بررسی تأثیر دانسیته جریان اعمالی بر خواص ترشوندگی پوشش سریم اکسید تولید شده به روش رسوب‌دهی الکتروشیمیایی
الموضوعات :نوید احمدی زاده 1 , پوریا نجفی سیار 2
1 - دانشجوی کارشناسی ارشد، بخش مهندسی مواد، دانشکده مهندسی، دانشگاه شیراز، شیراز، ایران
2 - استادیار، بخش مهندسی مواد، دانشکده مهندسی، دانشگاه شیراز، شیراز، ایران
الکلمات المفتاحية: رسوب‌دهی الکتروشیمیایی, سریم اکسید, آبگریزی, جذب هیدروکربن,
ملخص المقالة :
در این تحقیق پوشش سریم اکسید به روش رسوب‌دهی الکتروشیمیایی بر روی زیرلایه مس ایجاد شد. تأثیر دانسیته جریان اعمالی بر مورفولوژی، ساختار کریستالی، شیمی سطح، زبری سطح و رفتار ترشوندگی پوشش‌ها به ترتیب به وسیله میکروسکوپ الکترونی روبشی، آزمون تفرق اشعه ایکس، طیف سنجی تبدیل فوریه اشعه مادون قرمز، میکروسکوپ نیروی اتمی و اندازه‌گیری زاویه تماس آب بر روی پوشش‌ها بررسی شدند. نتایج حاصل نشان دادند که با افزایش دانسیته جریان اعمالی پوشش‌هایی ضخیم‌تر با میزان ترک سطحی و زبری بیشتر تولید می‌شوند. همچنین صفحات کریستالی (۰۰۲) در پوشش‌های تولید شده در دانسیته جریان‌های کمتر، رشد بیشتری داشتند و این پوشش‌ها دارای اندازه بلور بزرگ‌تری بودند. با اعمال دانسیته جریان‌های بیشتر، رفتار آبدوستی پوشش‌های سریا بیشتر شد. اگرچه در ابتدا پوشش‌های سریا رفتاری آبدوست داشتند اما پس از قرار گرفتن در معرض هوا و جذب هیدروکربن آبگریز شدند. پوشش‌های ساخته شده در دانسیته جریان‌های بالاتر میزان جذب هیدروکربن بیشتری از خود نشان دادند.
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[1]Y. Gu et al., "Research progress of biomimetic superhydrophobic surface characteristics, fabrication, & application," Adv. Mech. Eng., vol. 9, no. 12, pp, 1–13, 2017, doi: 10.1177/1687814017746859.
[2]J. Tam, G. Palumbo & U. Erb, "Recent advances in superhydrophobic electrodeposits," Materials (Basel)., vol. 9, no. 3, pp, 1–27, 2016, doi: 10.3390/ma9030151.
[3] ب. بکا، ح. غیور و ف. کریمخانی، "تأثیر ضخامت بذر لایه بر آبگریزی نانومیله های"ZnO ، فرآیندهای نوین در مهندسی مواد، دوره، 9، شماره، 1، ص 221-211، 1394.
[4]G. Azimi, R. Dhiman, H. M. Kwon, A. T. Paxson & K. K. Varanasi, "Hydrophobicity of rare-earth oxide ceramics," Nat. Mater., vol. 12, no. 4, pp, 315–320, 2013, doi: 10.1038/nmat3545.
[5]S. L. Sanjay, B. G. Annaso, S. M. Chavan & S. V. Rajiv, "Recent progress in preparation of superhydrophobic surfaces: a review," J. Surf. Eng. Mater. Adv. Technol., vol. 2, no. April, pp, 76–94, 2012.
[6]K. Nakayama, T. Hiraga, C. Zhu, E. Tsuji, Y. Aoki & H. Habazaki, "Facile preparation of self-healing superhydrophobic CeO 2 surface by electrochemical processes," Appl. Surf. Sci., vol. 423, pp, 968–976, 2017, doi: 10.1016/j.apsusc.2017.07.012.
[7]T. Ishizaki, Y. Masuda & M. Sakamoto, "Corrosion resistance & durability of superhydrophobic surface formed on magnesium alloy coated with nanostructured cerium oxide film & fluoroalkylsilane molecules in corrosive NaCl aqueous solution," Langmuir, vol. 27, no. 8, pp, 4780–4788, 2011, doi: 10.1021/la2002783.
[8]A. F. Feil & et al., "Micro & nano-texturization of intermetallic oxide alloys by a single anodization step: Preparation of artificial self-cleaning surfaces," ACS Appl. Mater. Interfaces, vol. 3, no. 10, pp, 3981–3987, 2011, doi: 10.1021/am200854r.
[9]F. Pedraza, S. A. Mahadik & B. Bouchaud, "Synthesis of ceria based superhydrophobic coating on Ni20Cr substrate via cathodic electrodeposition," Phys. Chem. Chem. Phys., vol. 17, no. 47, pp, 31750–31757, 2015, doi: 10.1039/c5cp04723d.
[10]S. Khan, G. Azimi, B. Yildiz & K. K. Varanasi, "Role of surface oxygen-to-metal ratio on the wettability of rare-earth oxides," Appl. Phys. Lett., vol. 106, no. 6, 2015, doi: 10.1063/1.4907756.
[11]Y. J. Cho, H. Jang, K. S. Lee & D. R. Kim, "Direct growth of cerium oxide nanorods on diverse substrates for superhydrophobicity & corrosion resistance," Appl. Surf. Sci., vol. 340, pp, 96–101, 2015, doi: 10.1016/j.apsusc.2015.02.138.
[12]I. K. Oh & et al., "Hydrophobicity of rare earth oxides grown by atomic layer deposition," Chem. Mater., vol. 27, no. 1, pp, 148–156, 2015, doi: 10.1021/cm503659d.
[13] D. J. Preston, N. Miljkovic, J. Sack, R. Enright, J. Queeney & E. N. Wang, "Effect of hydrocarbon adsorption on the wettability of rare earth oxide ceramics," Appl. Phys. Lett., vol. 105, no. 1, pp, 0–5, 2014, doi: 10.1063/1.4886410.
[14]R. Lundy & et al., "Exploring the Role of Adsorption & Surface State on the Hydrophobicity of Rare Earth Oxides," ACS Appl. Mater. Interfaces, vol. 9, no. 15, pp, 13751–13760, 2017, doi: 10.1021/acsami.7b01515.
[15]E. Külah & et al., "Surface chemistry of rare-earth oxide surfaces at ambient conditions: Reactions with water & hydrocarbons," Sci. Rep., vol. 7, no. March, pp, 1–10, 2017, doi: 10.1038/srep43369.
[16]Y. Cai, T. W. Coyle, G. Azimi & J. Mostaghimi, "Superhydrophobic Ceramic Coatings by Solution Precursor Plasma Spray," Sci. Rep., vol. 6, pp, 1–7, 2016, doi: 10.1038/srep24670.
[17]J. Tam, G. Palumbo, U. Erb & G. Azimi, "Robust Hydrophobic Rare Earth Oxide Composite Electrodeposits," Adv. Mater. Interfaces, vol. 4, no. 24, pp, 1–11, 2017, doi: 10.1002/admi.201700850.
[18]ا. صفائی، "ایجاد آرایـه های نانوکامپوزیتی ZnO/CeO2 درون کانـال های مونولیت لانـه زنبوری کوردیریتی"، فرآیندهای نوین در مهندسی مواد، دوره،10، شماره، 2، ص 175-167، 1395.
[19]C. E. Castano, M. J. O’Keefe & W. G. Fahrenholtz, "Cerium-based oxide coatings," Curr. Opin. Solid State Mater. Sci., vol. 19, no. 2, pp, 69–76, 2015, doi: 10.1016/j.cossms.2014.11.005.
[20]A. Q. Wang & T. D. Golden, "Anodic Electrodeposition of Cerium Oxide Thin Films I. Formation of Crystalline Thin Films," J. Electrochem. Soc., vol. 150, no. 9, pp, 616–620, 2003, doi: 10.1149/1.1596164.
[21]Y. Hamlaoui, L. Tifouti, C. Remazeilles & F. Pedraza, "Cathodic electrodeposition of cerium based oxides on carbon steel from concentrated cerium nitrate. Part II: Influence of electrodeposition parameters & of the addition of PEG," Mater. Chem. Phys., vol. 120, no. 1, pp, 172–180, 2010, doi: 10.1016/j.matchemphys.2009.10.042.
[22]Y. Hamlaoui & et al., "Cathodic electrodeposition of cerium-based oxides on carbon steel from concentrated cerium nitrate solutions. Part I. Electrochemical & analytical characterisation," Mater. Chem. Phys., vol. 113, no. 2–3, pp, 650–657, 2009, doi: 10.1016/j.matchemphys.2008.08.027.
[23]Y. Zhou & J. A. Switzer, "Growth of cerium(IV) oxide films by the electrochemical generation of base method," J. Alloys Compd., vol. 237, no. 1–2, pp, 1–5, 1996, doi: 10.1016/0925-8388(95)02048-9.
[24]Y. Yang, Y. Yang, X. Du, Y. Chen, Z. Zhang & J. Zhang, "Influences of the main anodic electroplating parameters on cerium oxide films," Appl. Surf. Sci., vol. 305, pp, 330–336, 2014, doi: 10.1016/j.apsusc.2014.03.078.
[25]L. Martínez, E. Román, J. L. De Segovia, S. Poupard, J. Creus & F. Pedraza, "Surface study of cerium oxide based coatings obtained by cathodic electrodeposition on zinc," Appl. Surf. Sci., vol. 257, no. 14, pp, 6202–6207, 2011, doi: 10.1016/j.apsusc.2011.02.033.
[26]L. Yang, X. Pang, G. Fox-Rabinovich, S. Veldhuis, & I. Zhitomirsky, "Electrodeposition of cerium oxide films & composites," Surf. Coatings Technol., vol. 206, no. 1, pp, 1–7, 2011, doi: 10.1016/j.surfcoat.2011.06.029.
[27]B. Bouchaud, J. Balmain, G. Bonnet & F. Pedraza, "Optimizing structural & compositional properties of electrodeposited ceria coatings for enhanced oxidation resistance of a nickel-based superalloy," Appl. Surf. Sci., vol. 268, pp, 218–224, 2013, doi: 10.1016/j.apsusc.2012.12.065.
[28]J. Creus, F. Brezault, C. Rebere & M. Gadouleau, "Synthesis & characterisation of thin cerium oxide coatings elaborated by cathodic electrolytic deposition on steel substrate," Surf. Coatings Technol., vol. 200, no. 14–15, pp, 4636–4645, 2006, doi: 10.1016/j.surfcoat.2005.04.027.
[29]I. Zhitomirsky, "Cathodic electrodeposition of ceramic & organoceramic materials. Fundamental aspects," Advances in Colloid & Interface Science, vol. 97, no. 1–3. pp, 279–317, 2002, doi: 10.1016/S0001-8686(01)00068-9.
[30]A. T. Kuhn & C. Y. Chan, "pH changes at near-electrode surfaces," J. Appl. Electrochem., vol. 13, no. 2, pp, 189–207, 1983, doi: 10.1007/BF00612481.
[31]M. Xue, N. Peng, C. Li, J. Ou, F. Wang & W. Li, "Enhanced superhydrophilicity & thermal stability of ITO surface with patterned ceria coatings," Appl. Surf. Sci., vol. 329, pp, 11–16, 2015, doi: 10.1016/j.apsusc.2014.12.145.
[32]L. Luo & et al., "Investigate interactions of water with mesoporous ceria using in situ VT-DRIFTS," Surf. Sci., vol. 691, no. June 2019, p, 121486, Jan. 2020, doi: 10.1016/j.susc.2019.121486.
[33]G. Carchini, M. García-Melchor, Z. Łodziana & N. López, "Underst&ing & Tuning the Intrinsic Hydrophobicity of Rare-Earth Oxides: A DFT+U Study," ACS Appl. Mater. Interfaces, vol. 8, no. 1, pp, 152–160, 2016, doi: 10.1021/acsami.5b07905.
[34]A. Matin, U. Baig, M. A. Gondal, S. Akhtar & S. M. Zubair, "Superhydrophobic & superoleophilic surfaces prepared by spray-coating of facile synthesized Cerium(IV) oxide nanoparticles for efficient oil/water separation," Appl. Surf. Sci., vol. 462, no. August, pp, 95–104, 2018, doi: 10.1016/j.apsusc.2018.08.104.
[35]V. Sundararajan & et al., "Drosophila melanogaster as an in vivo model to study the potential toxicity of cerium oxide nanoparticles," Appl. Surf. Sci., vol. 490, no. June, pp, 70–80, 2019, doi: 10.1016/j.apsusc.2019.06.017.
[36]E. Nourmohammadi & et al., "Cytotoxic activity of greener synthesis of cerium oxide nanoparticles using carrageenan towards a WEHI 164 cancer cell line," Ceram. Int., vol. 44, no. 16, pp, 19570–19575, 2018, doi: 10.1016/j.ceramint.2018.07.201.
[37]H. M. Marwani, E. M. Bakhsh, S. B. Khan, E. Y. Danish & A. M. Asiri, "Cerium oxide‑cadmium oxide nanomaterial as efficient extractant for yttrium ions," J. Mol. Liq., vol. 269, pp, 252–259, 2018, doi: 10.1016/j.molliq.2018.08.046.
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