Synthesis and study of photocatalytic properties of ZnO nanoparticles by the addition of ZnWO4

Subject Areas :

Seyed Ali Hasanzadeh ¹ , Mehdi Emsaki ² , Ali Saffar ³

1 - دانشگاه آزاد اسلامی واحد نجف آباد
2 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran
3 - Advanced Materials Research Center, Department of Materials Engineering, Najafabad Branch, Islamic Azad University, Najafabad, Iran

Received: 2017-07-08 Accepted : 2018-06-25 Published : 2019-12-22

Keywords: nanocomposite, Photocatalysis, Microemulsion, ZnO-ZnWO4,

Abstract :

ZnO (Zinc Oxide) is a whell-known semiconductor that widely used in many industries. In this research, photocatalytic activity of ZnO and nanocomposite resulting from it combination with ZnWO4 were investigated. The effect of adding ZnWO4 to ZnO nanoparticles was studied on the photocatalytic activity of ZnO-ZnWO4 nanocomposites. The water in oil microemulsion method was used to synthesize nanoparticles. and various stoichiometric ratios of this nanocomposite were synthesized to study photocatalytic properties. Characteristic were studied by X-ray diffraction, Field-scattering electron microscopy, Transmitted electron microscopy, and Ultraviolet-absorption spectroscopy. X-ray diffraction results show that ZnO-ZnWO4 nanocomposites with nanocrystals formed and the results of TEM showing the particle size distribution in the range of 40 to 60 nm. The results show that the photocatalytic degradation efficiency of methylene blue by ZnO nanoparticles has been significantly enhanced by the addition of ZnWO4 and the highest degradation efficiency is related to ZnO-30% ZnWO4 nanocomposite with 96.57%.

References:

 [1]     Fujishima, T. N. Rao & D. A. Tryk, “Titanium dioxide photocatalysisˮ, Journal of Photochemistry and Photobiology C, Vol. 1, pp. 1-21, 2000.

 

[2]     S. K. Lee, S. McIntyre & A. Mills, “Visible illustration of the direct lateral and remote photocatalytic destruction of soot by titaniaˮ, Journal of Photochemistry and Photobiology A, Vol. 162, pp. 203-206, 2004.

 

[3]     K. I. Ishibashi, A. Fujishima, T. Watanabe & K. Hashimoto, “Quantum yields of active oxidative species formed on TiO₂ photocatalystˮ, Journal of Photochemistry and Photobiology A, Vol. 134, pp. 139-142, 2000.

 

[4]     Abed, C. Bouzidi, H. Elhouichet, B. Gelloz & M. Ferif, “Mg doping induced high structural quality of sol–gel ZnO nanocrystals application in photocatalysisˮ, Applied Surface Science, Vol. 349, pp. 855-863, 2015.

 

[5]     Gao, H. Fan, X. Zhang & L. Song, “Template-free hydrothermal synthesis and high photocatalytic activity of ZnWO₄ nanorodsˮ, Materials Science and Engineering B, Vol. 177, pp. 1126-1132, 2012.

 

[6]     J. Ke, C. Niu, J. Zhang & G. Zeng, “Significantly enhanced visible light photocatalytic activity and surface plasmon resonance mechanism of Ag/AgCl/ZnWO₄compositeˮ, Journal of Molecular Catalysis A, Vol. 395, pp. 276-282, 2014.

 

[7]     R. Ebrahimi & O. Torabi, “Combination of mechanochemical activation and self-propagating behavior for the synthesis of nanocomposite Al₂O₃/B₄C powderˮ, Journal of Alloys and Compounds, Vol. 514, pp. 54-59, 2012.

 

[8]     S. A. Hassanzadeh Tabrizi & E. Taheri, “Synthesis of high surface area Al₂O₃–CeO₂ composite nanopowder via inverse co-precipitation methodˮ, Ceramics International, Vol. 37, pp. 1251-1257, 2011.

 

[9]     S. Supakanapitak, V. Boonamnuayvitaya & S. Jarudilokkul, “Synthesis of nanocrystalline CeO₂ particles by different emulsion methodsˮ, Materials Characterization, Vol. 67, pp. 83-92, 2012.

 

[10] Dodd, A. McKinley, T. Tsuzuki & M. Saunders, “Mechanochemical synthesis of nanoparticulate ZnO–ZnWO₄ powders and their photocatalytic activityˮ, Journal of the European Ceramic Society, Vol. 29, pp. 139-144, 2009.

 

[11] Hamrouni, N. Mousa, A. D. Paola, F. Parrino, A. Houas & L. Palmisano, “Characterization and photoactivity of coupled ZnO–ZnWO₄ catalysts prepared by a sol–gel methodˮ, Applied Catalysis B: Environmental, Vol. 154, pp. 379-385, 2014.

 

[12] Hamrouni, N. Moussa, A. D. Paola, L. Palmisano, A. Houas & F. Parrino, “Photocatalytic activity of binary and ternary SnO₂–ZnO–ZnWO₄ nanocompositesˮ, Journal of Photochemistry and Photobiology A:Chemistry, Vol. 309, pp. 47-54, 2015.

 

[13] M. V. Arularasu & R. Sundaram, “Synthesis and characterization of nanocrystalline ZnWO₄-ZnO composites and their humidity sensing performanceˮ, Sensing and Bio-Sensing Research, Vol. 11, pp. 20-25, 2016.

 

[14] Huang, T. Lin, K. Chu, Y. Yang & J. Lin, “Field emission properties of zinc oxide/zinc tungstate (ZnO/ZnWO4) composite nanorodsˮ, Surface & Coatings Technology, Vol. 231, pp. 289–292, 2013.

 

[15]    م. کرباسی، ع. نعمتی و م. حسینی زری، "سنتز نانوذرات TiO­₂ به روش میکروامولسیون و بررسی تغییرات ریزساختاری ذرات در حین کلسیناسیون"، نشریه علمی-پژوهشی علوم و فناوری رنگ، شماره 5، ص ص 50-43، 1390.

 

[16] C. Tojo, M. D. Dios & F. Barroso, “Surfactant Effects on Microemulsion-Based Nanoparticle Synthesisˮ, Materials, Vol. 4, pp. 55-72, 2011.

 

[17]    ا. خلیلی فرد، ع. حسن زاده تبریزی و م. نصر اصفهانی، "اثر pH بر خواص جذبی نانوذرات اکسید روی-اکسید کادمیوم برای حذف متیلن بلو و متیل اورانژ"، فصلنامه علمی-پژوهشی فرآیندهای نوین در مهندسی مواد، سال یازدهم، شماره 1، ص ص 42-31، بهار 1396.

 

[18]    ش. شجاعی و ع. حسن زاده تبریزی، "بررسی خواص لومینسنت CaSnO₃ :Sr²⁺ تهیه شده توسط روش میکروامولسیون با استفاده از فعال کننده سطحی تریتون X-100"، فصلنامه علمی-پژوهشی فرآیندهای نوین در مهندسی مواد، سال نهم، شماره 2، ص ص 123-117، تابستان 1394.

 

[19]    ز. مطلق ، ق. خرم‌آبادی، ح. گودینی و ر. چشمه‌ سلطانی، "بررسی کارایی فرآیند فوتوکاتالیستی نانوذرات ZnO بر روی رنگ‌بری متیلن بلو و حذف COD از فاضلاب سینتتیک"، فصلنامه علمی-پژوهشی دانشگاه علوم پزشکی لرستان، شماره 5، ص ص 61-51، زمستان 1391.

 

[20] I. K. Konstantinou & T. A. Albanis, “TiO₂-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations A reviewˮ, Applied Catalysis B: Environmental, Vol. 49, pp. 1-14, 2004.

 

[21]    ز. مطلق، ر. درویشی، ق. خرم‌آبادی، ح. گودینی و م. فروغی، "بررسی عوامل موثر بر رنگ‌بری متیلن بلو با استفاده از پرتودهی فرابنفش در حضور کاتالیست تثبیت شده"، مجله علمی دانشگاه علوم پزشکی ایلام، شماره اول، ص ص 46-36، فروردین 1392.