Determination of Trace Amount of Manganese‎ in Water Samples by Micro-funnel Magnetic Stirring-assisted Liquid Phase Microextraction Technique

Subject Areas : Journal of Chemical Health Risks

Majid Ramezani ¹ , Maryam Ghalenoei ²

1 - Department of Chemistry, faculty of Science, Arak Branch, Islamic Azad University, Arak, Iran, P.O.Box: 38135/567
2 - Department of Chemistry, faculty of Science, Arak Branch, Islamic Azad University, Arak, Iran, P.O.Box: 38135/567

Received: 2018-03-18 Accepted : 2019-09-24 Published : 2022-06-01

Keywords: Manganese, Flame atomic absorption spectrometry, Water samples, Micro-funnel magnetic stirring-assisted liquid phase Microextraction,

Abstract :

In this study, trace amounts of manganese ions were extracted using a sensitive, selective, rapid, and simple micro-funnel magnetic stirring-assisted liquid phase microextraction (MF-MSA-LPME) method and determined by flame atomic absorption spectrometry (FAAS). 1-(2-Thiazolylazo)-2-naphthol) (TAN) and 1-octanol were chosen as chelating agent and extraction solvent, respectively. The effective parameters on extraction efficiency such as type and volume of extraction solvent, pH of sample solution, ligand concentration, extraction time, and ion strength ‎were investigated and optimized. Under the optimum form, limit of detection (LOD), relative standard deviation, and the enrichment factor were 0.16 μg L-1, 2.9%, and 252, respectively. The calibration graph was linear over the range of 1-120 μg L-1 with correlation of coefficient r2 = 0.995.The proposed method could successfully determine trace amounts of manganese ions ‎in the real water samples with good accuracy and validity.

References:

1. Soko L., Chimuka L., Cukrowska E., Pole S., 2003. Extraction and preconcentration of manganese (II) from biological fluids (water, milk and blood serum) using supported liquid membrane and membrane probe methods. Anal Chem Acta. 485(1), 25-35.

2. Wang Z.Y., Fan R.H., Li Q.Q., Qian L., 2017. Preparation of Nickel and Manganese Oxides Composite via Co-Precipitation Method and its Supercapacitive Performan.  Key Eng Mater. 727, 770-774.

3. Daşbaşi T., Muğlu H., Soykan C.  Ülgen A., 2018. SPE and determination by FAAS of heavy metals using a new synthesized polymer resin in various water and dried vegetables samples. J Macromol Sci Pure Appl Chem. 55(3), 288-295.

4. Tobiasz A., Sołtys M., Kurys E., Domagała K., Dudek-Adamska D., Walas S., 2017. Multicomutation flow system for manganese speciation by solid phase extraction and flame atomic absorption spectrometry. Spectrochim. Acta, Part A. 134, 11-16.

5. Ghaedi M., Niknam K., Taheri K., Hossainian H. Soylak M., 2010. Flame atomic absorption spectrometric determination of copper, zinc and manganese after solid-phase extraction using 2,6-dichlorophenyl-3,3-bis(indolyl)methane loaded on Amberlite XAD-16. Food Chem Toxicol. 48(3), 891-897.

6. Tarafder P.K., Mondal R.K., Kunkal L., Murugan P., Rathore D.P.S., 2004. Liquid-Liquid Extraction and Spectrophotometric Determination of Mn(II) in Geochemical Samples. Chem Anal. (Warsaw) 49, 251-260.

7. Rod A.R., Borhani S., Shemirani F., 2006. Cloud point preconcentration and flame atomic absorption spectrometry: application to the determination of manganese in milk and water sample. Eur Food Res Technol. 223, 649-653.

8. Rezaei M., Assadi Y., Hosseini M.R.M., Aghaee E., Ahmadi F., Berijani S., 2006. Determination of organic compounds in water using dispersive liquid-liquid microextraction. J Chromatogr A. 1116(1-2), 1-9.

9. Shokoufi N., Shemirani F., Assadi Y., 2007. Fiber opticlinear array detection spectrophotometry in combination with dispersive liquid–liquid microextraction for simultaneous preconcentration and determination of palladium and cobalt. Anal Chim Acta. 597(2), 349-356.

10. Zhang Y., Lee H.K., 2013. Low-density solvent-based vortex-assisted surfactant-enhanced-emulsification liquid–liquid microextraction combined with gas chromatography–mass spectrometry for the fast determination of phthalate esters in bottled water. J Chromatogr A. 1274, 28-35.

11. Farajzadeh M.A., Djozan D. Khorram P., 2011. Development of a new microextraction method based on a dynamic single drop in a narrow-bore tube: Application in extraction and preconcentration of some organic pollutants in well water and grape juice samples. Talanta. 85(2), 1135-1142.

12. Ezoddin M., Abdi K., Esmaeili N., 2016. Ultrasound enhanced air-assisted surfactant liquid–liquid microextraction based on the solidification of an organic droplet for the determination of chromium in water, air and biological samples. Microchem J. 129, 200-204.

13. Hosseini M., Heydari R., Alimoradi M., 2014. Vortex and air assisted liquid–liquid microextraction as a sample preparation method for high-performed liquid chromatography determinations. Talanta. 130, 171-176.

14. Heydari F., Ramezani M., 2017. Application of response surface methodology for optimization and determination of palladium by in-tube ultrasonic and air-assisted liquid–liquid microextraction coupled with flame atomic absorption spectrometry. Sep Sci Technol. 52(10), 1643-1651.

15. Cabala R., Bursova M., 2012. Bell-shaped extraction device assisted liquid-liquid microextraction technique and its optimization using response-surface methodology. J Chromatogr A. 1230, 24-29.

16. Farahani A., Ramezani M., Hassan J., 2017. Microfunnel magnetic stirring-assisted dispersive liquid–liquid microextraction derivatization technique for the determination of 3-chloro-4-(dichloromethyl)-5-hydroxy-2(5H)-furanone (Mutagen X) in aqueous samples by GC-ECD. Sep Sci Technol. 52(9), 1505-1511.

17. Li N., Zhang H., Liu M., Wang Y., Ma J., Li J., Liu X., 2011. Solid Phase Extraction Clean-up Combined with Solidified Floating Organic Drop Microextraction for the Determination of Trace Manganese (II) in Different Environmental Matrices.  Anal Chem Lett. 1(4), 287-299.

18. Mohammadi S.Z., Afzali D., Baghelani Y.M., Karimzadeh L., 2011. Ultrasound - Assisted Emulsification Microextraction of Trace Amounts of Co and Mn Ions Prior to Flame Atomic Absorption Spectrometry. J Braz Chem Soc. 22(1), 104-110.

19. Mirabi A., Jamali M.R., Kazemi Q., 2016. Determination of trace amounts of manganese in water samples by flame atomic absorption spectrometry after dispersive liquid-liquid microextraction. Bulg Chem Commun. 48(3), 525-531.

20. Khani R., Shemirani F., 2010. Determination of Trace Levels of Nickel and Manganese in Soil, Vegetable and Water. CLEAN – Soil, Air, Water. 38(12), 1177-1183.