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عنوان URL للمقالة


رقم المقالة : IJC-2205-1935 (R1) زيارة : 50 الصفحة: 261 - 282

10.30495/ijc.2022.1959026.1935

نوع المخطوط: ابحاث

The Quest for Sustainable Catalysis through Transition Metal Doped Carbon-based Single-Atom Catalysts

الموضوعات : Iranian Journal of Catalysis

Chamalki Madhusha 1 (Department of Chemistry, Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.)
Madhavi de Silva 2 (Department of Chemistry, Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.|Center for Advanced Materials Research (CAMR), Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.)
Imalka Munaweera 3 (Department of Chemistry, Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.|Instrument Center, Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.)
Chandani Perera 4 (Department of Chemistry, University of Peradeniya, Peradeniya, Sri Lanka.)
Nilwala Kottegoda 5 (Department of Chemistry, Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.|Center for Advanced Materials Research (CAMR), Faculty of Applied Sciences, University of Sri Jayewardenepura, Gangodawila, Nugegoda, Sri Lanka.)

تاريخ الإرسال : 17 الأربعاء , شوال, 1443 تاريخ التأكيد : 29 السبت , محرم, 1444 تاريخ الإصدار : 05 الخميس , صفر, 1444

الکلمات المفتاحية: Graphene, Fullerene, Transition metals, Single-atom catalyst, Carbon-based single-atom catalysts, Sustainable catalysis,

ملخص المقالة :

Single-atom catalysts have recently received much scientific attraction as sustainable catalysts due to their greater activity and selectivity arising from the uniform distribution, electronic properties, and quantum mechanical interactions at the nanoscale of single atoms coupled with interactions at the metal-support interfaces. Carbon-based materials are an excellent support material for single-atom catalysts owing to their inherent properties such as adjustable pore size, high surface area to volume ratio, and ease of surface functionalization. The interactions at the single atom-carbon support interfaces give rise to the extraordinary catalytic activity in carbon-based single metal catalysts thus opening doors for a wide range of sustainable applications. This review focuses on the evolution of carbon-based single-atom catalysis covering different types of carbon substrates, usage of different single atoms with special attention to transition metals, and its wide range of applications including photocatalysis, organic catalysis, and electrocatalysis followed by the future perspectives on carbon-based single-atom catalysts.

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