Trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane/HOAc/KI system as a new and mild catalyst for efficient synthesis of 1H-benzimidazoles and 1H-benzothiazoles in water
الموضوعات : Iranian Journal of CatalysisKaveh Khosravi 1 , Akbar Mobinikhaledi 2 , Samira Kazemi 3 , Davood Azarifar 4 , Payam Rahmani 5
1 - Department of Chemistry, Faculty of Science, Arak University, Arak, 38156-8-8349, Iran.
2 - Department of Chemistry, Faculty of Science, Arak University, Arak, 38156-8-8349, Iran.
3 - Department of Chemistry, Faculty of Science, Arak University, Arak, 38156-8-8349, Iran.
4 - Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, 6517838683 Iran.
5 - Department of Organic Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, 6517838683 Iran.
الکلمات المفتاحية: 2-Aryl-1-arylmethyl-1H-benzimidazoles, 2-Aryl-1H-benzothiazoles, Condensation, Trans-3, 5-dihydroperoxy-3, 5-dimethyl-1, 2-dioxolane (DHPDMDO), KI, Aldehydes,
ملخص المقالة :
An efficient method has been developed for the catalysis of condensation of 1,2-phenylenediamines and 2-aminothiophenoles with different aldehydes into their corresponding 2-aryl-1H-benzimidazoles and 2-aryl-1H-benzothiazoles under mild condition. In this method, trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane (DHPDMDO)/HOAc/KI system was used as a novel and effective oxidant in water at room temperature with excellent results.
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