Synthetic Application of Magnetic Nanocomposite Fe3O4@PEG-Au as a Heterogeneous and Reusable Nanocatalyst in The Suzuki Coupling Reactions

Subject Areas : Journal of Nanoanalysis

Amir Homayoun Keihan ¹ , Hamed Veisi ² , Hadis Javaheri ³

1 - Molecular Biology Research Center, Baqiyatallah University of Medical Sciences, Tehran, Iran
2 - Nanobiotechnology Research Center, Baqiyatallah University of Medical Sciences, Tehran, Iran
3 - Department of Chemistry, Payame Noor University, Tehran, Iran

Received: 2017-04-22 Accepted : 2017-06-21 Published : 2017-06-01

Keywords: magnetic, Nanocatalyst, Suzuki, PEG, Gold NPs,

Abstract :

In the present study, we carried out chemical synthesis and characterization of Fe3O4@PEG-Au as a magnetic nanocomposite in aqueous solution by chemical co-precipitation of Fe3+ and Fe2+ ions and encapsulated by poly (ethylene glycol) (PEG) in order to enhancing hydrophilicity, biocompatibility and immobilizing gold ions in the presence of NaBH4 as a reducing agent. Nanostructures were characterized again with FESEM and TEM. The nanoparticles with their spherical shape and dimensions of approximately 12 nm were used as a heterogeneous catalyst for Suzuki coupling reactions whilst in mild conditions. The high efficiency of the catalytic reaction was affirmed by the good yields of products, easy work-up, and absence of leached gold from the support and the smooth recovery of the catalyst.

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