• Home
  • The Quest for Sustainable Catalysis through Transition Metal Doped Carbon-based Single-Atom Catalysts

Share To

Article Url


Manuscript ID : IJC-2205-1935 (R1) Visit : 107 Page: 261 - 282

10.30495/ijc.2022.1959026.1935

Article Type: Original Research

The Quest for Sustainable Catalysis through Transition Metal Doped Carbon-based Single-Atom Catalysts

Subject Areas : Iranian Journal of Catalysis

Chamalki Madhusha 1 , Madhavi de Silva 2 , Imalka Munaweera 3 , Chandani Perera 4 , Nilwala Kottegoda 5

1 - Department of Chemistry, Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.
2 - Department of Chemistry, Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.|Center for Advanced Materials Research (CAMR), Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.
3 - Department of Chemistry, Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.|Instrument Center, Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.
4 - Department of Chemistry, University of Peradeniya, Peradeniya, Sri Lanka.
5 - Department of Chemistry, Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.|Center for Advanced Materials Research (CAMR), Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.

Received: 2022-05-18 Accepted : 2022-08-27 Published : 2022-09-01

Keywords:

Abstract :

References:


  1. Gawande, M.B., K. Ariga, and Y. Yamauchi, Single‐Atom Catalysts. 2021. p. 2101584.
    2.
  2. Jeong, H., et al., Highly durable metal ensemble catalysts with full dispersion for automotive applications beyond single-atom catalysts. Nature Catalysis, 2020. 3(4): p. 368-375.
    3.
  3. Chen, Y., et al., Single-atom catalysts: synthetic strategies and electrochemical applications. Joule, 2018. 2(7): p. 1242-1264.
    4.
  4. Gawande, M.B., P. Fornasiero, and R. Zbořil, Carbon-based single-atom catalysts for advanced applications. ACS Catalysis, 2020. 10(3): p. 2231-2259.
    5.
  5. Ratnayake, S., et al., Combined Zr and Y phosphate coatings reinforced with chemically anchored B2O3 for the oxidation inhibition of carbon fiber. Materialia, 2021. 15: p. 100984.
    6.
  6. Liu, Y., et al., Unravelling the Enigma of Nonoxidative Conversion of Methane on Iron Single‐Atom Catalysts. Angewandte Chemie International Edition, 2020. 59(42): p. 18586-18590.
    7.
  7. Peng, Y., B. Lu, and S. Chen, Carbon‐supported single atom catalysts for electrochemical energy conversion and storage. Advanced Materials, 2018. 30(48): p. 1801995.
    8.
  8. Yang, Y., et al., Recent progress of carbon-supported single-atom catalysts for energy conversion and storage. Matter, 2020. 3(5): p. 1442-1476.
    9.
  9. Fan, M., et al., Improving the catalytic activity of carbon‐supported single atom catalysts by polynary metal or heteroatom doping. Small, 2020. 16(22): p. 1906782.
    10.
  10. Zhuo, H.-Y., et al., Theoretical understandings of graphene-based metal single-atom catalysts: stability and catalytic performance. Chemical Reviews, 2020. 120(21): p. 12315-12341.
    11.
  11. Tang, Y., et al., Theoretical insights into the CO/NO oxidation mechanisms on single-atom catalysts anchored H4, 4, 4-graphyne and H4, 4, 4-graphyne/graphene sheets. Fuel, 2022. 319: p. 123810.
    12.
  12. Hu, L., et al., Density functional calculation of transition metal adatom adsorption on graphene. Physica B: Condensed Matter, 2010. 405(16): p. 3337-3341.
    13.
  13. Wu, M., et al., Stability, electronic, and magnetic behaviors of Cu adsorbed graphene: A first-principles study. Applied Physics Letters, 2009. 94(10): p. 102505.
    14.
  14. Chan, K.T., J. Neaton, and M.L. Cohen, First-principles study of metal adatom adsorption on graphene. Physical Review B, 2008. 77(23): p. 235430.
    15.
  15. Liu, X., et al., Bonding and charge transfer by metal adatom adsorption on graphene. Physical Review B, 2011. 83(23): p. 235411.
    16.
  16. Rivera‐Cárcamo, C. and P. Serp, Single atom catalysts on carbon‐based materials. ChemCatChem, 2018. 10(22): p. 5058-5091.
    17.
  17. Jing, N., et al., Effect of defects on Young's modulus of graphene sheets: a molecular dynamics simulation. Rsc Advances, 2012. 2(24): p. 9124-9129.
    18.
  18. Banhart, F., J. Kotakoski, and A.V. Krasheninnikov, Structural defects in graphene. ACS nano, 2011. 5(1): p. 26-41.
    19.
  19. XIE, P.-Y., et al., Enhanced bonding between noble metal adatoms and graphene with point defects. Acta Physico-Chimica Sinica, 2012. 28(2): p. 331-337.
    20.
  20. Wu, J., et al., Tuning the Electrochemical Reactivity of Boron‐and Nitrogen‐Substituted Graphene. Advanced Materials, 2016. 28(29): p. 6239-6246.
    21.
  21. Qiu, H.J., et al., Nanoporous graphene with single‐atom nickel dopants: an efficient and stable catalyst for electrochemical hydrogen production. Angewandte Chemie International Edition, 2015. 54(47): p. 14031-14035.
    22.
  22. Jiang, K. and H. Wang, Electrocatalysis over graphene-defect-coordinated transition-metal single-atom catalysts. Chem, 2018. 4(2): p. 194-195.
    23.
  23. Chouhan, A., H.P. Mungse, and O.P. Khatri, Surface chemistry of graphene and graphene oxide: A versatile route for their dispersion and tribological applications. Advances in Colloid and Interface Science, 2020: p. 102215.
    24.
  24. Pei, S., et al., Green synthesis of graphene oxide by seconds timescale water electrolytic oxidation. Nature communications, 2018. 9(1): p. 1-9.
    25.
  25. Ren, S., et al., Graphene-supported metal single-atom catalysts: a concise review. Science China Materials, 2020. 63(6): p. 903-920.
    26.
  26. Ma, D., et al., Graphyne as a promising substrate for the noble-metal single-atom catalysts. Carbon, 2015. 95: p. 756-765.
    27.
  27. Liu, R., et al., Nitrogen-doped graphdiyne as a metal-free catalyst for high-performance oxygen reduction reactions. Nanoscale, 2014. 6(19): p. 11336-11343.
    28.
  28. Axet, M.R., et al., Surface coordination chemistry on graphene and two-dimensional carbon materials for well-defined single atom supported catalysts. Advances in Organometallic Chemistry, 2019. 71: p. 53-174.
    29.
  29. Aggarwal, M., et al., Photocatalytic Carbon Dioxide Reduction: Exploring the Role of Ultrathin 2D Graphitic Carbon Nitride (g-C3N4). Chemical Engineering Journal, 2021: p. 131402.
    30.
  30. Yang, M., et al., Structural stability and O2 dissociation on nitrogen-doped graphene with transition metal atoms embedded: A first-principles study. Aip Advances, 2015. 5(6): p. 067136.
    31.
  31. Kong, N., et al., Single Vanadium Atoms Anchored on Graphitic Carbon Nitride as a High-Performance Catalyst for Non-oxidative Propane Dehydrogenation. ACS nano, 2020. 14 (5): p. 5772-5779.
    32.
  32. Li, X.-H. and M. Antonietti, Metal nanoparticles at mesoporous N-doped carbons and carbon nitrides: functional Mott–Schottky heterojunctions for catalysis. Chemical Society Reviews, 2013. 42 (16): p. 6593-6604.
    33.
  33. Nasir, S., et al., Carbon-based nanomaterials/allotropes: A glimpse of their synthesis, properties and some applications. Materials, 2018. 11(2): p. 295.
    34.
  34. Shinohara, H., Endohedral metallofullerenes. Reports on Progress in Physics, 2000. 63(6): p. 843.
    35.
  35. Sun, B.-Y., et al., Entrapping of exohedral metallofullerenes in carbon nanotubes:(CsC60) n@ SWNT nano-peapods. Journal of the American Chemical Society, 2005. 127(51): p. 17972-17973.
    36.
  36. Changgeng, D., et al., Geometric and electronic structures of metal-substituted fullerenes C 59 M (M= Fe, Co, Ni, and Rh). The Journal of chemical physics, 1999. 111(18): p. 8481-8485.
    37.
  37. Stoyanov, S.R., A.V. Titov, and P. Král, Transition metal and nitrogen doped carbon nanostructures. Coordination Chemistry Reviews, 2009. 253(23-24): p. 2852-2871.
    38.
  38. Marco-Martínez, J., et al., Enantioselective Cycloaddition of Münchnones onto [60] Fullerene: Organocatalysis versus Metal Catalysis. Journal of the American Chemical Society, 2014. 136(7): p. 2897-2904.
    39.
  39. Soltani, A., et al., Interaction of hydrogen with Pd-and co-decorated C24 fullerenes: density functional theory study. Synthetic Metals, 2017. 234: p. 1-8.
    40.
  40. He, H., et al., Bioadhesive injectable hydrogel with phenolic carbon quantum dot supported Pd single atom nanozymes as a localized immunomodulation niche for cancer catalytic immunotherapy. Biomaterials, 2022. 280: p. 121272.
    41.
  41. Fan, X., et al., A conjugated porous polymer complexed with a single-atom cobalt catalyst as an electrocatalytic sulfur host for enhancing cathode reaction kinetics. Energy Storage Materials, 2021. 41: p. 14-23.
    42.
  42. Kamiya, K., et al., Platinum-modified covalent triazine frameworks hybridized with carbon nanoparticles as methanol-tolerant oxygen reduction electrocatalysts. Nature Communications, 2014. 5(1): p. 1-6.
    43.
  43. Jiao, S., et al., Point-defect-optimized electron distribution for enhanced electrocatalysis: towards the perfection of the imperfections. Nano Today, 2020. 31: p. 100833.
    44.
  44. Zhang, L., et al., Single-atom catalyst: a rising star for green synthesis of fine chemicals. National Science Review, 2018. 5(5): p. 653-672.
    45.
  45. Singh, B., et al., Single‐atom catalysts: a sustainable pathway for the advanced catalytic applications. Small, 2021. 17(16): p. 2006473.
    46.
  46. Guo, J., et al., A minireview on the synthesis of single atom catalysts. RSC advances, 2022. 12(15): p. 9373-9394.
    47.
  47. Kaiser, S.K., et al., Single-atom catalysts across the periodic table. Chemical reviews, 2020. 120(21): p. 11703-11809.
    48.
  48. Vilé, G., et al., Cover Picture: A Stable Single‐Site Palladium Catalyst for Hydrogenations (Angew. Chem. Int. Ed. 38/2015). Angewandte Chemie International Edition, 2015. 54(38): p. 10987-10987.
    49.
  49. Xi, J., et al., Confined-interface-directed synthesis of Palladium single-atom catalysts on graphene/amorphous carbon. Applied Catalysis B: Environmental, 2018. 225: p. 291-297.
    50.
  50. Reuillard, B., et al., A Poly (cobaloxime)/Carbon Nanotube Electrode: Freestanding Buckypaper with Polymer‐Enhanced H2‐Evolution Performance. Angewandte Chemie, 2016. 128(12): p. 4020-4025.
    51.
  51. Kim, Y.T., et al., Fine size control of platinum on carbon nanotubes: from single atoms to clusters. Angewandte Chemie International Edition, 2006. 45(3): p. 407-411.
    52.
  52. Tran, P.D., et al., Noncovalent modification of carbon nanotubes with pyrene‐functionalized nickel complexes: carbon monoxide tolerant catalysts for hydrogen evolution and uptake. Angewandte Chemie, 2011. 123(6): p. 1407-1410.
    53.
  53. Georgakilas, V., et al., Noncovalent functionalization of graphene and graphene oxide for energy materials, biosensing, catalytic, and biomedical applications. Chemical reviews, 2016. 116(9): p. 5464-5519.
    54.
  54. He, X., et al., Mechanochemical kilogram-scale synthesis of noble metal single-atom catalysts. Cell Reports Physical Science, 2020. 1(1): p. 100004.
    55.
  55. Chen, X., et al., Highly active and stable single iron site confined in graphene nanosheets for oxygen reduction reaction. Nano Energy, 2017. 32: p. 353-358.
    56.
  56. Cui, X., et al., A graphene composite material with single cobalt active sites: a highly efficient counter electrode for dye‐sensitized solar cells. Angewandte Chemie International Edition, 2016. 55(23): p. 6708-6712.
    57.
  57. Robertson, A.W., et al., Spatial control of defect creation in graphene at the nanoscale. Nature communications, 2012. 3(1): p. 1-7.
    58.
  58. Robertson, A.W., et al., Dynamics of single Fe atoms in graphene vacancies. Nano letters, 2013. 13(4): p. 1468-1475.
    59.
  59. Wang, H., et al., Doping monolayer graphene with single atom substitutions. Nano letters, 2012. 12(1): p. 141-144.
    60.
  60. Wang, H., et al., Interaction between single gold atom and the graphene edge: A study via aberration-corrected transmission electron microscopy. Nanoscale, 2012. 4(9): p. 2920-2925.
    61.
  61. Chen, Y.N., X. Zhang, and Z. Zhou, Carbon‐based substrates for highly dispersed nanoparticle and even single‐atom electrocatalysts. Small Methods, 2019. 3(9): p. 1900050.
    62.
  62. Wang, L., et al., Preparation, characterization and catalytic performance of single-atom catalysts. Chinese Journal of Catalysis, 2017. 38(9): p. 1528-1539.
    63.
  63. Song, Z., et al., Recent Advances in MOF‐Derived Single Atom Catalysts for Electrochemical Applications. Advanced Energy Materials, 2020. 10(38): p. 2001561.
    64.
  64. Kaneti, Y.V., et al., Nanoarchitectured design of porous materials and nanocomposites from metal‐organic frameworks. Advanced materials, 2017. 29(12): p. 1604898.
    65.
  65. Zhao, S.-N., et al., Highly efficient heterogeneous catalytic materials derived from metal-organic framework supports/precursors. Coordination Chemistry Reviews, 2017. 337: p. 80-96.
    66.
  66. Ma, T.Y., et al., Metal–organic framework derived hybrid Co3O4-carbon porous nanowire arrays as reversible oxygen evolution electrodes. Journal of the American Chemical Society, 2014. 136(39): p. 13925-13931.
    67.
  67. Jiao, L. and H.-L. Jiang, Metal-organic-framework-based single-atom catalysts for energy applications. Chem, 2019. 5(4): p. 786-804.
    68.
  68. Zhou, D., et al., Atomic regulation of metal-organic framework derived carbon-based single-atom catalysts for electrochemical CO 2 reduction reaction. Journal of Materials Chemistry A, 2021.
    69.
  69. Zou, L., et al., Single‐Atom Catalysts Derived from Metal–Organic Frameworks for Electrochemical Applications. Small, 2021. 17(16): p. 2004809.
    70.
  70. Yin, P., et al., Single cobalt atoms with precise N‐coordination as superior oxygen reduction reaction catalysts. Angewandte Chemie, 2016. 128(36): p. 10958-10963.
    71.
  71. Zhang, F., et al., In situ mosaic strategy generated Co-based N-doped mesoporous carbon for highly selective hydrogenation of nitroaromatics. Journal of Catalysis, 2017. 348: p. 212-222.
    72.
  72. Wang, J., et al., Design of N-coordinated dual-metal sites: a stable and active Pt-free catalyst for acidic oxygen reduction reaction. Journal of the American Chemical Society, 2017. 139(48): p. 17281-17284.
    73.
  73. Xia, Y., Z. Yang, and R. Mokaya, Templated nanoscale porous carbons. Nanoscale, 2010. 2(5): p. 639-659.
    74.
  74. Liang, H.-W., et al., Mesoporous metal–nitrogen-doped carbon electrocatalysts for highly efficient oxygen reduction reaction. Journal of the American Chemical Society, 2013. 135(43): p. 16002-16005.
    75.
  75. Zhang, N., et al., Single-atom site catalysts for environmental catalysis. Nano Research, 2020: p. 1-18.
    76.
  76. Sun, S., et al., Single-atom catalysis using Pt/graphene achieved through atomic layer deposition. Scientific reports, 2013. 3(1): p. 1-9.
    77.
  77. Yan, H., et al., Single-atom Pd1/graphene catalyst achieved by atomic layer deposition: remarkable performance in selective hydrogenation of 1, 3-butadiene. Journal of the American chemical society, 2015. 137(33): p. 10484-10487.
    78.
  78. Zhang, Q. and J. Guan, Single‐atom catalysts for electrocatalytic applications. Advanced Functional Materials, 2020. 30(31): p. 2000768.
    79.
  79. Zhao, Y., R. Tang, and R. Huang, Palladium supported on graphitic carbon nitride: an efficient and recyclable heterogeneous catalyst for reduction of nitroarenes and Suzuki coupling reaction. Catalysis Letters, 2015. 145(11): p. 1961-1971.
    80.
  80. Shang, Y., et al., Carbon-based single atom catalyst: Synthesis, characterization, DFT calculations. Chinese Chemical Letters, 2021.
    81.
  81. Tavakkoli, M., et al., Mesoporous Single-Atom-Doped Graphene–Carbon Nanotube Hybrid: Synthesis and Tunable Electrocatalytic Activity for Oxygen Evolution and Reduction Reactions. ACS Catalysis, 2020. 10(8): p. 4647-4658.
    82.
  82. Li, H., et al., Carbon-supported metal single atom catalysts. New Carbon Materials, 2018. 33(1): p. 1-11.
    83.
  83. Zhang, H., et al., Single‐atom catalysts: emerging multifunctional materials in heterogeneous catalysis. Advanced Energy Materials, 2018. 8(1): p. 1701343.
    84.
  84. Fu, X., et al., In situ polymer graphenization ingrained with nanoporosity in a nitrogenous electrocatalyst boosting the performance of polymer‐electrolyte‐membrane fuel cells. Advanced Materials, 2017. 29(7): p. 1604456.
    85.
  85. Chung, H.T., et al., Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst. Science, 2017. 357(6350): p. 479-484.
    86.
  86. Mahanta, U., et al., Ionic-liquid-based deep eutectic solvents as novel electrolytes for supercapacitors: COSMO-SAC predictions, synthesis, and characterization. ACS Sustainable Chemistry & Engineering, 2019. 8(1): p. 372-381.
    87.
  87. Veena Gopalan, E., et al., Template-assisted synthesis and characterization of passivated nickel nanoparticles. Nanoscale research letters, 2010. 5(5): p. 889-897.
    88.
  88. Zhao, S., et al., Controlled One‐pot Synthesis of Nickel Single Atoms Embedded in Carbon Nanotube and Graphene Supports with High Loading. ChemNanoMat, 2020. 6(7): p. 1063-1074.
    89.
  89. Chen, Z., et al., Single‐Atom Catalysis: From Simple Reactions to the Synthesis of Complex Molecules. Advanced Materials, 2021: p. 2103882.
    90.
  90. Ding, S., et al., High-temperature flame spray pyrolysis induced stabilization of Pt single-atom catalysts. Applied Catalysis B: Environmental, 2021. 281: p. 119471.
    91.
  91. Yang, X.-F., et al., Single-atom catalysts: a new frontier in heterogeneous catalysis. Accounts of chemical research, 2013. 46(8): p. 1740-1748.
    92.
  92. Asokan, C., L. DeRita, and P. Christopher, Using probe molecule FTIR spectroscopy to identify and characterize Pt-group metal based single atom catalysts. Chinese Journal of Catalysis, 2017. 38(9): p. 1473.
    93.
  93. Bakandritsos, A., et al., Mixed‐Valence Single‐Atom Catalyst Derived from Functionalized Graphene. Advanced Materials, 2019. 31(17): p. 1900323.
    94.
  94. Choi, W.I., et al., Combinatorial Search for high‐activity hydrogen catalysts based on transition‐metal‐embedded graphitic carbons. Advanced Energy Materials, 2015. 5(23): p. 1501423.
    95.
  95. Xiao, M., et al., Solar energy conversion on g-C3N4 photocatalyst: light harvesting, charge separation, and surface kinetics. Journal of energy chemistry, 2018. 27(4): p. 1111-1123.
    96.
  96. Gao, C., et al., Heterogeneous single-atom photocatalysts: Fundamentals and applications. Chemical reviews, 2020. 120(21): p. 12175-12216.
    97.
  97. Wang, Q., et al., Single-atom catalysts for photocatalytic reactions. ACS Sustainable Chemistry & Engineering, 2019. 7(7): p. 6430-6443.
    98.
  98. Zhou, P., et al., Metal single atom strategy greatly boosts photocatalytic methyl activation and C–C coupling for the coproduction of high-value-added multicarbon compounds and hydrogen. ACS Catalysis, 2020. 10(16): p. 9109-9114.
    99.
  99. Chu, C., et al., Spatially separating redox centers on 2D carbon nitride with cobalt single atom for photocatalytic H2O2 production. Proceedings of the National Academy of Sciences, 2020. 117(12): p. 6376-6382.
    100.
  100. Zhao, Q., et al., Effective and durable Co single atomic cocatalysts for photocatalytic hydrogen production. ACS applied materials & interfaces, 2017. 9(49): p. 42734-42741.
    101.
  101. Lin, C., et al., Porphyrin-Based Metal–Organic Frameworks for Efficient Photocatalytic H2 Production under Visible-Light Irradiation. Inorganic Chemistry, 2021. 60(6): p. 3988-3995.
    102.
  102. Roy, S. and E. Reisner, Visible‐Light‐Driven CO2 Reduction by Mesoporous Carbon Nitride Modified with Polymeric Cobalt Phthalocyanine. Angewandte Chemie International Edition, 2019. 58(35): p. 12180-12184.
    103.
  103. Wang, K., et al., Molten salt assistant synthesis of three-dimensional cobalt doped graphitic carbon nitride for photocatalytic N2 fixation: experiment and DFT simulation analysis. Chemical Engineering Journal, 2019. 368: p. 896-904.
    104.
  104. Guo, X.-W., et al., Single-atom molybdenum immobilized on photoactive carbon nitride as efficient photocatalysts for ambient nitrogen fixation in pure water. Journal of Materials Chemistry A, 2019. 7(34): p. 19831-19837.
    105.
  105. Zeng, Z., et al., Single-atom platinum confined by the interlayer nanospace of carbon nitride for efficient photocatalytic hydrogen evolution. Nano Energy, 2020. 69: p. 104409.
    106.
  106. Wang, F., et al., The facile synthesis of a single atom-dispersed silver-modified ultrathin gC 3 N 4 hybrid for the enhanced visible-light photocatalytic degradation of sulfamethazine with peroxymonosulfate. Dalton Transactions, 2018. 47(20): p. 6924-6933.
    107.
  107. Qiu, S., et al., Carbon dots decorated ultrathin CdS nanosheets enabling in-situ anchored Pt single atoms: A highly efficient solar-driven photocatalyst for hydrogen evolution. Applied Catalysis B: Environmental, 2019. 259: p. 118036.
    108.
  108. Ma, M., et al., Role of N in Transition‐Metal‐Nitrides for Anchoring Platinum‐Group Metal Atoms toward Single‐Atom Catalysis. Small Methods, 2022: p. 2200295.
    109.
  109. Gao, G., et al., Single atom (Pd/Pt) supported on graphitic carbon nitride as an efficient photocatalyst for visible-light reduction of carbon dioxide. Journal of the American Chemical Society, 2016. 138(19): p. 6292-6297.
    110.
  110. Wang, F., et al., Novel ternary photocatalyst of single atom-dispersed silver and carbon quantum dots co-loaded with ultrathin g-C3N4 for broad spectrum photocatalytic degradation of naproxen. Applied catalysis B: environmental, 2018. 221: p. 510-520.
    111.
  111. Ye, X., Y. Cui, and X. Wang, Ferrocene‐Modified Carbon Nitride for Direct Oxidation of Benzene to Phenol with Visible Light. ChemSusChem, 2014. 7(3): p. 738-742.
    112.
  112. Yang, J., et al., Electronic Metal–Support Interaction of Single‐Atom Catalysts and Applications in Electrocatalysis. Advanced Materials, 2020. 32(49): p. 2003300.
    113.
  113. Lu, B., Q. Liu, and S. Chen, Electrocatalysis of single-atom sites: impacts of atomic coordination. ACS Catalysis, 2020. 10(14): p. 7584-7618.
    114.
  114. Umer, M., et al., Machine learning assisted high-throughput screening of transition metal single atom based superb hydrogen evolution electrocatalysts. Journal of Materials Chemistry A, 2022. 10(12): p. 6679-6689.
    115.
  115. Hu, J., et al., Carbon-based Single Atom Catalysts for Tailoring ORR Pathway: A Concise Review. Journal of Materials Chemistry A, 2021.
    116.
  116. Pu, Z., et al., Single-atom catalysts for electrochemical hydrogen evolution reaction: recent advances and future perspectives. Nano-Micro Letters, 2020. 12(1): p. 1-29.
    117.
  117. Fan, L., et al., Atomically isolated nickel species anchored on graphitized carbon for efficient hydrogen evolution electrocatalysis. Nature communications, 2016. 7(1): p. 1-7.
    118.
  118. Chen, X., et al., Multiscale porous single-atom Co catalysts for epoxidation with O 2. Journal of Materials Chemistry A, 2022. 10(11): p. 6016-6022.
    119.
  119. Fei, H., et al., Atomic cobalt on nitrogen-doped graphene for hydrogen generation. Nature communications, 2015. 6(1): p. 1-8.
    120.
  120. Zitolo, A., et al., Identification of catalytic sites for oxygen reduction in iron-and nitrogen-doped graphene materials. Nature materials, 2015. 14(9): p. 937-942.
    121.
  121. Zhang, X., et al., Catalytically active single-atom niobium in graphitic layers. Nature communications, 2013. 4(1): p. 1-7.
    122.
  122. Guo, J., et al., Ultrasmall tungsten carbide catalysts stabilized in graphitic layers for high-performance oxygen reduction reaction. Nano Energy, 2016. 28: p. 261-268.
    123.
  123. Zhang, Z., et al., Facile synthesis of a Ru-dispersed N-doped carbon framework catalyst for electrochemical nitrogen reduction. Catalysis Science & Technology, 2020. 10(5): p. 1336-1342.
    124.
  124. Sun, T., et al., Single-atomic cobalt sites embedded in hierarchically ordered porous nitrogen-doped carbon as a superior bifunctional electrocatalyst. Proceedings of the National Academy of Sciences, 2018. 115(50): p. 12692-12697.
    125.
  125. Cao, L., et al., Identification of single-atom active sites in carbon-based cobalt catalysts during electrocatalytic hydrogen evolution. Nature Catalysis, 2019. 2(2): p. 134-141.
    126.
  126. Deng, D., et al., A single iron site confined in a graphene matrix for the catalytic oxidation of benzene at room temperature. Science advances, 2015. 1(11): p. e1500462.
    127.
  127. Vidal, S., et al., Fullerenes for catalysis: metallofullerenes in hydrogen transfer reactions. Chemical Communications, 2017. 53(35): p. 4842-4844.
    128.
  128. Jin, C., et al., Single-atom nickel confined nanotube superstructure as support for catalytic wet air oxidation of acetic acid. Communications Chemistry, 2019. 2(1): p. 1-7.
    129.
  129. Zhang, B., et al., Stabilizing a platinum1 single‐atom catalyst on supported phosphomolybdic acid without compromising hydrogenation activity. Angewandte Chemie, 2016. 128(29): p. 8459-8463.
    130.
  130. Mitchell, S., E. Vorobyeva, and J. Pérez‐Ramírez, The multifaceted reactivity of single‐atom heterogeneous catalysts. Angewandte Chemie International Edition, 2018. 57(47): p. 15316-15329.
    131.
  131. Erünal, E., et al., Enhancement of hydrogen storage capacity of multi-walled carbon nanotubes with palladium doping prepared through supercritical CO2 deposition method. International Journal of Hydrogen Energy, 2018. 43(23): p. 10755-10764.
    132.
  132. Li, M., et al., Highly efficient single atom cobalt catalyst for selective oxidation of alcohols. Applied Catalysis A: General, 2017. 543: p. 61-66.
    133.
  133. He, W.-L., et al., Suspending ionic single-atom catalysts in porphyrinic frameworks for highly efficient aerobic oxidation at room temperature. Journal of catalysis, 2018. 358: p. 43-49.
    134.
  134. Lee, M., S. Ko, and S. Chang, Highly selective and practical hydrolytic oxidation of organosilanes to silanols catalyzed by a ruthenium complex. Journal of the American Chemical Society, 2000. 122(48): p. 12011-12012.
    135.
  135. Sen, R., D. Saha, and S. Koner, Lanthanide carboxylate frameworks: efficient heterogeneous catalytic system for epoxidation of olefins. Catalysis letters, 2012. 142(1): p. 124-130.
    136.
  136. Sofer, Z., et al., Uranium-and thorium-doped graphene for efficient oxygen and hydrogen peroxide reduction. ACS nano, 2014. 8(7): p. 7106-7114.
    137.
  137. Liu, J.-C., et al., Theoretical understanding of the stability of single-atom catalysts. National Science Review, 2018. 5(5): p. 638-641.
    138.
  138. Wang, H., et al., Surpassing the single-atom catalytic activity limit through paired Pt-O-Pt ensemble built from isolated Pt 1 atoms. Nature communications, 2019. 10(1): p. 1-12.
    139.

Sanad

Sanad is a platform for managing Azad University publications

Links

Related Centers

Technical Support

Official pages

The rights to this website are owned by the Raimag Press Management System.
Copyright © 2021-2024

Home| Login| About Us| Contact Us|
[فارسی] [العربية] [fa] [ar]