Investigation of correlation between rheological and physico-mechanical properties of rubber compound based on NR with NR’s Lipid content by ATR-FTIR spectroscopy
Subject Areas :Zohreh Asghari-Barzegar 1 , Saeed Taghvaei-Ganjali 2 , Mercedeh Malekzadeh 3 , Fereshteh Motiee 4
1 - CHEMISTRY DEPARTMENT, TEHRAN NORTH BRANCH, ISLAMIC AZAD UNIVERSITY.TEHRAN, IRAN
2 - Department of Chemistry, Islamic Azad University, Tehran, Iran
3 - CHEMISTRY DEPARTMENT, TEHRAN NORTH BRANCH, ISLAMIC AZAD UNIVERSITY, TEHRAN, IRAN
4 - Depatrment of Chemistry, Islamic Azad University of Tehran North Branch,Tehran, Iran
Keywords: Rheological Properties, Lipid, Physico-Mechanical Properties, Natural rubber, ATR-FTIR Spectroscopy,
Abstract :
In this study correlation between rheological and some physico-mechanical properties of rubber compound based on Natural Rubber (NR) with NR’s lipid content was investigated by simple, fast and non distractive attenuated total reflection Fourier transform infrared (ATR-FTIR) spectroscopy. The results demonstrated that NR’s lipid content had satisfactory correlation with rheological and some physico-mechanical properties of rubber compound based on NR. Also for evaluation of obtained models SMR 20 JU-based rubber compound was selected as case study. The results showed that Ts2, T’c90, viscosity and hardness can be predict by error lower than 5% and the results were acceptable. About CRI and fatigue can be predicted by error lower than 30% and the results might be acceptable, but it depends on the process type. Obtained modeling techniques by ATR-FTIR data can be used as simple, fast and non distractive method with good repeatability for predicting of rheological and physico-mechanical properties of rubber compound based on NR.
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[2] Liengprayoon, S.; Chaiyut, J.; Sriroth, K.; Bonfils, F; Sainte-Beuve, J.; Dubreucq, E.; Vaysse, L.; Eur. J. Lipid Sci.Tech. 115, 1021-1031, 2013.
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[23] Amnuaypornsri, S.; Sakdapipanich, J.; Toki, S.; Hsiao B.S.; Rubber Chem. Technol. 81, 753-766, 2008.
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[26] Motiee, F.; Taghvaei-Ganjali, S.; Malekzadeh, M.; Int. J. Ind. Chem. 4, 1-8, 2013.
[27] Asghari-Barzegar, Z.; Taghvaei-Ganjali, S.; Malekzadeh, M.; Motiee, F.; Rubber Chem. Technol. 94(1), 108-120, 2020.
[28] Grange, J.; PhD thesis, Universite de Bordeaux, Bordeaux, France, 2018.
[29] Morton, M.; “Rubber Technology”, Third edition, Springer, Dordrecht, Netherlands, 1999.
[30] Toki, S.; Hsiao, B.S.; Amnuaypornsri, S.; Sakdapipanich, J.; Polymer. 50, 2142–2148, 2009.
[31] Vaysse, L.; Bonfils, F.; Sainte-Beuve, J.; Cartault, M.; “Natural rubber” in: Matyjaszewski K.; Moller M. (Eds.); “Polymer science: a comprehensive reference”, Elsevier, Netherlands, 281-293, 2012.
_||_[1] Liengprayoon, S.; Bonfils, F.; Sainte‐Beuve, J.; Sriroth, K.; Dubreucq, E.; Vaysse, L.; Eur. J. Lipid Sci.Technol. 110, 563- 569, 2008.
[2] Liengprayoon, S.; Chaiyut, J.; Sriroth, K.; Bonfils, F; Sainte-Beuve, J.; Dubreucq, E.; Vaysse, L.; Eur. J. Lipid Sci.Tech. 115, 1021-1031, 2013.
[3] Rodphukdeekul, S.; Liengprayoon, S.; Santisopasri, V.; Sriroth, K.; Bonfils, F; Dubreucq, E; Vaysee, L; Kasetsart J.; Nat. Sci. 42, 306- 314, 2008.
[4] Kawahara, S.; Kakubo, T.; Sakdapipanich, J.T.; Isono, Y.; Tanaka Y.; Polymer 41, 7483–7488, 2000.
[5] Hasma, H.; Subramaniam, S.; J Nat Rubber Res. 1, 30–40, 1986.
[6] Rolere, S.; Bottier, C.; Vaysse, L.; Sainte-Beuve, J.; Bonfils, F; Express. Polym. Lett. 10(5), 408–419, 2016.
[7] Rolere, S.; Cartault, M.; Sainte-Beuve, J.; Bonfils, F.; Polym. Test. 61, 378-385, 2017.
[8] Rolere, S.; Liengprayoon, S.; Vaysse, L.; Sainte-Beuve, J.; Bonfils, F.; Polym. Test. 43, 83- 93, 2015.
[9] Altman, R.F.A.; Ind. Eng. Chem. 40(2), 241-249, 1948.
[10] Smitthipong, W.; Tantatherdtam, R.; Rungsanthie, K.; Suwanruji, P.; Sriroth, K.; Radabutra, S.; Thanawan, S.; Vallet, M.; Nardin, M.; Mougin, K.; Chollakup, R.; Adv. Matter. Res. 844, 345-348, 2014.
[11] Musigamart, N.; Ph.D. Thesis, University of Montpellier SupAgro, Montpellier, France, 2015.
[12] Siriwong S.; Rungvichaniwat, A.; Klinpituksa, P.; Musa, K.H.; Abdullah, A.; Glo.; Adv. Res. J. Agri. Sci. 70(2), 053-063, 2018.
[13] Kawahara, S.; Tanaka, Y.; J. Polym. Sci. Pol. Phys. 33, 753-758, 1995.
[14] Monadjemi, S.M.A.; McMahan, C.; Cornish, K.; J. Res. Updates Polym. Sci. 5, 87-96, 2016.
[15] Liengprayoon, S.; Ph.D. Thesis, University of Montpellier SupAgro, Montpellier, France, 2008.
[16] Salomez, M.; Subileau, M.; Intapun, J; Bonfils, F.; Sainte-Beuve, J.; Vaysse, L.; Dubreucq, E.; J. Appl. Microbiol. 117, 921-929, 2014.
[17] Amnuaypornsrl, S.; Nimpalboon, A.; Sakdapipanich, J.; KGK Marz. 88-92, 2009.
[18] Nimpaiboon, A.; Amnuaypornsri, S.; Sakdapipanich, J.; Polym. Test. 32, 1135–1144, 2013.
[19] Amnuaypornsri, S.; Toki, S.; Hsiao, B.S.; Sakdapipanich, J.; Polymer. 53, 3325-3330, 2012.
[20] Nimpaiboon, A.; Sakdapipanich, J.; Polym. Test. 32, 1408–1416, 2013.
[21] Ramirez-Cadavid, D.A.; Cornish, K.; Michel Jr, F.C.; Ind. Crop. Prod. 107, 624-640, 2017.
[22] Le, H.H.; Abhijeet, S.; Ilisch, S.; Klehm, J.; Henning, S.; Beiner, M.; Sarkawi, S.S.; Dierkes, W.; Das, A.; Fischer, D.; Stöckelhuber, K. W.; Wiessner. S.; Khatiwada, S.P.; Adhikari, R.; Pham, T.; Heinrich, G.; Radusch, H.J.; Polymer. 55, 4738- 4747, 2014.
[23] Amnuaypornsri, S.; Sakdapipanich, J.; Toki, S.; Hsiao B.S.; Rubber Chem. Technol. 81, 753-766, 2008.
[24] Lee, Y.S.; Lee, W.K.; Cho, S.; Kim, I.; Ha, C.; J. Anal. Appl. Pyrol. 78, 85-94, 2007.
[25] Taghvaei-Ganjali, S.; Motiee, F.; Fotoohi, F.; Rubber Chem. Technol. 81, 297-317, 2008.
[26] Motiee, F.; Taghvaei-Ganjali, S.; Malekzadeh, M.; Int. J. Ind. Chem. 4, 1-8, 2013.
[27] Asghari-Barzegar, Z.; Taghvaei-Ganjali, S.; Malekzadeh, M.; Motiee, F.; Rubber Chem. Technol. 94(1), 108-120, 2020.
[28] Grange, J.; PhD thesis, Universite de Bordeaux, Bordeaux, France, 2018.
[29] Morton, M.; “Rubber Technology”, Third edition, Springer, Dordrecht, Netherlands, 1999.
[30] Toki, S.; Hsiao, B.S.; Amnuaypornsri, S.; Sakdapipanich, J.; Polymer. 50, 2142–2148, 2009.
[31] Vaysse, L.; Bonfils, F.; Sainte-Beuve, J.; Cartault, M.; “Natural rubber” in: Matyjaszewski K.; Moller M. (Eds.); “Polymer science: a comprehensive reference”, Elsevier, Netherlands, 281-293, 2012.