β-aminoketones derivatives synthesize by reusable catalyst of copper coated Fe3O4@Sapogenin

Subject Areas :

majid heidarpour ¹ , hossein anaraki ardakani ² , Neda Hasanzadeh ³ , Ayeh Rayatzadeh ⁴

1 - Department of chemistry, Ahvaz branch, Islamic Azad University, Ahvaz, Iran.
2 - Department of Chemistry, Mahshahr Branch, Islamic Azad University, Mahshahr, Iran
3 - Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran
4 - Department of Chemistry, Ahvaz Branch, Islamic Azad University, Ahvaz, Iran

Received: 2020-11-14 Accepted : 2020-12-19 Published : 2021-11-22

Keywords: green chemistry, three-component reaction . quillaja sapogenin, β-aminoketones: Copper(II) chloride,

Abstract :

In this research, a new magnetic core–shell nanocomposite Fe3O4@Sapogenin/Cu(II) based on quillaja sapogenin was prepared and The structure, magnetic features, and morphology of magnetic nanoparticles (MNPs) Fe3O4@Sapogenin/Cu(II) were studied totally via different experiments, such as energy-dispersive X-ray spectroscopy (EDS), thermogravimetric analysis (TGA), Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), high-resolution transmissionelectron microscopy (HR-TEM), and Brunauer–Emmett–Teller (BET). vibrating sample magnetometer (VSM), scanning electron microscopy (SEM), inductively coupled plasma (ICP). The achievements demonstrated that the proposed agents were beneficial to synthesis the derivatives of β-aminoketone via a one-pot three-component reaction of ketones, aromatic aldehydes, and aromatic amines in ethanol under environmentally friendly conditions . The advantage of this reaction is the high efficiency of the products and the short reaction time. Furthermore, Fe3O4@Sapogenin/Cu(II) nanocatalyst can be easily recovered magnetically and can be reused for other runs without any reduction in the activity, also, with the use of this catalyst, several a novel products were obtained for the first time.

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