1,3-Dichloro-5,5-dimethylhydantoin: an efficient catalyst for the solvent free synthesis of 1,8-dioxo-octahydro-xanthenes

الموضوعات : Iranian Journal of Catalysis

Farhad Shirini ¹ (Department of Chemistry, College of Science, University of Guilan, Rasht, zip code 41335, I.R. Iran)
Kurosh Rad-Moghadam ² (Department of Chemistry, College of Science, University of Guilan, Rasht, zip code 41335, I.R. Iran)
Tahereh Naghdi ³ (Department of Chemistry, College of Science, University of Guilan, Rasht, zip code 41335, I.R. Iran)

تاريخ الإرسال : 16 السبت , ذو الحجة, 1432 تاريخ التأكيد : 17 الإثنين , جمادى الأولى, 1433 تاريخ الإصدار : 11 الجمعة , رجب, 1433

الکلمات المفتاحية: 1, Aldehydes, 8-Dioxo-octahydro-xanthenes, 3-Dichloro-5, 5-dimethylhydantoin, Cyclic 1, 3-dicarbonyl compounds, Solvent-free conditions,

ملخص المقالة :

This paper describes the applicability of 1,3-dichloro-5,5-dimethylhydantoin, as a cheap, stable and commercially available catalyst, in the promotion of the synthesis of 1,8-dioxo-octahydro-xanthenes (DOXOs) via the one-pot condensation of aldehydes and cyclic 1,3-dicarbonyl compounds. This novel synthetic method has the advantages of high yields, short reaction times, low cost and availability of the catalyst, solvent-free reaction conditions, simplicity and easy work-up compared to the conventional methods reported in the literature.

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