Tungstophosphoric acid embedded magnetic chitosan as a green catalyst for the synthesis of N-cyclohexyl-3-aryl quinoxaline-2-amines
الموضوعات : Iranian Journal of CatalysisAli Ayati 1 , Mansoureh Daraie 2 , Majid Heravi 3 , Bahareh Tanhaei 4
1 - Department of Chemical Engineering, Quchan University of Advanced Technology, Quchan, Iran.
2 - Department of Chemistry, School of Sciences, Alzahra University, Vanak, Tehran, Iran.
3 - Department of Chemistry, School of Sciences, Alzahra University, Vanak, Tehran, Iran.
4 - Department of Chemical Engineering, Quchan University of Advanced Technology, Quchan, Iran.
الکلمات المفتاحية: Green synthesis, Heteropolyacid, Multicomponent reactions, Magnetic Chitosan,
ملخص المقالة :
In the present study, a novel catalyst was well designed by incorporating the tungstophosphoric acid into the magnetic chitosan, as highly stable composite, in which the iron oxides were used the strong super-magnetic core. The prepared composite was characterized by several methods, including FTIR, XRD, SEM, TEM and EDS and its catalytic activity was examined in a facile, green and highly efficient one-pot reaction for the synthesis of N-cyclohexyl-3-aryl-quinoxaline-2-amines with o-phenylenediamine, benzaldehyde and cyclohexyl isocyanide in water, under reflux conditions. This heterogeneous catalytic system was separated easily by an external magnet and was reused at least in four runs without pre-activation and appreciable loss in its activity.
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