The Effects of SiO2 Nanoparticles on Mechanical and Physicochemical Properties of Potato Starch Films
Subject Areas : Journal of Chemical Health RisksZ. Torabi 1 , A. MohammadiNafchi 2
1 - Biopolymer Research Group, Food Science and Technology Division, Agriculture Department, Damghan
Branch, Islamic Azad University, Damghan, Semnan, Iran
2 - Biopolymer Research Group, Food Science and Technology Division, Agriculture Department, Damghan
Branch, Islamic Azad University, Damghan, Semnan, Iran
Keywords: Mechanical Properties, Bionanocomposite, SiO2 nanoparticle, Starch film,
Abstract :
In this paper effect of SiO2 nanoparticles was investigated on potato starch films. Potato starch films were prepared by casting method with addition of nano-silicon dioxide and a mixture of sorbitol/glycerol (weight ratio of 3 to 1) as plasticizers. SiO2 nanoparticles incorporated to the potato starch films at different concentrations 0, 1, 2, 3, and 5% of total solid, and the films were dried under controlled conditions. Â Physicochemical properties such as water absorption capacity (WAC), water vapor permeability (WVP) and mechanical properties of the films were measured. Results show that by increasing the concentration of silicon dioxide nanoparticles, mechanical properties of films can be improved. Also incorporation of silicon dioxide nanoparticles in the structure of biopolymer decrease permeability of the gaseous molecules such as water vapor. In summary, addition of silicon dioxide nanoparticles improves functional properties of potato starch films and these bio Nano composites can be used in food packaging.
- Pavlath A., Orts W., Edible Films and
- Coatings: Why, What, and How? In: Huber KC,
- Embuscado ME, eds. Edible Films and Coatings
- for Food Applications: Springer New York,
- :1.
- Lacroix M., Mechanical and Permeability
- Properties of Edible Films and Coatings for Food
- and Pharmaceutical Applications. In: Huber KC,
- Embuscado ME, eds. Edible Films and Coatings
- for Food Applications: Springer New York;
- :347.
- Mohammadi Nafchi A., Moradpour M.,
- Saeidi M., Alias A.K., Thermoplastic starches:
- Properties, challenges, and prospects. Starch âââ
- Stärke, 2013. 65(1-2):61. doi:
- 1002/star.201200201.
- Li J. H., Hong R. Y., Li M. Y., Li H. Z.,
- Zheng Y., Ding J., Effects of ZnO nanoparticles on
- the mechanical and antibacterial properties of
- polyurethane coatings. Progress in Organic
- Coatings. 3// 2009. 64(4):504. doi:
- http://dx.doi.org/10.1016/j.porgcoat.2008.08.013.
- Simo R., Cordenunsi B., Characterization
- of starch granules. Starches. Vol null: CRC Press,
- Ellis R. P., Cochrane M. P., Dale M. F.
- B., Duffus C. M., Lynn A., Morrison I. M., Starch
- production and industrial use. Journal of the
- Science of Food and Agriculture, 1998. 77(3):289.
- doi: 10.1002/(SICI)1097-
- (199807)77:3<289::AID-JSFA38>3.0.CO;2-
- D.
- Zou D., Yoshida H., Size effect of silica
- nanoparticles on thermal decomposition of
- PMMA. Journal of Thermal Analysis and
- Calorimetry. 2010. 99(1):21. doi: 10.1007/s10973-
- -0531-4.
- Myllärinen P., Buleon A., Lahtinen R.,
- Forssell P., The crystallinity of amylose and
- amylopectin films. Carbohydrate Polymers, 4/1/
- 48(1):41. doi:
- http://dx.doi.org/10.1016/S0144-8617(01)00208-9.
- Abdorreza M. N., Cheng L. H., Karim A.
- A., Effects of plasticizers on thermal properties
- and heat sealability of sago starch films. Food
- Hydrocolloids. 2011, 25(1):56. doi: DOI:
- 1016/j.foodhyd.2010.05.005.
- ASTM. Standard Test Method for
- Tensile Properties of Thin Plastic Sheeting D882âââ
- Annual book of ASTM standards.
- Philadelphia, PA2010.
- Maizura M., Fazilah A., Norziah M.,
- Karim A., Antibacterial Activity and Mechanical
- Properties of Partially Hydrolyzed Sago Starchâââ
- Alginate Edible Film Containing Lemongrass Oil.
- Journal of Food Science, 2007. 72(6):C324. doi:
- 1111/j.1750-3841.2007.00427.x.
- Laohakunjit N., Noomhorm A., Effect of
- plasticizers on mechanical and barrier properties of
- rice starch film. Starch/Staerke, 2004. 56(8):348.
- McHugh T. H., Avena-Bustillos R.,
- Krochta J., Hydrophilic Edible Films: Modified
- Procedure for Water Vapor Permeability and
- Explanation of Thickness Effects. Journal of Food
- Science, 1993. 58(4):899. doi: 10.1111/j.1365-
- 1993.tb09387.x.
- ASTM. Standard Test Methods for Water
- Vapor Transmission of Materials E96/E96M-05.
- Annual Book of ASTM Standards. Philadelphia,
- PA, 2005.
- Kiatkamjornwong S., Chomsaksakul W.,
- Sonsuk M., Radiation modification of water
- absorption of cassava starch by acrylic
- acid/acrylamide. Radiation Physics and Chemistry,
- 59(4):413. doi: 10.1016/s0969-
- x(00)00297-8.
- Wu M., Wang M., Ge M., Investigation
- into the performance and mechanism of SiO2
- nanoparticles and starch composite films. Journal
- of the Textile Institute, 2009. 100(3):254
- Nafchi A. M., Nassiri R., Sheibani S.,
- Ariffin F., Karim A. A., Preparation and
- characterization of bionanocomposite films filled
- with nanorod-rich zinc oxide. Carbohydrate
- Polymers. 7/1/ 2013. 96(1):233. doi:
- http://dx.doi.org/10.1016/j.carbpol.2013.03.055.
- Schlemmer D., Angélica R. S., Sales M.
- J. A., Morphological and thermomechanical
- characterization of thermoplastic
- starch/montmorillonite nanocomposites.
- Composite Structures. 2010. 92(9):2066.
- Godbillot L., Dole P., Joly C., Rogé B.,
- Mathlouthi M., Analysis of water binding in
- starch plasticized films. Food Chemistry, 2006.
- (3):380. doi: DOI: 10.1016/j.foodchem, 2005.
- 054.
- Lourdin D., Coignard L., Bizot H.,
- Colonna P., Influence of equilibrium relative
- humidity and plasticizer concentration on the
- water content and glass transition of starch
- materials. Polymer, 1997. 38(21):5401.
- Bajpai S. K., Chand N., Chaurasia V.,
- Investigation of water vapor permeability and
- antimicrobial property of zinc oxide nanoparticlesloaded
- chitosan-based edible film. Journal of
- Applied Polymer Science, 2010. 115(2):674. doi:
- 1002/app.30550.
- Wu M., Wang Y., Wang M., Ge M.,
- Effect of SiO2 Nanoparticles on the Wear
- Resistance of Starch Films. Fiber and textiles in
- Eastern Europe, 2008. 16(4):96.
- Voon H., Bhat R., Easa A., Liong M. T.,
- Karim A. A., Effect of Addition of Halloysite
- Nanoclay and SiO2 Nanoparticles on Barrier and
- Mechanical Properties of Bovine Gelatin Films.
- Food Bioprocess Technol, 2012/07/01
- ;5(5):1766. doi: 10.1007/s11947-010-0461-y.
- Xia X., Hu Z., Marquez M. Physically
- bonded nanoparticle networks: a novel drug
- delivery system. Journal of Controlled Release,
- 103(1):21. doi: DOI:
- 1016/j.jconrel.2004.11.016.
- Tunç S., Duman O., Preparation and
- characterization of biodegradable methyl
- cellulose/montmorillonite nanocomposite films.
- Applied Clay Science, 2010. 48(3):414. doi:
- 1016/j.clay.2010.01.016.
- Müller C. M. O., Laurindo J. B.,
- Yamashita F., Effect of nanoclay incorporation
- method on mechanical and water vapor barrier
- properties of starch-based films. Industrial Crops
- and Products, 2011. 33(3):605. doi:
- 1016/j.indcrop.2010.12.021.