سنتز نانوذره های NiO دوپه شده با Cu (II) با آسیاب گلوله سیاره‌ای و شناسایی آن

محورهای موضوعی : شیمی کاربردی

الهام سجادی ¹ ( دانشجوی کارشناسی ارشد شیمی، آزمایشگاه تحقیقاتی نانومواد، دانشکده شیمی، دانشگاه تبریز، تیریز، ایران. )
مسیح دربندی ² ( دانشیار نانوشیمی، آزمایشگاه تحقیقاتی نانومواد، دانشکده شیمی، دانشگاه تبریز، تبریز، ایران. )

تاریخ دریافت : 1402/02/19 تاریخ پذیرش : 1402/04/22 تاریخ انتشار : 1402/12/27

کلید واژه: نیکل اکسید, سونوفتوکاتالیست, آسیاب گلوله‌ای, فنل, مس (П) اکسید, دوپه کردن.,

چکیده مقاله :

در این پژوهش، ابتدا نانوذره های میان متخلخل نیکل هیدروکسید با روش حلال گرمایی سنتز؛ سپس، به عنوان ماده اولیه با حفظ ساختار و ریخت در یک عملیات گرمایی به نانوذره های نیکل اکسید تبدیل شدند. پس ازآن، به وسیله یک آسیاب گلوله ای با مس (П) دوپه شد. ازآن جایی که در طی فرایند سنتز از هیچ ماده شیمیایی سمی، گران قیمت و پیچیده استفاده نشد، نتیجه های این پژوهش می تواند از نظر علمی و صنعتی در تولید سایر نانومواد دوپه شده به کارگرفته شود. برای مطالعه های ساختاری و ترکیب شیمیایی نانو‌مواد سنتزشده، روش‌های میکروسکوپی الکترونی روبشی (SEM)، پراش پرتو ایکس (XRD)، طیف سنجی تفکیک انرژی (EDS) و اندازه گیری مساحت سطح و تخلخل سنجی با روش جذب و واجذب نیتروژن (BET) به¬کارگرفته شد. الگو‌های XRD ساختار FCC نانوذره های سنتزشده و عدم وجود فاز ناخالصی را نشان دادند. همچنین، اندازه گیری‌های BET میان متخلخل بودن نانوذره ها، سطح ویژه و حجم منافذ مناسبی را نشان داد. همچنین، رفتار کاتالیستی نانوذره های نیکل اکسید دوپه شده با مس در حذف و تخریب سونوفتوکاتالیستی آلاینده‌ فنل تحت نور مرئی و امواج فراصوت مطالعه شد. ماده فنل محلول در آب به عنوان آلاینده مدل پس از افزودن کاتالیست نیکل اکسید دوپه شده با مس، تحت نور مرئی و امواج فراصوت در مدت ۶0 دقیقه، حدود 5/86 درصد تخریب شد.

چکیده انگلیسی:

In this research, first mesoporous nickel hydroxide nanoparticles were synthesized by solvothermal method. Then the nickel hydroxide nanoparticles were converted into nickel oxide nanoparticles by maintaining the structure and morphology during heat treatment and then doped with copper (П) by ball milling method. Since no toxic, expensive, and complex chemicals were used during the synthesis process, the results of this research can be considered scientifically and industrially in the production of other doped nanomaterials. Methods such as scanning electron microscopy (SEM), X-ray diffraction (XRD), energy–dispersive spectroscopy (EDS), and surface area and porosity measurement by nitrogen absorption and desorption method (BET) were used to study the structure and chemical composition of the synthesized nanomaterials. XRD patterns showed FCC structure of the synthesized nanoparticles and the absence of impurity phase. Also, BET measurements showed the mesoporous nature of nanoparticles and good specific surface area and pore volume. The catalytic behavior of copper doped nickel oxide nanoparticles in the removal and sonophotocatalytic degradation of phenol pollutant under visible light and ultrasound waves was studied. It was observed that the phenol substance soluble in water as a model pollutant was destroyed by about 86.5% under visible light and ultrasonic waves after adding copper doped nickel oxide catalyst.

منابع و مأخذ:

[1] Guozhang Cao (University of Washington). Nanostructures and Nanomaterials:  Synthesis, Properties and Applications. London: Imperial College Press; 2004. In: Brock SL. Journal of the American Chemical Society. 2004;126(44):14679. doi: 10.1021/ja0409457
[2] Babanzadeh S, Mehdipour-Ataei S, Mahjoub AR. Preparation and characterization of novel polyimide/SiO2 nano-hybrid films by in situ polymerization. Journal of inorganic and organometallic Polymers and Materials. 2012;22(6):1404-12. doi: 10.1007/s10904-012-9764-y
[3] Gaur APS, Zhang B, Lui YH, Tang X, Hu S. Morphologically tailored nano-structured MoS2 catalysts via introduction of Ni and Co ions for enhanced HER activity. Applied Surface Science. 2020;516:146094. doi: 10.1016/j.apsusc.2020.146094
[4] Yasin G, Khan MA, Arif M, Shakeel M, Hassan TM, Khan WQ, et al. Synthesis of spheres-like Ni/graphene nanocomposite as an efficient anti-corrosive coating; effect of graphene content on its morphology and mechanical properties. Journal of Alloys and Compounds. 2018;755:79-88. doi: 10.1177/00 21998312461822
[5] Zhang Y, Zhang P, Xu Y, Song X, Wang H, Ma T. Synthesis of pomegranate-shaped micron ZnMn2O4 with enhanced lithium storage capability. Journal of Materiomics. 2021;7(4):699-707. doi: 10.1016/j.jmat. 2021.01.005
[6] Abdallah A, Basma H, Awad R. Preparation, characterization, and application of nickel oxide nanoparticles in glucose and lactose biosensors. Modern Applied Science. 2019;13:99. doi: 10.5539/mas.v13n6p99
[7] Manna I, Sahoo S, Bandyopadhyay M. Effect of engineered nickel oxide nanoparticle on reactive oxygen species-nitric oxide interplay in the roots of Allium cepa L. Front Plant Sci. 2021;12:586509. doi: 10.3389/fpls. 2021.586509
[8] Narender SS, Varma VVS, Srikar CS, Ruchitha J, Varma PA, Praveen BVS. Nickel oxide nanoparticles: A brief review of their synthesis, characterization, and applications. Chemical Engineering & Technology. 2022;45(3):397-409. doi: 10.1002/ceat. 202100442
[9] Abuzeid HM, Julien CM, Zhu L, Hashem AM. Green synthesis of nanoparticles and their energy storage, environmental, and biomedical applications. Crystals. 2023;13(11):1576. doi: 10.3390/cryst13111576
[10] Hong S-J, Mun H-J, Kim B-J, Kim Y-S. Characterization of nickel oxide nanoparticles synthesized under low temperature. Micromachines. 2021; 12(10):1168. doi: 10.3390/mi12101168
[11] Muhammed A, Asere TG, Diriba TF. Photocatalytic and antimicrobial properties of ZnO and Mg-doped ZnO nanoparticles synthesized using Lupinus albus leaf extract. ACS Omega. 2024;9(2):2480-90. doi: 10.1021/acsomega.3c07093
[12] Xia P, Song Y-J, Liu Y-Z, Long M-X, Yang C, Zhang X-Y, et al. Advances in the optical and electronic properties and applications of bismuth-based semiconductor materials. Journal of Materials Chemistry C. 2024; Advance Article. doi: 10.1039/D3TC03329E
[13] Shabani M, Haghighi M, Kahforoushan D, Haghighi A. Mesoporous-mixed-phase of hierarchical bismuth oxychlorides nanophotocatalyst with enhanced photocatalytic application in treatment of antibiotic effluents. Journal of Cleaner Production. 2019;207:444-57. doi: 10.1016/j. jclepro.2018.10.042
[14] Mousavi M, Habibi-Yangjeh A, Pouran SR. Review on magnetically separable graphitic carbon nitride-based nanocomposites as promising visible-light-driven photocatalysts. Journal of Materials Science: Materials in electronics. 2018;29(3):1719-47. doi: 10.1007/s10854-017-8166-x
[15] Mousavi M, Moradian S, Pourhakkak P, Zhang G, Habibi MM, Madadi M, et al. Fabrication of S-scheme heterojunction g-C3N4-nanosheet/ZnMoO4 nanocomposite with high efficiency in photocatalytic N2 fixation and Cr(VI) detoxification. Journal of Materials Science. 2022;57:9145-9163. doi: 10.1007/ s10853-022-07225-5
[16] Khaksar AM, Nazif S, Taebi A, Shahghasemi E. Treatment of phenol in petrochemical wastewater considering turbidity factor by backlight cascade photocatalytic reactor. Journal of Photochemistry and Photobiology A-chemistry. 2017;348:161-7. doi: 10.1016/j. resconrec.2006.11.003
[17] Tiandho Y, Afriani F, Evi J, Lingga R, Handoyo. Kinetic evaluation of methylene blue decolorization by CuO as a Fenton-like catalyst. IOP Conference Series: Earth and Environmental Science. 2021;926(1):012103. doi: 10.1088/1755-1315/926/1/012103
[18] Chan S, Wu T, Juan JC, Teh C. Recent developments of metal oxide semiconductors as photocatalysts in advanced oxidation processes (AOPs) for treatment of dye wastewater. Journal of Chemical Technology and Biotechnology. 2011;86:1130-58. doi: 10.1002/jctb.2636
[19] Pirsaheb M, Moradihamadani N. Sonochemical degradation of pesticides in aqueous solution: investigation on the influence of operating parameters and degradation pathway – a systematic review. RSC Advances. 2020;10:7396-423. doi: 10. 1039/C9RA11025A
[20] Joseph CG, Li Puma G, Bono A, Krishnaiah D. Sonophotocatalysis in advanced oxidation process: A short review. Ultrasonics Sonochemistry. 2009;16(5):583-9. doi: 10.1016/j.ultsonch.2009.02.002
[21] Peterson MW, Turner JA, Nozik AJ. Mechanistic studies of the photocatalytic behavior of titania: Particles in a photoelectrochemical slurry cell and the relevance to photodetoxification reactions. The Journal of Physical Chemistry. 1991;95(1):221-5. doi: 10.1021/j100154a044
[22] Dinesh GK, Anandan S, Sivasankar T. Sonophotocatalytic treatment of Bismarck Brown G dye and real textile effluent using synthesized novel Fe(0)-doped TiO2 catalyst. RSC Advances. 2015;5(14):10440-51. doi: 10.1039/C4RA07685K
[23] Al-Hamdi AM, Sillanpää M, Bora T, Dutta J. Efficient photocatalytic degradation of phenol in aqueous solution by SnO2:Sb nanoparticles. Applied Surface Science. 2016;370:229-36. doi: 10.1016/j.apsusc.2016.02.123
[24] Jiang R-H, Liang S-Q, Wu F, Tang L-M, Qin B, Chen Y-Y, et al. Phylogenomic analysis, cryptic species discovery, and DNA barcoding of the genus Cibotium in China based on plastome data. Frontiers in Plant Science. 2023;14. doi: 10.3389/fpls. 2023.1183653