-
حرية الوصول المقاله
1 - Effect of Eu doping on the structure, morphology and luminescence properties of ZnO submicron rod for white LED applications
Mei XinAbstractEu3+-doped ZnO submicron rod has been prepared by a hydrothermal method. Synthesized rods are characterized by X-ray diffraction, scanning electron microscopy and photoluminescence spectra (PL). The results indicated structures and morphology of rods affected by أکثرAbstractEu3+-doped ZnO submicron rod has been prepared by a hydrothermal method. Synthesized rods are characterized by X-ray diffraction, scanning electron microscopy and photoluminescence spectra (PL). The results indicated structures and morphology of rods affected by the Eu3+ doping concentration. 5D0–7FJ (J = 1, 2 and 3) of Eu3+ emission appeared, and energy transfer from the ZnO host and deep defects of ZnO to Eu3+ in the ZnO:Eu is occurred. Strong and white emission was observed in the sample with 15% Eu. تفاصيل المقالة -
حرية الوصول المقاله
2 - Improve Synthesis of Iron Oxide Nanorode with Hydrothermal Method
M. Aghazadeh Fatemeh AghazadehMaghemite and magnetite nanoparticles and nanorode are now losing interests in the field of nanobiotechnology and pharmaceutical for their applications. This paper reports on a hydrothermal process for the synthesis of Fe2 O3 in the γ-phases nanorodes, when the hy أکثرMaghemite and magnetite nanoparticles and nanorode are now losing interests in the field of nanobiotechnology and pharmaceutical for their applications. This paper reports on a hydrothermal process for the synthesis of Fe2 O3 in the γ-phases nanorodes, when the hydrothermal temperature was 100 ̊ C. The uniqueness of the method lies in the use of ferrous ammonium sulphate, hexamine was added as the stabilizer and hydrolyzing agents. The crystal structure, shape particle and magnetic properties of the samples were determined by X-ray diffraction (XRD) and Transmission electron microscopy (TEM) and magnetometer (AGFM), respectively. The particle size was 60nm and length in the range of 300nm. The magnetic behavior of the particles was like the typical behavior of superparamagnetic particles, so smaller particles can improve the magnetic properties and decreasing the coercivity. تفاصيل المقالة -
حرية الوصول المقاله
3 - Optimization of Nanocrystals NaX Zeolite Synthesis with Different Silica Sources
Mansoor Anbia Farideh BandarchianThe effects of varying the silica source on synthesis of NaX zeolite crystals via conventional hydrothermal method have been investigated. Five different silica sources were selected while other parameters like Al source, reaction and aging time, SiO2/Al2O3molar ratio أکثرThe effects of varying the silica source on synthesis of NaX zeolite crystals via conventional hydrothermal method have been investigated. Five different silica sources were selected while other parameters like Al source, reaction and aging time, SiO2/Al2O3molar ratio and temperature were same. The prepared products were characterized by XRD technique. The results showed that different crystallites, different conversion rates and different amounts of impurity phase in the synthesized NaX zeolite. For more evidence the best obtained powder of NaX zeolite nanoparticles was checked by FTIR, SEM, TGA, and BET analysis. The corresponding sample had a good agreement with standard IR peaks, octahedral nanocrystals of zeolite X, thermal stability up to 800°C, surface area 751.88 m2/g and total pore Volume 0.3599 cm3/g respectively. Therefore, it can be concluded that the use of different silica sources significantly influence the synthesized products. تفاصيل المقالة -
حرية الوصول المقاله
4 - Synthesis of cobalt oxide and cobalt ferrite nanoparticles by hydrothermal method and investigation of tensile properties of polymer matrix composites made with these nanoparticles
Ayfan Salah Hassan Mohammad Moarrefi romeileh Azadeh AezamiThe hydrothermal method synthesized the first cobalt ferrite and cobalt oxide nanoparticles in this article. The synthesized nanoparticles were then subjected to various analyzes such as X-ray diffraction patterns, scanning electron microscopy images, infrared spectrosc أکثرThe hydrothermal method synthesized the first cobalt ferrite and cobalt oxide nanoparticles in this article. The synthesized nanoparticles were then subjected to various analyzes such as X-ray diffraction patterns, scanning electron microscopy images, infrared spectroscopy, and vibration sample magnetometer to ensure their properties and prepare the nanoparticles for the next step. Then, 6% by weight of nanoparticles were added to the epoxy resin as a reinforce, and a polymer matrix composite was made. After making the composites according to the ASTM D638 standard, they were subjected to a tensile test. The results showed that the nanoparticles were prepared very fine, uniform, high purity, and had good magnetic properties. Also, hydrothermal was a suitable method for the synthesis of these nanoparticles. Furthermore, samples made using cobalt ferrite nanoparticles offer better tensile properties than samples made with cobalt oxide. However, in general, the tensile properties of composites have improved compared to pure polymers. تفاصيل المقالة -
حرية الوصول المقاله
5 - Making epoxy/copper ferrite and copper hydroxide composite using nanoparticles synthesized by hydrothermal and ultrasonic method and checking the thermal properties of composites
Elaf ayad Kamel Aljahlavi Mohammad Moarrefi Romeileh Azadeh Azami GheymasiIn this research, nanoparticles of copper ferrite was synthesized by hydrothermal method and nanoparticles of copper hydroxide was synthesized by ultrasonic method. Then, to check the properties of these nanoparticles, analyzes such as X-ray diffraction pattern (XRD), s أکثرIn this research, nanoparticles of copper ferrite was synthesized by hydrothermal method and nanoparticles of copper hydroxide was synthesized by ultrasonic method. Then, to check the properties of these nanoparticles, analyzes such as X-ray diffraction pattern (XRD), scanning electron microscope (SEM), vibrating sample magnetometry (VSM) and infrared spectroscopy (IR) were taken. The results of analyzes showed that the nanoparticles were prepared in a completely uniform, fine and homogeneous manner and no agglomeration was seen in them. In addition, these nanoparticles had good magnetic properties and the peaks of the X-ray diffraction pattern were consistent with the standard peaks. In the next step, 5% by weight of copper ferrite and copper hydroxide nanoparticles were added to the epoxy resin and then mixed together by a stirrer. In the next step, the epoxy resin was subjected to ultrasonic waves and after the complete distribution of nanoparticles in the field, it was placed in the vacuum chamber for bubble removal and finally poured into the mold. Finally, various tests were taken from the composites, such as: thermal properties test (TGA) and flame resistance test (UL-94). تفاصيل المقالة -
حرية الوصول المقاله
6 - Low Temperature Hydrothermal Synthesis and Characterization and Optical Properties of Sr5Nb4O15 – Nb2O5 Nanocomposite
Sh. Khademinia M. Behzad A. Alemi M. DolatyariSr5Nb4O15 – Nb2O5 nanocomposites were synthesized in 2 and 4 M KOH aqueous solutions, via a non-stoichiometric 1:2 Sr:Nb molar ratio hydrothermal method at 160°C for 48 h (S1 and S2, respectively). Sr(NO3)2 and Nb2O5 were used as raw materials. The synthesized أکثرSr5Nb4O15 – Nb2O5 nanocomposites were synthesized in 2 and 4 M KOH aqueous solutions, via a non-stoichiometric 1:2 Sr:Nb molar ratio hydrothermal method at 160°C for 48 h (S1 and S2, respectively). Sr(NO3)2 and Nb2O5 were used as raw materials. The synthesized nanomaterials were characterized by powder X-Ray diffraction (PXRD) technique. It was found that Sr5Nb4O15 has been crystallized in hexagonal crystal structure with space group P-3m1. Nb2O5 lattice parameters were also found as a= 6.175 Å, b= 29.175 Å, and c= 3.93 Å and a= 12.73 Å, b= 5.56 Å, and c= 4.88 Å with γ= 105.1°, respectively for the orthorhombic and monoclinic crystal structures. The morphologies of the synthesized materials were studied by field emission scanning electron microscope (FESEM). The FESEM images showed that the S1 and S2 nanocomposites had flower and plate like structures, respectively. Ultraviolet–Visible (UV-Vis) spectra analyses showed that the synthesized nanocomposites had strong light absorption properties in the ultraviolet light region. FTIR spectra of the obtained nanomaterials were also studied. Cell parameter refinements of the synthesized nanocomposites were also investigated. تفاصيل المقالة -
حرية الوصول المقاله
7 - Effect of Titania Colloid Solution Concentration on Hydrophobicity of Well-Aligned TiO2 Nanorods Synthesized via Hydrothermal Method
Farhad karimkhani h. ghayour B. BokaAmong one dimensional nanomaterials, TiO2 nanorods have found important applications in various industries due to optical, photocatalyst and self-cleaning properties. In this research, at first TiO2 nanorods were synthesized on a glass substrate by hydrothermal method. أکثرAmong one dimensional nanomaterials, TiO2 nanorods have found important applications in various industries due to optical, photocatalyst and self-cleaning properties. In this research, at first TiO2 nanorods were synthesized on a glass substrate by hydrothermal method. Then a thin film of TiO2 particles was dip coated (as seed layer) on the substrate. After that, hydrothermal synthesis of TiO2 nanorods with 0.05 and 0.1 mol concentrations was carried out on the seed layer. Morphology and microstructure of the seed layer and nanorods were investigated using scanning electron microscopy (SEM), X-ray diffraction (XRD) and atomic force microscopy (AFM). Hydrophobicity of nanorods was studied by contact angle instrument. Results revealed that nanorods synthesized on the glass substrate without seed layer are not aligned at all and have the average diameter of 120 nm, whereas nanorods synthesized on the seed layer are well-aligned with 30nm average diameter. The result obtained from contact angle instrument showed that nanorods synthesized with 0.05mol concentration have larger contact angle (157º), compared to those synthesized with 0.1mol concentration which have 115º contact angle. تفاصيل المقالة -
حرية الوصول المقاله
8 - Bismuth Pyromangenate: Hydrothermal and Solid State Synthesis, Characterization and Optical Properties
Mahdi Behzad Shahin khademiniaBi2Mn2O7 nano-powders were synthesized via a stoichiometric 1:1 Bi:Mn molar ratio hydrothermal method at 180 °C for 48 h in a 1M NaOH aqueous solution; and solid state method, using Bi(NO3)3.5H2O and MnO2 as raw materials. The synthesized materials were characterize أکثرBi2Mn2O7 nano-powders were synthesized via a stoichiometric 1:1 Bi:Mn molar ratio hydrothermal method at 180 °C for 48 h in a 1M NaOH aqueous solution; and solid state method, using Bi(NO3)3.5H2O and MnO2 as raw materials. The synthesized materials were characterized by powder X-ray diffraction (PXRD) technique. Also, the rietveld analysis was done in FullProf in profile matching mode. It was found that Bi2Mn2O7 crystallizes in a cubic crystal structure with space groupFd3 ̄m. The size and morphologies of the synthesized materials were studied by transmission electron microscopy (TEM) and field emission scanning electron microscopy (FESEM) techniques, respectively. The FESEM images showed that the synthesized Bi2Mn2O7 has rod like structure in hydrothermal method and a mixture of rod and particle structures in solid state method. Also, BET-BJH analysis investigated for determination of pore size, pore volume, average particle size, pore width and surface area of the obtained materials. Also, photoluminescence spectra of the obtained materials were studied. تفاصيل المقالة -
حرية الوصول المقاله
9 - Alfa- Bismuth(III)oxide catalyzed Biginelli reactions using experimentally designed optimized condition
Mahdi Behzad marzie sabaghian Hamideh samari jahromiα-Bi2O3 was synthesized via a hydrothermal method at 180 °C for 12 h in 1 (S1) and 2 (S2) M KOH aqueous solutions, using Bi(NO3)3•5H2O as raw material. The synthesized material was characterized by X-ray powder diffraction (XRPD) technique. The XRPD resul أکثرα-Bi2O3 was synthesized via a hydrothermal method at 180 °C for 12 h in 1 (S1) and 2 (S2) M KOH aqueous solutions, using Bi(NO3)3•5H2O as raw material. The synthesized material was characterized by X-ray powder diffraction (XRPD) technique. The XRPD results indicated that by using 1M KOH aqueous solution, α-Bi2O3 was obtained with small fractions of β-Bi2O3, while 2M KOH solution resulted in pure α-Bi2O3. The α-Bi2O3 was crystallized in a monoclinic crystal structure with space group of P21/c. The size and morphologies of the synthesized material was studied by field emission scanning electron microscope (FESEM). The FESEM images showed that the obtained material had multigonal structures in micron dimensions. The synthesized material was tested as catalyst in Biginelli reactions and excellent performance was achieved in the optimized conditions. Experimental design was used to obtain optimized reaction conditions. Also the optical properties of the obtained material were studied by ultraviolet visible (UV-Vis) diffuse reflectance spectrum (DRS). تفاصيل المقالة -
حرية الوصول المقاله
10 - Hydrothermal synthesis, structural and catalytic studies of CuBi2O4 nanoparticles
Mehdi Salehi fatemeh Soleimani Ahmad GholizadehIn the present work CuBi2O4 nano-spinel has been synthesized via mild hydrothermal method at 180°C for 10 h. The synthesized nanomaterials were characterized by several techniques to emphasis the structure and properties of produced materials. The crystal structure was أکثرIn the present work CuBi2O4 nano-spinel has been synthesized via mild hydrothermal method at 180°C for 10 h. The synthesized nanomaterials were characterized by several techniques to emphasis the structure and properties of produced materials. The crystal structure was investigated by X-ray powder diffraction method and the values of refined unit cell volume and the structure properties were studied by using the Rietveld analysis is done using fullprof program. The results shew the formation of tetrahedral structure with space group P4/ncc for this sample. Also, the morphologies of the synthesized materials were figured out by field emission scanning electron microscope (FE-SEM). According to the FESEM images, several nano cubic form particle grew on micro spherical particles. As well, the catalytic performance of obtained CuBi2O4 was studied in Biginelli reaction. The reaction conditions of this study optimized by experimental design method. This experiment stablished high catalytic performance of copper bismuth oxide in compare with some other metal oxide catalysts.Also, the results shew this product is reusable homogenous catalyst. تفاصيل المقالة -
حرية الوصول المقاله
11 - Influence of heat treatment on synthesis of stoichiometric perovskite PbTiO3 nanostructure via hydrothermal method
Sahebali ManafiIn this research, the stoichiometric perovskite lead titanate (PbTiO3) nanostructure was synthesized successfully by the hydrothermal method. The effect of heat treatment of the autoclave and the furnace on the structure of this material was investigated. Titanium dioxi أکثرIn this research, the stoichiometric perovskite lead titanate (PbTiO3) nanostructure was synthesized successfully by the hydrothermal method. The effect of heat treatment of the autoclave and the furnace on the structure of this material was investigated. Titanium dioxide (TiO2), titanium tetrachloride (TiCl4) and lead oxide (PbO), lead nitrate (Pb(NO3)2) were used as the titanium and lead sources, respectively. The negative amount of the Gibbs free energy shows the reactivity of the reaction at room temperature. Characterization of PbTiO3 was carried out using scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The amount of lead titanate increased by raising the temperature of the autoclave. The objective of this research was developing the hydrothermal method to produce the phase-pure lead titanate at lower temperatures; also the effect of the precursor materials and heat treatment on morphology and crystal grows the development of PbTiO3 nanopowders were investigated. There are not any secondary phases when the sample was calcined at high temperatures. It seemed that heating in the furnace in a longer period and higher temperatures could affect the size of the crystallites. The powder was heated at 1200 ℃ had the larger grains and the ferroelectric domains that may cause the lowering of the dielectric constant. تفاصيل المقالة -
حرية الوصول المقاله
12 - Influence of heat treatment on synthesis of stoichiometric perovskite PbTiO3 nanostructure via hydrothermal method
Sahebali Manafi Sedigheh JoughehdoustIn this research, the stoichiometric perovskite lead titanate (PbTiO3) nanostructurewas synthesized successfully by the hydrothermal method. The effect of heattreatment of the autoclave and the furnace on the structure of this materialwas investigated. Titanium dioxide أکثرIn this research, the stoichiometric perovskite lead titanate (PbTiO3) nanostructurewas synthesized successfully by the hydrothermal method. The effect of heattreatment of the autoclave and the furnace on the structure of this materialwas investigated. Titanium dioxide (TiO2), titanium tetrachloride (TiCl4) and leadoxide (PbO), lead nitrate (Pb(NO3)2) were used as the titanium and lead sources,respectively. The negative amount of the Gibbs free energy shows the reactivityof the reaction at room temperature. Characterization of PbTiO3 was carried outusing scanning electron microscopy (SEM), transmission electron microscopy(TEM) and X-ray diffraction (XRD). The amount of lead titanate increased by raisingthe temperature of the autoclave. The objective of this research was developingthe hydrothermal method to produce the phase-pure lead titanate at lowertemperatures; also the effect of the precursor materials and heat treatment onmorphology and crystal grows the development of PbTiO3 nanopowders wereinvestigated. There are not any secondary phases when the sample was calcinedat high temperatures. It seemed that heating in the furnace in a longer periodand higher temperatures could affect the size of the crystallites. The powder washeated at 1200 oC had the larger grains and the ferroelectric domains that maycause the lowering of the dielectric constant. تفاصيل المقالة -
حرية الوصول المقاله
13 - Hydrothermal Synthesis, Structural and Catalytic Studies of CuBi2O4 Nanoparticles
Fatemeh Soleimani Mehdi Salehi Ahmad GholizadehIn the present work CuBi2O4 nano-spinel has been synthesized via mild hydrothermal methodat 180°C for 10 h. The synthesized nanomaterials were characterized by several techniquesto emphasis the structure and properties of produced materials. The crystal structure wa أکثرIn the present work CuBi2O4 nano-spinel has been synthesized via mild hydrothermal methodat 180°C for 10 h. The synthesized nanomaterials were characterized by several techniquesto emphasis the structure and properties of produced materials. The crystal structure wasinvestigated by X-ray powder diffraction method and the values of the refined unit cell volumeand the structure properties were studied by using the Rietveld analysis is done using Fullprofprogram. The results shew the formation of tetrahedral structure with space group P4/ncc for this sample. Also, the morphologies of the synthesized materials were figured outby field emission scanning electron microscope (FE-SEM). According to the FESEM images,several nano cubic form of particles grew on micro spherical particles. As well, the catalyticperformance of obtained CuBi2O4 was studied in Biginelli reaction. The reaction conditions ofthis study optimized by experimental design method. This experiment stablished high catalyticperformance of copper bismuth oxide in compare with some other metal oxide catalysts. Also,the results shew this product is reusable homogenous catalyst. تفاصيل المقالة -
حرية الوصول المقاله
14 - Hydrothermally synthesized nanocrystalline Nb2O5 and its visible-light photocatalytic activity for the degradation of congo red and methylene blue
Subhash Dharmraj Khairnar Manohar Rajendra Patil Vinod Shankar ShrivastavaNb2O5 nanoparticles were synthesized by the hydrothermal method. Structural, morphological and elemental analysis of synthesized Nb2O5 nanoparticles was carried out using X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscop أکثرNb2O5 nanoparticles were synthesized by the hydrothermal method. Structural, morphological and elemental analysis of synthesized Nb2O5 nanoparticles was carried out using X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy, respectively. The average crystal size calculations were performed on the basis of X-ray diffraction pattern and were about 12.44 nm. The synthesized Nb2O5 nanoparticles were explored for the photocatalytic degradation of congo red (CR) and methylene blue (MB) dyes in their aqueous solutions using a spectrophotometric method. For the Photocatalytic degradation of both the dyes, pH of dye solutions was varied in the range of 2 to 10. For the optimization, the maximum decolorization of 90 % and 87 % was observed for low initial dye concentration of 10 mg/L and pH values of CR and MB dyes were about 8 and 2, respectively. Besides, the effects of parameters such as the contact time and catalyst dose were studied systematically. تفاصيل المقالة -
حرية الوصول المقاله
15 - Optical and photocatalytic properties Undoped and Mn-doped ZnO nanoparticles synthesized by hydrothermal method: Effect of annealing temperature
Maryam Bordbar Seyed Mohammad Vasegh Somaye Jafari Ali Yeganeh FaalUndoped and Mn-doped ZnO nanoparticles were successfully prepared by the hydrothermal method with different annealing temperature conditions. Structural, chemical and optical properties of the samples were studied by X-ray diffraction (XRD), Field Emission scanning elec أکثرUndoped and Mn-doped ZnO nanoparticles were successfully prepared by the hydrothermal method with different annealing temperature conditions. Structural, chemical and optical properties of the samples were studied by X-ray diffraction (XRD), Field Emission scanning electron microscopy (FESEM), UV-Vis spectrophotometry and Fourier transform infrared (FT-IR) spectroscopy. The phase purity was confirmed by X-ray powder diffraction (XRD) and XRD spectra showed that all the samples were hexagonal wurtzite structure and as the annealing temperature increases the material becomes less crystalline. In addition, the average crystal size was found to be 15-30 nm from SEM and XRD. It is seen that the optical band gap increases when the ZnO is doped with manganese and decreases when annealing temperature increases. The photoacatalytic activity of Undoped and Mn-doped ZnO nanoparticles was tested by the degradation of metyl orang (MO) under UV light and indicated that Mn-doped ZnO has higher photocatalytic activity relative to ZnO nanoparticles and photocatalytic activity decreases when annealing temperature increases. تفاصيل المقالة
سند
Sanad is a platform for managing Azad University publications
الروابط
المراكز ذات الصلة
دعامة
الصفحات الرسمية
حقوق هذا الموقع الإلكتروني مملوكة لنظام SANAD Press Management. © 1442-1446