Number 2 Volume 2

Open Access Article

1 - A Novel, Heterogeneous Catalyst for the One-Pot Synthesis of 1,8-Dioxodecahydroacridine Derivatives Under Solvent-Free Conditions
Tayebeh Sanaeishoar Mitra Saremi

An efficient and environmental-friendly synthetic route to 1,8-dioxodecahydroacridines derivatives have been developed via multi-component one-pot Hantzsch reaction of various aldehydes and ammonium acetate with 2 equivalents dimedone in the presence of Phosphorus pento More

An efficient and environmental-friendly synthetic route to 1,8-dioxodecahydroacridines derivatives have been developed via multi-component one-pot Hantzsch reaction of various aldehydes and ammonium acetate with 2 equivalents dimedone in the presence of Phosphorus pentoxide supported on aluminaas catalyst under solvent-free conditions. The present approach offersseveral advantages such as short reaction times, easy isolation and purification of product, and safe, non-toxic, recyclable and economic use of catalyst. Manuscript profile

Open Access Article

2 - Synthesis of 1,8-dioxo-octahydroxanthenes under solvent-free conditions via Phosphorus pentoxide supported on alumina (P2O5/Al2O3) catalyzed tandem reaction of Aldehyde with dimedone
Tayebeh Sanaeishoar Negar Hormozinezhad

Phosphorus pentoxide used on alumina (P2O5/Al2O3) as an inexpensive, eco-friendly and non-toxic acid catalyst for the one-pot synthesis of 1,8-dioxo-octahydroxanthenes via multi-component reactions under solvent-free conditions. The present approach offers several advan More

Phosphorus pentoxide used on alumina (P2O5/Al2O3) as an inexpensive, eco-friendly and non-toxic acid catalyst for the one-pot synthesis of 1,8-dioxo-octahydroxanthenes via multi-component reactions under solvent-free conditions. The present approach offers several advantages such as short reaction times, high yields, easy purification, recovery and reusability of the catalyst. Manuscript profile

Open Access Article

3 - Investigation into the regioisomeric composition of some fused tetrazoles
Paria Nasehi Omid Baravaye Sanaz Hafezi Birgani Mohsen Nikpour

Treatment of 7-chloro-1-phenylpyrimido[4,5-e][1,3,4]thiadiazines with hydrazine in boiling ethanol gave corresponding7-hydrazinyl derivatives. Diazotization of the latter compounds acheived a mixture of 5H-tetrazolo[1',5':1,2]pyrimido[4,5-e][1,3,4]thiadiazine and 9H-tet More

Treatment of 7-chloro-1-phenylpyrimido[4,5-e][1,3,4]thiadiazines with hydrazine in boiling ethanol gave corresponding7-hydrazinyl derivatives. Diazotization of the latter compounds acheived a mixture of 5H-tetrazolo[1',5':1,2]pyrimido[4,5-e][1,3,4]thiadiazine and 9H-tetrazolo[5',1':2,3]pyrimido[4,5-e][1,3,4]thiadiazines. Ratio of these two group of products determined by 1HNMR studies and no significant preference was observed for their formation. Efforts for separation of the products were unsuccessful and its reason is discussed. Manuscript profile

Open Access Article

4 - Manganese salophen complex supported on magnetic nanoparticles as an efficient, selective and recyclable catalyst for epoxidation of alkenes
Mozhgan Afshari Maryam Gorjizadeh Simin Nazari

A magnetically recoverable catalyst consisting of Mn (III) salophen complex was prepared. The synthesized catalyst was characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), inductively coupled plasm More

A magnetically recoverable catalyst consisting of Mn (III) salophen complex was prepared. The synthesized catalyst was characterized by X-ray powder diffraction (XRD), transmission electron microscopy (TEM), vibrating sample magnetometry (VSM), inductively coupled plasma atomic emission spectroscopy (ICP-AES) and Fourier transform infrared (FT-IR). The immobilized catalyst was shown to be an efficient heterogeneous catalyst for the epoxidation of various alkenes using hydrogen peroxide (H2O2) as oxidant. The catalyst could be easily and efficiently isolated from the final product solution by magnetic decantation and be reused for 5 consecutive reactions without showing any significant activity degradation. Manuscript profile

Open Access Article

5 - Interaction of Prolin, Leucine and methylurea with inorganic cluster [(PO4)M12O36].nH2O; (M = Mo, W)
Paria Nasehi Saeide Sayyahi Zahra Naeimavi Mohsen Nikpour

Three new inorganic-organic hybrid materials based on heteropolyoxometalates, [L-C6H14NO2]3[(PO4)Mo12O36].3H2O (1), [L-C5H10NO2]3[(PO4)W12O36].H2O (2), and [C2H7N2O]3[(PO4)W12O36]. 4H2O (3), where C6H14NO2, C5H10NO2, and C2H7N2O are protonated L-leucine, L-proline, and More

Three new inorganic-organic hybrid materials based on heteropolyoxometalates, [L-C6H14NO2]3[(PO4)Mo12O36].3H2O (1), [L-C5H10NO2]3[(PO4)W12O36].H2O (2), and [C2H7N2O]3[(PO4)W12O36]. 4H2O (3), where C6H14NO2, C5H10NO2, and C2H7N2O are protonated L-leucine, L-proline, and methylurea, respectively, have been synthesized and structurally characterized by some physico-chemical methods. Elemental analyses, IR, Raman, mass, UV, and 1H NMR spectroscopies of the title hybrid materials indicate that there are van der Waals interactions between O atoms of the heteropolyoxometalates and water molecules, as well as the N and O atoms of the amino acids and methyl urea moieties. The molecular structures of synthesized hybrid materials contain discrete entities of L-leucinium, L-prolinium or methyluronium and water molecules that surround every [(PO4)M12O36]3- anion, over the extended crystalline network. The observed bands in Raman spectra of 2 and 3 demonstrate that [(PO4)W12O36]3- anion retains its “Keggin structure”. Between pH =7 and pH =4 the characteristic bands of the Keggin anion [(PO4)M12O36]3−(M = Mo, W) appear at 210 and 260 nm in the UV spectra, respectively. Manuscript profile

Open Access Article

6 - Synthesis and Application of New Oxidant bis(banzyltriphenylphosphonium) peroxodisulfate on Oxidation of Benzylhalides to Corresponding Benzylaldehyde Compounds
Rashid Badri Seid Sina Mohsenin Elham Tahanpesar

Put the peroxodisulfate ion (S2O82-) in the phase transfer catalyst banzyltriphenylphosphonium can make a catalyst with mild oxidation property, and used it for oxidation of Benzylhalides to corresponding Benzylaldehyde Compounds. For making catalyst used xylene and wat More

Put the peroxodisulfate ion (S2O82-) in the phase transfer catalyst banzyltriphenylphosphonium can make a catalyst with mild oxidation property, and used it for oxidation of Benzylhalides to corresponding Benzylaldehyde Compounds. For making catalyst used xylene and water as solvent, and it was an easy process with high yield. Oxidation used in reflux condition with acetonitrile as solvent. The advantages of this oxidation: high yield and short time. Manuscript profile

Open Access Article

7 - AlCl3 supported on nano silica as an efficient catalyst for the preparation of coumarin
Leila Sarami Elham Tahanpesar

The Pechmann condensation has been used as a simple and efficient method for the preparation of coumarin derivatives, which phenols and ethyl acetoacetate were reacted in the presence of AlCl3 supported on nano silica as an efficient catalyst at 110 oC under solvent fre More

The Pechmann condensation has been used as a simple and efficient method for the preparation of coumarin derivatives, which phenols and ethyl acetoacetate were reacted in the presence of AlCl3 supported on nano silica as an efficient catalyst at 110 oC under solvent free condition to form products with good to excellent yield (55 -90%), which are identified by spectroscopic method ( FT-IR, NMR) and melting points and compared with reference samples. Manuscript profile

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