• Home
  • Theoretical and Experimental Analysis for the Removal of Dye from Aqueous Solution by Using Charcoal from Pomegranate Seeds

Share To

Article Url


Manuscript ID : 694637 Visit : 196 Page: 521 - 530

10.22034/jchr.2022.694637

Article Type: Original Research

Theoretical and Experimental Analysis for the Removal of Dye from Aqueous Solution by Using Charcoal from Pomegranate Seeds

Subject Areas : Journal of Chemical Health Risks

Lekaa Hussain Khadim 1

1 - Department of Chemistry, College of Education for Woman, University of Kufa, Iraq

Received: 2021-09-17 Accepted : 2022-03-05 Published : 2023-09-01

Keywords: Adsorption, DFT, Isotherms, Dyes, adsorption kinetic, Activated charcoal,

Abstract :

This study initiates an experimental and theoretical investigation to evaluate the selective and competitive adsorption of two dyes, sulforhodamine B and Brilliant Green, on coal from pomegranate seeds. For this purpose, the effects of numerous parameters like initial dye concentration, initial pH, adsorbent dose and solution temperature were examined and studied in batch mode. The experimental results indicate that the adsorption is fast and fits better with the quasi-second order kinetic model than the quasi-first order kinetics. Adsorption data were studied using Langmuir and Freundlich isotherms. The obtained results showed that the Freundlich model provided a better correlation of the experimental data. The geometries of sulforodamine B and Brilliant Green were optimized using Gaussian 09W software through the density functional theory (DFT) at the theoretical level B3LYP / LanL2DZ, and the calculations (link length and connection angle) were well matched with experimental data at both levels.

References:


  1. Abbas M., Trari M., 2020. Removal of methylene blue in aqueous solution by economic adsorbent derived from apricot stone activated carbon. Fibers and Polymers. 21(4), 810-820.‏
    2.
  2. Robinson T.M., Marchant R., Nigam P., 2001. Remediation of dyes in textile effluent: A critical review on current treatment technologies with a proposed alternative. Biores Technol. 77, 247-255.‏
    3.
  3. Khera R.A., Iqbal M., Jabeen S., Abbas M., Nazir A., Nisar J., Tahir M.A., 2019. Adsorption efficiency of Pitpapra biomass under single and binary metal systems. Surfaces and Interfaces. 14, 138-145.‏
    4.
  4. Abbas M., Adil M., Ehtisham-ul –haque S., Munir B., Yameen M., Ghaffar A., Shar G.A., Tahir M.A., Iqbal M., 2018. Sci Total Environ. 626, 1295.
    5.
  5. Iqbal M., 2016. Vicia faba bioassay for environmental toxicity monitoring: a review. Chemosphere. 144, 785-802.‏
    6.
  6. Tyagi U., 2020. Adsorption of dyes using activated carbon derived from pyrolysis of vetiveria zizanioides in a fixed bed reactor. Groundwater for Sustainable Development. 10, 100303.‏
    7.
  7. El Kassimi A., Achour Y., El Himri M., Laamari R., El Hadda M., 2021. Removal of two cationic dyes from aqueous solutions by adsorption onto local clay: experimental and theoretical study using DFT method. International Journal of Environmental Analytical Chemistry. 1-22.‏
    8.
  8. Mech N., Khemis I.B., Dotto G.L., Franco D., Sellaoui L., Lamine A.B., 2019. Investigation of the adsorption mechanism of methylene blue (MB) on Cortaderia selloana flower spikes (FSs) and on Cortaderia selloana flower spikes derived carbon fibers (CFs). Journal of Molecular Liquids. 280, 268-273.‏
    9.
  9. Jawad A.H., Razuan R., Appaturi J.N., Wilson L.D., 2019. Adsorption and mechanism study for methylene blue dye removal with carbonized watermelon (Citrullus lanatus) rind prepared via one-step liquid phase H2SO4 activation. Surfaces and Interfaces. 16, 76-84.‏
    10.
  10. El Kassimi A., Achour Y., El Himri M., Laamari R., El Haddad M., 2021. Removal of two cationic dyes from aqueous solutions by adsorption onto local clay: experimental and theoretical study using DFT method. International Journal of Environmental Analytical Chemistry. 1-22.‏
    11.
  11. Olajire A.A., Giwa A.A., Bello I.A., 2015. Competitive adsorption of dye species from aqueous solution onto melon husk in single and ternary dye systems. International Journal of Environmental Science and Technology. 12(3), 939-950.‏
    12.
  12. Khadem L.H., Mageed N.S., 2013. Removal of Azo Compounds from Aqueous Solutions by the Process of Adsorption on Bentonaite Surfaces. J Chem and Cheml Sci. 3(3), 117-130.‏
    13.
  13. Xie H.J., Tan W., Zhang J., Niu H.B., 2011. Adsorption of Methylene Blue from Aqueous Solution onto Peracetic Acid-Modified Loosestrife Powder-A New Adsorbent. In Advanced Materials Research. Trans Tech Publications Ltd.‏ 152, pp. 691-696.
    14.
  14. Lin Y.Q., Tsai W.T., 2021. Liquid-Phase Removal of Methylene Blue as Organic Pollutant by Mesoporous Activated Carbon Prepared from Water Caltrop Husk Using Carbon Dioxide Activation. Processes 2021. 9, 238.‏
    15.
  15. Suárez-Garcıa F., Martınez-Alonso A. Tascón J., 2001. Porous texture of activated carbons prepared by phosphoric acid activation of apple pulp. Carbon. 7(39), 1111-1115.
    16.
  16. Ahmed M.J., Dhedan S.K., 2012. Equilibrium isotherms and kinetics modeling of methylene blue adsorption on agricultural wastes-based activated carbons. Fluid Phase Equilibria. 317, 9–14.
    17.
  17. Berrios M., Martin M., Martin A., 2012. Treatment of pollutants in wastewater: Adsorption of methylene blue onto olive-based activated carbon. Journal of Industrial and Engineering Chemistry. 18(2), 780–784.
    18.
  18. Attia A.A., Girgis B.S., Fathy N.A., 2008. Removal of methylene blue by carbons derived from peach stones by H3PO4 activation: Batch and column studies. Dyes and Pigments. 76(1), 282–289.
    19.
  19. Abbas M., 2020. Experimental investigation of activated carbon prepared from apricot stones material (ASM) adsorbent for removal of malachite green (MG) from aqueous solution. Adsorption Science & Technology. 38(1–2), 24–45
    20.
  20. Baquero M.C., Giraldo L., Moreno J.C., Suarez-Garcıa F., Martınez-Alonso A., Tascon J.M., 2003. Activated carbons by pyrolysis of coffee bean husks in presence of phosphoric acid. Journal of Analytical and Applied Pyrolysis. 70(2), 779-84.
    21.
  21. Kyzas G.Z., Lazaridis N.K., Mitropoulos A.C., 2012. Removal of dyes from aqueous solution with untreated coffee residues as potential low-cost adsorbents: Equilibrium, reuse and thermodynamic approach. Chemical Engineering Journal. 189, 148–159.
    22.

22.Yagmur E., Ozmak M., Aktas Z., 2008. A novel method for production of activated carbon from waste tea by chemical activation with microwave, energy. Fuel . 87(15–16), 3278–3285

  1. Valix M., Cheung W.H., McKay G., 2004. Preparation of activated carbon using low temperature carbonization and physical activation of high ash raw bagasse for acid dye adsorption. Chemosphere. 56(5), 493–501.
    2.
  2. Laine J., Calafat A., Labady M., 1989. Preparation and characterization of activated carbons from coconut shell impregnated. Carbon. 27(2), 191–195
    3.
  3. Harrache Z., Abbas M., Aksil T., Trari, M., 2019. Modeling of adsorption isotherms of (5, 5’-disodium indigo sulfonate) from aqueous solution onto activated carbon: equilibrium, thermodynamic studies, and error analysis. Desalination and Water Treatment. 147, 273-283.
    4.
  4. Frisch M.J., Trucks G.W., Schlegel H.B., Scuseria G.E., Robb M.A., Cheeseman J.R., Scalmani G., Barone V., Mennucci B., Petersson G.A., 2010. Gaussian 09, Revision C.01; Gaussian Inc. Wallingford, CT, USA.
    5.
  5. Dennington R., Keith T., Millam J., 2009. GaussView, Version 5, Semichem Inc. Shawnee Mission, KS.
    6.
  6. Belghiti M.E., Bouazama S., Echihi S., Mahsoune A., Elmelouky A., Dafali A., Tabyaoui M., 2020. Understanding the adsorption of newly Benzylidene-aniline derivatives as a corrosion inhibitor for carbon steel in hydrochloric acid solution: Experimental, DFT and molecular dynamic simulation studies. Arabian Journal of Chemistry. 13(1), 1499-1519.‏
    7.
  7. Geerlings P., Chamorro E., Chattaraj P.K., De Proft F., Gázquez J.L., Liu S., Ayers P., 2020. Conceptual density functional theory: status, prospects, issues. Theoretical Chemistry Accounts. 139(2), 1-18.‏
    8.
  8. Boumya W., Khnifira M., Machrouhi A., Abdennouri M., Sadiq M., Acha, M., Barka N., 2021. Adsorption of Eriochrome Black T on the chitin surface: Experimental study, DFT calculations and molecular dynamics simulation. Journal of Molecular Liquids. 331, 115706‏.
    9.
  9. Sadegh H., Ali G.A., Makhlouf A.S., Chong K.F, Alharbi N.S., Agarwal S., Gupta V.K., 2018. MWCNTs-Fe3O4 nanocomposite for Hg (II) high adsorption efficiency. Journal of Molecular Liquids. 258, 345-5.
    10.
  10. Das M.P., Renuka M., Vijaylakshmi J.V., Suguna P.R., 2018. Removal of Methylene Blue by Adsorption Using Fish Scale Chitin. Nature Environment and Pollution Technology. 17(3), 993-998.‏
    11.
  11. Maruca R., Jo Sunder B., Wightman J.P., 1982. Interaction of heavy metals with chitin & chitosan III Chromium. J Appl Pol Sci. 27, 4827-4837.
    12.
  12. Attia A.A., Girgis B.S., Khedr S.A., 2003. Capacity of activated carbon derived from pistachio shells by H3PO4 in the removal of dyes and phenolics. J Chem Technol Biotechnol. 78, 611-619.
    13.
  13. Dursun A.Y., 2003. The effect of pH on the equilibrium of heavy metal bisorption by Aspergillus miger. Fresenius Environ Bull. 12, 1315-1322.
    14.
  14. Kim S.K., Rajapakse N., 2005. Enzymatic reduction and biological activities of chitosan oligosaccharides (COS): A review. Carboh Pol. 62, 357-368.
    15.
  15. Marthur N.K., Narang C.K., 1990. Chitin and Chitosan, versatile polysaccharides from marine animals. J Chem Ed. 67, 938-942.
    16.
  16. Shaban M., Abukhadra M.R., Khan A.A.P., Jibali B.M., 2018. Removal of Congo red, methylene blue and Cr (VI) ions from water using natural serpentine. Journal of the Taiwan Institute of Chemical Engineers. 82, 102-116.‏
    17.
  17. Lai C.H., Chen C.Y., 2001. Removal of metal ions and humic acid from water by iron-coated filter media. Chemosphere. 44(5), 1177-1184.‏
    18.
  18. Namal O.O., Kalipci E., 2020. Adsorption kinetics of methylene blue removal from aqueous solutions using potassium hydroxide (KOH) modified apricot kernel shells. International Journal of Environmental Analytical Chemistry. 100(14), 1549-1565.‏
    19.
  19. Munagapati V.S., Wen H.Y., Vijaya Y., Wen J C., Wen J.H., Tian Z., Raul Garcia J., 2021. Removal of anionic (Acid Yellow 17 and Amaranth) dyes using aminated avocado (Persea americana) seed powder: adsorption/desorption, kinetics, isotherms, thermodynamics, and recycling studies. International Journal of Phytoremediation. 1-13.‏
    20.
  20. Fegousse A., El Gaidoumi A., Miyah Y., El Mountassir R., Lahrichi A., 2019. Pineapple bark performance in dyes adsorption: optimization by the central composite design. Journal of Chemistry. (3), 1-11.‏
    21.
  21. Langmuir I., 1916. The constitution and fundamental properties of solids and liquids. Part I. Solids. Journal of the American chemical society. 38(11), 2221-2295.
    22.
  22. Freundlich H., 1907. Über die adsorption in lösungen. Zeitschrift für physikalische Chemie. 57(1), 385-470.
    23.
  23. El Kassimi A., Boutouil A., El Himri M., Laamari M.R., El Haddad M., 2020. Selective and competitive removal of three basic dyes from single, binary and ternary systems in aqueous solutions: A combined experimental and theoretical study. Journal of Saudi Chemical Society. 24(7), 527-544.‏
    24.
  24. Mullick A., Moulik S., Bhattacharjee S., 2018. Removal of hexavalent chromium from aqueous solutions by low-cost rice husk-based activated carbon: kinetic and thermodynamic studies. Indian Chemical Engineer. 60(1), 58-71.
    25.

 

Related articles

The rights to this website are owned by the Raimag Press Management System.
Copyright © 2021-2024

Home| Login| About Us| Contact Us|
[فارسی] [العربية] [fa] [ar]