Green synthesis of magnetic copper ferrite nanoparticles using tragacanth gum as a biotemplate and their catalytic activity for the oxidation of alcohols

الموضوعات : Iranian Journal of Catalysis

Ali Ramazani ¹ (Department of Chemistry, University of Zanjan, P O Box 45195-313, Zanjan, Iran.)
Saeid Taghavi Fardood ² (Department of Chemistry, University of Zanjan, P O Box 45195-313, Zanjan, Iran.)
Zahra Hosseinzadeh ³ (Department of Chemistry, University of Zanjan, P O Box 45195-313, Zanjan, Iran.)
Fariba Sadri ⁴ (Department of Chemistry, Payame Noor University, P.O. Box 19395-3697, Tehran, Iran.)
Sang Woo Joo ⁵ (School of Mechanical Engineering, Yeungnam University, Gyeongsan 712-749, Republic of Korea.)

تاريخ الإرسال : 13 الأربعاء , ربيع الثاني, 1438 تاريخ التأكيد : 18 الأربعاء , شوال, 1438 تاريخ الإصدار : 10 الجمعة , ذو الحجة, 1438

الکلمات المفتاحية: oxidation, Alcohols, Nanomagnetic catalyst, Copper ferrite, Tragacanth gel,

ملخص المقالة :

During this study, we report the green synthesis of magnetic copper ferrite nanoparticles using tragacanth gum as a reducing and stabilizing agent by the sol-gel method. The green synthesized CuFe2O4 MNPs are characterized by powder X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), vibrating sample magnetometer (VSM) and scanning electron microscopy (SEM). The X-raypowderdiffraction (XRD) analysis revealed the formation of Cubic phase ferrite MNPs with average crystallite size of 14 nm. This study has demonstrated that CuFe2O4nanoparticles can act as an efficient catalyst for selective oxidations of alcohols applying oxone (potassium hydrogen monopersulfate) as oxidant in the presence of acetonitrile as solvent at 40 ºC. Primary and secondary alcohols gave the corresponding products in good yields. Furthermore, the catalyst can be simply recovered and reused several times with almost no loss in activity.

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