Design, fabrication and catalytic performance of zeolite CaY functionalized with 4-methylpyridinium chloride ionic liquid as a new multifunctional nanocatalyst in the three-component synthesis of isoxazolones

Subject Areas : شیمی آلی

Mehdi Kalhor ¹ (Department of Chemistry, Payame Noor University, Tehran, 19395-4697, Iran.)
Zeinab Hozhabri ² (Department of Chemistry, Faculty of Basic Sciences, Payam Noor University, Tehran, Iran)
Zahra Seyedzade ³ (Department of Chemistry, Faculty of Basic Sciences, Payam Noor University, Tehran, Iran)

Received: 2022-11-19 Accepted : 2023-01-03 Published : 2023-02-20

Keywords: Ionic liquid, Multi-functional nanocatalyst, three-component synthesis, isoxazolone, Zeolite CaY, 4-methylpyridinium chloride,

Abstract :

In this study, first zeolite CaY was obtained through the reaction of zeolite NaY with CaCl2. Then it was functionalized by reaction with an organic linker, 3-chloropropyl triethoxysilane, followed by reaction with 4-methylpyridine (4-MePyr IL@CaY). The structure and morphology of this new multi-functional nanoporous material were investigated and identified using Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDS), thermogravimetric analysis (TGA-DTA) and Brunaeur-Emmet-Teller (BET) instrumental analyses. The catalytic activity of this multifactorial nanosystem in the easy synthesis of 4-(arylidene)-3-methyl-5-(4H)-isoxazolones was investigated through the three-component condensation reaction of various benzaldehydes, hydroxylamine hydrochloride and ethyl acetate under green conditions. One of the obvious advantages of this nanocatalyst is the presence of Lewis acid (Ca2+) sites and ionic liquid 4-methylpyridinium chloride on a nanoporous solid substrate, which can be very important and instructive in multi-component syntheses. Simplicity of process, catalyst recyclability and easy product separation, high yield and mild conditions are other advantages of this procedure.

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