Fe-MCM-22 catalyzed multicomponent synthesis of dihydropyrano [2,3-c] pyrazole derivatives

محورهای موضوعی : Iranian Journal of Catalysis

Rameshwar Magar ¹ (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad (M.S.), 431004, India.)
Ganesh Pawar ² (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad (M.S.), 431004, India.)
Sachin Gadekar ³ (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad (M.S.), 431004, India.)
Machhindra Lande ⁴ (Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad (M.S.), 431004, India.)

تاریخ دریافت : 1395/07/23 تاریخ پذیرش : 1395/12/07 تاریخ انتشار : 1395/12/11

کلید واژه: Heterogeneous catalyst, Fe-MCM-22 zeolite, Multicomponent synthesis, Dihydropyrano [2, 3-c] pyrazoles,

چکیده مقاله :

The Fe-MCM-22 zeolite was found to be an efficient solid heterogeneous catalyst for synthesis of dihydropyrano [2,3-c] pyrazoles via one pot four component reaction of ethyl acetoacetate, hydrazine hydrate, aromatic aldehyde and malononitrile in aqueous alcohol. The catalyst was synthesized by hydrothermal method under autogenous pressure and modified by Fe (III) ion exchange. The prepared catalyst was characterized by X-ray diffraction (XRD), Scanning Electron Microscopy-Energy Dispersive spectroscopy (SEM-EDS), Fourier Transform Infrared Spectroscopy (FT-IR), and Brunauer-Emmett-Teller (BET) measurement technique. This ecofriendly protocol provides several advantages such as use of an inexpensive catalyst, short reaction time, mild reaction condition, simple work-up, good to excellent yield and reusability of the catalyst.

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