Ultrasonic Assisted Adsorption of Rhodamine B (RhB) Dye by Albizia Stem Bark Lebbeck Modified by Fe2 (MoO4)3 Nanocomposite Synthesis: Experimental Design Methodology

Subject Areas : Polymer

Shiva Enolghozati ¹ , Nasrin Choobkar ² , Elham Pournamdari ³ , Farzaneh Marahel ⁴

1 - Department of Environment, Kermanshah Branch, Islamic Azad University, Kermanshah, Iran.
2 - Department of Environment, Kermanshah Branch, Islamic Azad University, Kermanshah, Iran.
3 - Department of Chemistry, Islamshahr Branch, Islamic Azad University, Islamshahr, Iran.
4 - Department of Chemistry, Omidiyeh Branch, Islamic Azad University, Omidiyeh, Iran.

Received: 2023-07-15 Accepted : 2023-07-15 Published : 2023-05-01

Keywords:

Abstract :

The applicability of Albizia Stem Bark Lebbeck Modified by Fe2 (MoO4)3 nanocomposite synthesis for removing Rhodamine B dye from aqueous solutions has been reported. Identical techniques including BET, IR, XRD, EDX, and SEM have been utilized to characterize this novel material. Also, the impacts of variables including initial Rhodamine B dye concentration (X1), pH (X2), adsorbent dosage (X3), and Sonication time (X4) came under scrutiny using central composite design (CCD) under response surface methodology (RSM).The values of 10 mg L-1, 0.025g, 6.0, 5.0 min were considered as the ideal values for Rhodamine B dye concentration, adsorbent mass, pH value, and contact time respectively. The adsorption equilibrium and kinetic data were fitted with the Langmuir isotherm model and pseudo-second-order kinetics (R2: 0.999) with maximum adsorption capacity (qmax: 98.0 mgg-1) respectively. Thermodynamic parameters (R2: 0.998, ΔG°: -95.58 kJ mol-1, ΔH°: -29.24 kJ mol-1, ΔS°: -131.49 kJ mol-1 K-1) also indicated Rhodamine B dye adsorption is feasible, spontaneous and exothermic. The overall results confirmed that Albizia Stem Bark Lebbeck Modified by Fe2 (MoO4)3 nanocomposite could be a promising adsorbent material for Rhodamine B dye removal from aqueous solutions.

References:

1. X. Tao, Sh. Wang, Zh. Li, J. Environ. Manage., 255, 109834 (2020).
2. L.P. Lingamdinne, J.R. Koduru, R.R. Karri, J. Environ. Manage., 231, 622 (2019).
3. M. Ali Khan, M. R. Siddiqui , M. Otero, Sh. Ahmed Alshareef, M. Rafatullah,Polymers., 12, 500 (2020).
4. F. Marahel, Iran. J. Chem. Chem. Eng., 38, 129 (2019).
5. Y. Zhao, Zh. Li, J. Mol. Liq., 293, 111516 (2019).
6. F.H.M. Souza, V.F.C. Leme, G.O.B. Costa, K.C. Castro, T.R. Giraldi, G.S.S. Andrade, Water Air Soil Pollut., 231, 1 (2020).
7. A. Selvakumar, S. Rangabhashiyam, J. Environ. Pollut., 255, 113291 (2019).
8. M. Kiani, S. Bagheri, A. Khalaji, N. Karachi, Desal. Water Treat., 226, 147 (2021).
9. O.A. Adeleke, A. Ahmad, K. Hossain, M. Rafatullah, J. Mol. Liq., 281, 48 (2019).
10. S. Singh, N. Parveen, H. Gupta, Environ. Technol. Innova., 12, 189 (2018).
11. A.A. Abdulrazak, S. Rohani, Adv. Mater. Sci. Eng., 2018, 1 (2018).
12. H. Zeng, M. Gao, T. Shen, F. Ding, Colloid. Surf. A., 555, 746 (2018).
13. A.L.D. Da Rosa, E. Carissimi, G.L. Dotto, H. Sander, L.A. Feris, J. Clean. Prod., 198,1302 (2018).
14. M. Tuzen, A. Sari, T.A. Saleh, J. Environ. Manage., 206, 170 (2018).
15. D.L. Postai, C.A. Demarchi, F. Zanatta, D.C.C. Melo, C.A. Rodrigues, Alexan. Eng. J.,55, 1713 (2016).
16. H. Esmaeilli, F. Foroutan, D. Jafari, Korean. J. Chem. Eng., 37, 804 (2020).
17. H. Pooladi, R. Foroutan, H. Esmaeili, Environ. Monitor. Assess., 193, 1 (2021).
18. M.M. Rashad, A.A. Ibrahim, D.A. Rayan, M.M.S. Sanad, I.M. Helmy, Environ.Nanotechnol. Monit. Manag., 8, 175 (2017).
19. R. Foroutan, S. J. Peighambardoust, S. Hemmati, Int. J. Biolog. Macromol., 189, 432 (2021).
20. G. Haghdoost, J. Phys. Theore. Chem., 15(3,4), 141 (2019).
21. F. Maghami, M. Abrishamkar, B. Mombeni Goodajdar, M. Hossieni, Desal. Water Treat., 223, 388 (2021).
22. M. Rahmani Piani, M. Abrishamkar, B. Mombeni Goodajdar, M. Hossieni, Desal. WaterTreat., 223, 288 (2021).
23. S. Mahdi Hadi, M.K.H. Al – Mashhadani, M.Y. Eisa, Chem. Ind. Chem. Eng. Q., 25, 39 (2019).
24. S. Bagheri, H. Aghaei, M. Ghaedi, A. Asfaram, M. Monajemi, A.A. Bazrafshan, Ultrason. Sonochem., 41, 279 (2018).
25. F. Raoufi, H. Aghaee, M. Monajjemi, Orient. J. Chem., 32, 1839 (2016).
26. H.S. Ghazi Mokri, N. Modirshahla, M.A. Behnajady, B. Vahid, Int. J. Environ. Sci. Technol., 12, 1401 (2015).
27. M. Ullah, R. Nazir, M. Khan, W. Khan, M. Shah, S.G. Afridi, J. Soil and Water Res., 15, 30 (2020).
28. S. Rahdar, A. Rahdar, M.N. Zafar, S.S. Shafqat, S. Ahmadi, J. Mater. Res. Technol., 8, 3800 (2019).
29. G.K. Sharma, N. Dubey, A Review, Int. J. Ayur. Herb. Med., 5, 1683 (2015).
30. H.Z. Khafri, M. Ghaedi, A. Asfaram, M. Safarpoor, Ultrason. Sonochem., 38, 371(2017).
31. M. Pargari, F. Marahel, B. Mombini Godajdar, Desal. Water Treat., 212, 164 (2021).
32. M. Kiani, S. Bagheri, N. Karachi, E. Alipanahpour Dil, Desal. Water Treat., 152, 366 (2019).
33. D. Nunez-Gomez, F. Lapolli, M. Nagel-Hassemer, M. Lobo-Recio, Energy Proc., 136, 233 (2017).
34. V. Kumar, P. Saharan, A.K. Sharma, A. Umar, I. Kaushal, Y. Al-Hadeethi, B. Rashad,A. Mittal, J. Ceram. Int., 46, 10309 (2020).
35. F. Marahel, B. Mombeni Goodajdar, N. Basri, L. Niknam, A.A. Ghazali, Iran. J. Chem.Chem. Eng., 41, 1 (2022). doi: 10.30492/IJCCE.2021.527025.4636.
36. Z. M. Saigal, A.M. Ahmed, J. Chem., 21, 212 (2021).
37. A. Azari, R. Nabizadeh, S. Nasseri, A.H. Mahvi, A.R. Mesdaghinia, Chemospher., 250,126238 (2020).
38. A. S. Abdulhameed, A. K. Talaq Mohammad, A.H. Jawad, Desal. Water Treat., 164, 364 (2019).
39. M. Hubbe, S. Azizian, S. Douven, A Review. Bio Resource., 14(3), 7582 (2019).
40. R. Han, Y. Zhang, Y. Xie, J. Separa. Purif. Technol., 234, 116119 (2019).
41. A. Asfaram, M. Ghaedi, S. Hajati, A. Goudarzi, Ultrason. Sonochem., 32, 418 (2016).
42. N. Karachi, S. Motahari, S. Nazarian, Desal Water Treat., 228, 389 (2021).
43. N.N. Abd Malek, A.H. Jawad, A.S. Abdulhameed, K. Ismail, B.H. Hameed, Int. J. Biolog. Macromol., 146, 530 (2020).
44. Sh. Bouroumand, F. Marahel, F. Khazali, Desal. Water Treat., 223, 388 (2021).
45. A.H. Jawad, N.N.M. Firdaus Hum, A.S. Abdulhameed, M.Z. Mohd Ishak, Int. J. Environ. Anal. Chem., 100, 1 (2020). https://doi.org/10.1080/03067319.2020.1807529.
46. A.H. Jawad, I.A. Mohammed, A.S. Abdulhameed, J. Polymers Environ., 28, 2720 (2020).
47. F. Marahel, B. Mombeni Goodajdar, L. Niknam, M. Faridnia, E. Pournamdari, S.Mohammad Doost, Int. J. Environ. Anal. Chem., 101, 1 (2021). https://doi.org/10.1080/03067319.2021.1901895.