthesis
Hossein Eshtiagh-Hosseini
1
(Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, Mashhad, P.O. Box 917791436, Iran)
Masoud Mirzaei
2
(Department of Chemistry, School of Sciences, Ferdowsi University of Mashhad, Mashhad, P.O. Box 917791436, Iran)
کلید واژه: Protein, Hybrid, Proline, Hydrogen bonding, Polyoxometallates, Molybdenum, Keggin, Peptide,
چکیده مقاله :
Crystallographic data analyses indicate that three types of prolinium cations, along with two types of hydrogen bonding, produce and stabilize the helical structure of triprolinium 12-phosphomolybdate. There are similarities between this organic-inorganic compound and peptides/proteins. The stronger “conventional” hydrogen bonds and the less common C-H…O attractions play critical roles in generating and stabilizing the DNA-like network.
