Application of multipurpose dimethyl formamide-like task specific ionic liquid as a recyclable reagent for direct iodination of alcohols

محورهای موضوعی : Iranian Journal of Catalysis

Ahmed Ali Hullio ¹ , G.M. Mastoi ²

1 - Dr. M.A Kazi Institute of Chemistry, University of Sindh Jamshoro-76080 Sindh, Pakistan.
2 - Dr. M.A Kazi Institute of Chemistry, University of Sindh Jamshoro-76080 Sindh, Pakistan.

تاریخ دریافت : 1390/08/10 تاریخ پذیرش : 1390/09/09 تاریخ انتشار : 1390/09/10

کلید واژه: DMF-like ionic liquid, Iminium chloride, Vilsmier reagent, Thioiminium salt, Alcohols and alkyl iodides,

چکیده مقاله :

A direct and an efficient conversion of a wide range of primary, secondary even tertiary alcohols to the corresponding iodides have been achieved under ionic liquid conditions. The method involves preparation of ionic liquid-based iminium chloride intermediate from DMF-like ionic liquid then stirring it with alcohol in present of sodium iodide. The higher yields of alkyl iodides were obtained within minimum time with simplest operational procedure. The DMF-like ionic liquids could be recycled.

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