Application of multipurpose dimethyl formamide-like task specific ionic liquid as a recyclable reagent for direct iodination of alcohols

الموضوعات : Iranian Journal of Catalysis

Ahmed Ali Hullio ¹ (Dr. M.A Kazi Institute of Chemistry, University of Sindh Jamshoro-76080 Sindh, Pakistan.)
G.M. Mastoi ² (Dr. M.A Kazi Institute of Chemistry, University of Sindh Jamshoro-76080 Sindh, Pakistan.)

تاريخ الإرسال : 05 الثلاثاء , ذو الحجة, 1432 تاريخ التأكيد : 05 الأربعاء , محرم, 1433 تاريخ الإصدار : 06 الخميس , محرم, 1433

الکلمات المفتاحية: DMF-like ionic liquid, Iminium chloride, Vilsmier reagent, Thioiminium salt, Alcohols and alkyl iodides,

ملخص المقالة :

A direct and an efficient conversion of a wide range of primary, secondary even tertiary alcohols to the corresponding iodides have been achieved under ionic liquid conditions. The method involves preparation of ionic liquid-based iminium chloride intermediate from DMF-like ionic liquid then stirring it with alcohol in present of sodium iodide. The higher yields of alkyl iodides were obtained within minimum time with simplest operational procedure. The DMF-like ionic liquids could be recycled.

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