Adsorption of malachite green dye on different natural absorbents modified with magnetite nanoparticles
Subject Areas : Journal of NanoanalysisNaereh Besharati 1 , Nina Alizadeh 2
1 - Department of Chemistry, University of Guilan, Rasht, Iran
2 - Department of Chemistry, University of Guilan, Rasht, Iran
Keywords: Magnetic nanoparticles, Malachite green, Natural absorbents,
Abstract :
This study was focused on the adsorption of malachite green as a cationic dye on magnetite nanoparticles loaded green tea waste (MNLGTW), peanut husk (MNLPH), Azolla (MNLA) and Fig leave (MNLFL) as naturally cheap sources of adsorbent. MNLGTW, MNLPH, MNLA and MNLFL were prepared with chemical precipitation method and they were characterized with Fourier transform infrared spectroscopy (FT-IR), powder X-ray diffraction (XRD), Scanning electron microscopy (SEM) and Energy Dispersive X- ray (EDX) analysis. Different parameters affecting the dye removal efficiency were optimized. At optimum conditions, the sorption of the malachite green on theMNLGTW, MNLPH, MNLA, and MNLFL adsorbents was best described by a pseudo second-order kinetic model with R2 =1, qeq= 12.51 mg g-1 , R2 =0.9996, qeq=625 mg g-1 , R2 =0.9842, qeq=0.5772 mg g-1 and R2 =0.9912, qeq=0.517 mg g-1 respectively. Equilibrium data were fitted wellto the Langmuir isotherm more than Freundlich and Temkin isotherm. The synthesized sorbent showed complete dye removal with 112.359, 98.039, 23.1 and 73.2 mg g-1 for MNLGTW, MNLPH, MNLA,and MNLFL, respectively. The results showed MNLGTW, MNLPH, MNLA and MNLFL can be used as efficient adsorbents for removal of malachite green from aqueous solutions.
[1] V.K. Garg, R. Kumar and R. Gupta, Dyes. Pigm., 62, 1 (2004).
[2] S. Srivastava, R. Sinha and D. Roya, Aquat. Toxicol., 66, 319 (2004).
[3] Food standards Australia newzeland Consumer. Chemical in foods., (2005). http://www.foodstandards.gov.au/consumer/chemicals/malachitegreen/Pages/default.aspx
[4] R. Mirzajani and S. Ahmadi, J. Ind. Eng. Chem., 23, 171 (2014).
[5] S. Namrodi, M. Golipor, H. Mirrezai and M. Mazandarani, National conference about planning of environmental protection. (2013).
[6] N. Nashaat, N. Nassar, N. Nedal, G. Vitale and A. Arar, J. Chem. Engin., 93, (2015).
[7] S. Kanchi, Environ. Anal. Chem. (2014).
[8] S. Chakraborty, S. Chowdhury and P.D. Saha, J. Carbohydr. Polym., 86, 1533 (2011).
[9] Y. Liu, X. Sun and B. Li, J. Carbohydr. Polym., 81, 335 (2010).
[10] I. Safarik, M. Safarikova, Phys. Proced., 9, 274 (2010).
[11] I. Safarik, K. Horska, B. Svobodova and M. Safarikova, Eur. Food Res. Technol., 234, 345 (2012).
[12] I. Safarik, P. Lunackova, E. Mosiniewicz-Szablewska, F. Weyda and M. Safarikova, Holzforschung., 61, 247 (2007).
[13] C. Namasivayam and N. Kanchana, Chemosphere., 25, 1691 (1992).
[14] C. Namasivayam, N. Muniasamy, K. Gayatri, M. Rani and K. Ranganathan, Bioresour. Technol., 57, 37 (1996).
[15] T. Robinson, B. Chandran and P. Nigam, Water. Res., 36, 2824 (2002).
[16] O. Serpil and K. Fikret, Environ. Manage., 81, 307 (2006).
[17] Y. Bulut, N. Gozubenli and H. Aydin, Hazard. Mater., 144, 300 (2007).
[18] M.T. Sulak, E. Demirbas and M. Kobya, Bio Tech., 98, 2590 (2006).
[19] A. Mittal, L. Kurup and J. Mittal, Hazard. Mater., 146, 243 (2007).
[20] F. Ovaisi, M. Nikazar and MH. Razagi, National conference about planning of environmental protection, (2012).
[21] W. WU, Q. He and C. Jiang, Nanoscale Res Lett., 3, 397 (2008).
[22] M. Golshekan and SH. Shariati, ACta. Chim., 60, 2, 358 (2013).
[23] M. Manoochehri, SM. Mostashari, and SH. Shariati, Cell. Chem.Tech., 47, 727 (2013).
[24] SH. Shariati, M. Faraji, Y. Yamini and A.A. Rajabi, Else Desal., 270, 160 (2011).
[25] N. Yang, S. Zhu, D. Zhang and S. Xu, Mater. Lett., 62, 645 (2008).
[26] J. Park, K. An, Y. Hwang, J.G. Park, H.J. Noh, J.Y. Kim, J.H. Park, N.M. Hwang and T. Hyeon, Nat. Mater., 3, 891 (2004).
[27] J.H. Jang and H.B. Lim, Microchem., 94, 148 (2010).
[28] N.A. Taha and, E. maghraby, J. Glob. Nest., 17, 25 (2015).
[29] D. Ashoori, S.A. Noorhosseini and S.F. Noorhosseini, Bioscien. IJB., 4, 196 (2014).
[30] Green Tea Processing. How Green Tea is processed. Available at: https://www.o- cha.com/green-tea- processing.html
[31] N. Alizadeh. S. Shariati, N. Besharati, Int. J. Environ. Res., 11,197 (2017).
[32] T.V. Padmesh, K. Vijayaraghavan, G. Sekaran and M. Velan, J. Hazard. Mater., 125, 121 (2005).
[33] H. Benaïssa, Thirteenth International Water Technology Conference IWTC Hurghada Egypt., 13 (2009).
[34] V.K. Gupta and A. Nayak, J. Chem. Eng., 180, 81 (2012).
[35] R. Massart, IEEE. Trans. Magn., 17, 1247 (1981).
[36] P. Panneerselvam, N. Morad and K.A. Tan, Hazard. Mat., 186, 160 (2011).
[37] L.C.A. Oliveira, R.V.R.A. Rios, J.D. Fabris, K. Sapag, V.K. Gargc and R.M. Lago, Appl. Clay. Sci., 22, 169 (2003).
[38] E.N. EI Qada, S.J. Allen and G.M. Walker, Chem. research., 17, 6044 (2006).
[39] G. Zhang and y. Bao, Energy. procedia., 16, 1141 (2011).
[40] K. Kusmierek and A. Swiatkowski, Reac kinet mech cat., 116, 261 (2015).
[41] G. Alberghina, R. Bianchini, M. Fichera and S. Fisichella, Dyes. Pig., 46, 129 (2000).
[42] J. German Heins and M. Flury, Geoderma., 97, 87 (2000).
[43] I. Langmuir, Am Chem. Soc., 40, 1361 (1918).
[44] H.M.F. Freundlich, Z. Phys. Chem., 57, 385 (1906).
[45] M.J. Tempkin and V. Pyzhev, Acta. PhysioChim., 12, 271 (1940).
[46] M.J. Iqbal and M.N. Ashiq, J. Hazard.Mater., 139, 57 (2007).
[47] P. Saha, S.h. Chowdhury, S. Gupta and I. Kumar, Chem Eng J., 165, 874 (2010).
[48] M.A. Malana, S. Ijaz and M.N. Ashiq, Desalination., 263, 249 (2010).
[49] S.D. Khattri and M.K. Singh, J. Hazard. Mater., 167, 1089 (2009).
[50] S.S. Tahir and N. Rauf, Chemosphere., 63, 1842 (2006).
[51] M. Ghaedi and N. Mosallanejad, J. Ind. Eng. Chem., 20, 1085 (2014).
[52] R. Mirzajani and S. Ahmadi, J. Ind. Eng. Chem., 23, 171 (2015).
[53] A. Afkhami, R. Moosavi and T. Madrakian, Talanta., 82, 785 (2010).