Synthesis and Investigation of Corrosion Inhibition of 4-(naphthalen-1-yl) thiazol-2-amineoncopper in HCl: Experimental and Theoretical Studies

الموضوعات :

Razieh Farahati ¹ (Industrial Electrochemistry Research Laboratory, Faculty of Chemistry, Iran University of Science and Technology, Tehran, Iran)
S. Morteza Mousavi-Khoshdel ² (Industrial Electrochemistry Research Laboratory, Faculty of Chemistry, Iran University of Science and Technology, Tehran, Iran)
Ali Ghaffarinejad ³ (Industrial Electrochemistry Research Laboratory, Faculty of Chemistry, Iran University of Science and Technology, Tehran, Iran Research Laboratory of Real Samples Analysis, Faculty of Chemistry, Iran University of Science and Technology, Tehran, Iran Electroanalytical Chemistry Research Center, Iran University of Science and Technology, Tehran, Iran)
Hamidreza (Jafar) Rezania ⁴ (Department of Organic Chemistry, Faculty of Chemistry, Kharazmi University, Tehran, Iran)

تاريخ الإرسال : 07 الأربعاء , شوال, 1442 تاريخ التأكيد : 07 الأربعاء , شوال, 1442 تاريخ الإصدار : 21 الخميس , ذو القعدة, 1442

الکلمات المفتاحية:

ملخص المقالة :

4-(naphthalen-1-yl) thiazol-2-amine (NTA) was synthesized and its corrosion inhibition ability on the copper was investigated. The inhibition efficiencies were evaluated by electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, scanning electron microscopy (SEM), and atomic force microscopy (AFM).The experiments were performed in various concentrations of NTA in 1 M HCl solution. Computational studies (molecular dynamics (MD) simulation and density functional theory (DFT)) were also executed. The corrosion inhibition efficiency of this compound at optimum concentration was about 90%, demonstrating that NTA is an effective corrosion inhibitor. The adsorption of inhibitor obeyed the Langmuir adsorption model.

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