Palladium-Cobalt on Reduced Graphene Oxide as an Electro-catalyst for Ethylene Glycol Oxidation in Alkaline Medium: Synthesis and Electrochemical Performance

Subject Areas : Chemistry

Hamid Asgari ¹ , Somayeh Majidi ²

1 - Department of Chemical Engineering, Health, Safety and Environment, Najafabad Branch, Islamic Azad University, Najafabad, Iran.
2 - Department of Chemistry, Najafabad Branch, Islamic Azad University, Najafabad, Iran

Received: 2021-05-02 Accepted : 2021-07-06 Published : 2021-08-01

Keywords:

References:

[1] K. Tran, T. Q. Nguyen, A. M. Bartrom, A. Sadiki, J. L. Haan, “A Fuel-Flexible Alkaline Direct Liquid Fuel Cell”, Fuel Cells, Vol. 14, 2014, pp. 834-841.

[2] Z. Y. Li, Y. J. Liang, S. P. Jiang, X. D. Shan, M. L. Lin, C. W. Xu, “Electrooxidation of Methanol and Ethylene Glycol Mixture on Platinum and Palladium in Alkaline Medium”, Fuel Cells, Vol. 12, 2012, pp. 677-682.

[3] M. Zhiani, S. Majidi, H. Rostami, M.M.Taghiabadi, “Comparative study of aliphatic alcohols electrooxidation on zero-valent palladium complex for direct alcohol fuel cells”, Int. J. Hydrogen Energy, Vol. 40, 2015, pp. 568-576.

[4] T. Asset, A. Serov, M. Padilla, A.J. Roy, I. Matanovic, M. Chatenet, et al., “Design of Pd-Pb catalysts for glycerol and ethylene glycol electrooxidation in alkaline medium”, Electrocatalysis, Vol. 9, 2018, pp. 480-485.

[5] F. Gomes, V.L. Oliveira, P.M.P. Pratta, G.T. Filho, “Reactivity of alcohols with three-carbon atom chain on Pt in acidic medium”, Electrocatalysis, Vol. 6, 2015, pp.7-19.

[6] G. Cui, P.K. Shen, H. Meng, J. Zhao, G. Wu, “Tungsten carbide as supports for Pt electrocatalysts with improved CO tolerance in methanol oxidation”, J. Power Sources, Vol. 196, 2011, pp. 6125-6130.

[7] Y. Xia, X. Yang, “Toward cost-effective and sustainable use of precious metals in heterogeneous catalysts”, Acc. Chem. Res., Vol. 50, 2017, pp. 450-454.

[8] Y. Kim, H. Kim, W.B. Kim, “PtAg nanotubes for electrooxidation of ethylene glycol and glycerol in alkaline media”, Electrochem. Commun. Vol. 46, 2014, pp. 36-39.

[9] C. Xu, P.K. Shen, “Novel Pt/CeO2/C catalysts for electrooxidation of alcohols in alkaline media”, Chem. Commun., Vol. 19, 2004, pp. 2238-2239.

[10] C. Xu, R. Zeng, P.K. Shen, Z. Wei, “Synergistic effect of CeO2 modified Pt/C catalysts on the alcohols oxidation”, Electrochim. Acta, Vol. 51, 2005, pp. 1031-1035.

[11] R. Baronia, J. Goel, V. Kataria, S. Basu, S.K. Singhal, “Electro-oxidation of ethylene glycol on Pt-Co metal synergy for direct ethylene glycol fuel cells: Reduced graphene oxide imparting a notable surface of action”, Int. J. Hydrogen Energy, Vol. 44, 2019, pp. 10023-10032.

[12] K.J. Ju, L. Liu, J.J. Feng, Q.L. Zhang, J. Wei, A.J. Wang, “Bio-directed one-pot synthesis of Pt-Pd alloyed nanoflowers supported on reduced graphene oxide with enhanced catalytic activity for ethylene glycol oxidation”, Electrochim. Acta, Vol. 188, 2016, pp. 696-703.

[13] N. Cai, J. Wu, R. Dong, C. Jin, “High performance of AuPt deposited on Ni nanoparticles in ethylene glycol oxidation”, J. Power Sources, Vol. 412, 2019, pp. 37-43.

[14] T. Ramulifho, K.I. Ozoemena, R.M. Modibedi, C.J. Jafta, M.K. Mathe, “Electrocatalytic oxidation of ethylene glycol at palladium-bimetallic nanocatalysts (PdSn and PdNi) supported on sulfonate-functionalised multi-walled carbon nanotubes”, J Electroanal. Chem., Vol. 692, 2013, pp. 26-30.

[15] A. Serov, U. Martinez, P. Atanassov, “Novel Pd–In catalysts for alcohols electrooxidation in alkaline media”, Electrochem. Commun., Vol. 34, 2013, pp. 185-188.

[16] R. Kannan, K. Karunakaran, S. Vasanthkumar, “PdNi-decorated manganite nanocatalyst for electrooxidation of ethylene glycol in alkaline media”, Ionics, Vol. 18, 2012, pp. 803-809.

[17] V. Bambagioni, M. Bevilacqua, C. Bianchini, J. Filippi, A. Marchionni, F. Vizza, et al., “Ethylene glycol electrooxidation on smooth and nanostructured Pd electrodes in alkaline media”, Fuel Cells, Vol. 10, 2010, pp. 582-590.

[18] O.O. Fashedemi, K.I. Ozoemena, “Comparative electrocatalytic oxidation of ethanol, ethylene glycol and glycerol in alkaline medium at Pd-decorated FeCo@ Fe/C core-shell nanocatalysts”, Electrochim. Acta, Vol. 128, 2014, pp. 279-286.

[19] P.K. Shen, C. Xu, “Alcohol oxidation on nanocrystalline oxide Pd/C promoted electrocatalysts”, Electrochem. Commun., Vol. 8, 2006, pp. 184-188.

[20] C. Xu, Z. Tian, P. Shen, S.P. Jiang, “Oxide (CeO2, NiO, Co3O4 and Mn3O4)-promoted Pd/C electrocatalysts for alcohol electrooxidation in alkaline media”, Electrochim. Acta, Vol. 53, 2008, pp. 2610-2618.

[21] S. Yongprapat, A. Therdthianwong, S. Therdthianwong, “Au/C catalysts promoted with metal oxides for ethylene glycol electro-oxidation in alkaline solution”, J Electroanal. Chem., Vol. 697, 2013, pp. 46-52.

[22] C. Jin, Y. Song, Z.Chen, “A comparative study of the electrocatalytic oxidation of ethylene glycol on PtAu nanocomposite catalysts in alkaline, neutral and acidic media”, Electrochim. Acta, Vol. 54, 2009, pp. 4136-4140.

[23] M. Brandalise, M.M. Tusi, R.M. Piasentin, M. Santos, E.V. Spinace, A.O. Neto, “Synthesis of PdAu/C and PdAuBi/C electrocatalysts by borohydride reduction method for ethylene glycol electro-oxidation in alkaline medium”, Int. J. Electrochem. Sci., Vol. 7, 2012, pp. 9609-9621.

[24] K.I. Ozoemena, “Nanostructured platinum-free electrocatalysts in alkaline direct alcohol fuel cells: catalyst design, principles and applications”, RSC Adv., Vol. 6, 2016, pp. 89523-89550.

[25] R. Ferrando, J. Jellinek, R.L. Johnston, “Nanoalloys: from theory to applications of alloy clusters and nanoparticles”, Chem. Rev., Vol. 108, 2008, pp. 845-910.

[26] A. Ambrosi, C.K. Chua, N.M. Latiff, A.H. Loo, C.H.A. Wong, A.Y.S. Eng, et al., “Graphene and its electrochemistry–an update”, Chem. Soc. Rev., Vol. 45, 2016, pp. 2458-2493.

[27] A.A. Elzatahry, A.M. Abdullah, T.A.S. El-Din, A.M. Al-Enizi, A.A. Maarouf, A. Galal, et al., “Nanocomposite graphene-based material for fuel cell applications”, Int. J. Electrochem. Soc., Vol. 7, 2012, pp. 3115-3126.

[28] H. Rostami, A.A. Rostami, A. Omrani, “Investigation on ethanol electrooxidation via electrodeposited Pd–Co nanostructures supported on graphene oxide”, Int. J. Hydrogen Energy, Vol. 40, 2015, pp. 10596-10604.

[29] A.S. Douk, H. Saravani, M. Noroozifar, “A fast method to prepare Pd-Co nanostructures decorated on graphene as excellent electrocatalyst toward formic acid oxidation”, J. Alloys Compd, Vol. 739, 2018, pp. 882-891.

[30] D. Wang, H.L. Xin, H. Wang, Y. Yu, E. Rus, D.A. Muller, et al., “Facile synthesis of carbon-supported Pd–Co core–shell nanoparticles as oxygen reduction electrocatalysts and their enhanced activity and stability with monolayer Pt decoration”, Chem. Mate., Vol. 24, 2012, pp. 2274-2281.

[31] Y. Wang, Y. Zhao, J. Yin, M. Liu, Q. Dong, Y. Su, “Synthesis and electrocatalytic alcohol oxidation performance of Pd–Co bimetallic nanoparticles supported on graphene”, Int. J. Hydrogen Energy, Vol. 39, 2014, pp. 1325-1335.

[32] S.N. Alam, N. Sharma, L. Kumar, “Synthesis of graphene oxide (GO) by modified hummers method and its thermal reduction to obtain reduced graphene oxide (rGO)”, Graphene, Vol. 6, 2017, pp. 1-18.

[33] F.T. Johra, J.W. Lee, W.G. Jung. “Facile and safe graphene preparation on solution based platform”, J. Ind. Eng. Chem., Vol. 20, 2014, pp. 2883-2887.

[34] A.C. Ferrari, J. Robertson, “Interpretation of Raman spectra of disordered and amorphous carbon”, Phys. Rev., Vol. 61, 2000, pp.14095-14107.

[35] R. Krishna, D.M. Fernandes, J. Ventura, C. Freire, E. Titus, “Facile synthesis of reduced graphene oxide supported Pd@NixB/RGO nanocomposite: novel electrocatalyst for ethanol oxidation in alkaline media”, Int. J. Hydrogen Energy, Vol. 41, 2016, pp.11811-11822.

[36] L.L. Wang, D.D. Johnson, “Predicted trends of core− shell preferences for 132 late transition-metal binary-alloy nanoparticles”, J. Ame. Chem. Soc., Vol. 131, 2009, pp. 14023-14029.

[37] H. Yamauchi, “Surface segregation in jellium binary solid solutions”, Phys. Rev. B, Vol. 31, 1985, pp.7688-7694.

[38] M. Zhiani, A. Abedini. S. Majidi, “Comparison of electro-catalytic activity of Fe-Ni-Co/C and Pd/C nanoparticles for glucose electro-oxidation in alkaline half-cell and direct glucose fuel cell”, Electrocatalysis, Vol. 9, 2019, pp.735-743.

[39] B. Wieland, J.P. Lancaster, C.S. Hoaglund, P. Holota, W.J. Tornquist, “Electrochemical and infrared spectroscopic quantitative determination of the platinum-catalyzed ethylene glycol oxidation mechanism at CO adsorption potentials”, Langmuir, Vol. 12, 1996, pp.2594-2601