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  • List of Articles


      • Open Access Article

        1 - Brønsted Acidic Ionic Liquid: An Efficient and Reusable Catalyst for the Multi-Component Synthesis of Dihydropyrimidinones under Solvent-Free Conditions
        Heshmatollah Alinezhad Neda Ghobadi
        An efficient and convenient procedure for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones and thiones by condensation of 1,3-dicarbonyl compounds, Aromatic and aliphatic aldehydes, and urea or thiourea in the presence of catalytic amount of Brønsted acidic ionic More
        An efficient and convenient procedure for the synthesis of 3,4-dihydropyrimidin-2(1H)-ones and thiones by condensation of 1,3-dicarbonyl compounds, Aromatic and aliphatic aldehydes, and urea or thiourea in the presence of catalytic amount of Brønsted acidic ionic liquid 3-methyl-1-sulfonic acid imidazolium chloride {[Msim]Cl} under thermal solvent-free conditions reacted easily to afford the corresponding 3,4-dihydropyrimidin-2(1H)-ones and thiones. Straightforward and clean workup, short reaction time, good to excellent yields and reusability of the catalyst are the advantages of this method. Manuscript profile
      • Open Access Article

        2 - Removal of hazardous heterocyclic dyes from aqueous solutions with ZnO adsorbent
        Nima Razzaghi-Asl Parya Nasehi
        In this study , Copper oxide as a good and inexpensive adsorbent has been introduced and used for the removal of erythrosine and red carmoisine dyes from several water solutions successfully. The effect of various parameters such as pH, dye concentration, amount of adso More
        In this study , Copper oxide as a good and inexpensive adsorbent has been introduced and used for the removal of erythrosine and red carmoisine dyes from several water solutions successfully. The effect of various parameters such as pH, dye concentration, amount of adsorbent, contact time and temperature on removal processing was investigated. Adsorption isothermal data could be interpreted by the Langmuir and Freundlich, isotherm models. Manuscript profile
      • Open Access Article

        3 - Calcium Chloride catalyzed Intramolecular Oxa Michael addition of 2’-Hydroxychalcone to Flavanone
        Pramod Kulkarni
        An efficient cyclization of 2’-hydroxychalcone to flavanone using calcium chloride as a catalyst was developed. The scope of the reaction was studied with substituted 2’-hydroxychalcone and these chalcones was converted into corresponding flavanone in good y More
        An efficient cyclization of 2’-hydroxychalcone to flavanone using calcium chloride as a catalyst was developed. The scope of the reaction was studied with substituted 2’-hydroxychalcone and these chalcones was converted into corresponding flavanone in good yield. The merits of this method are inexpensive and easily available catalyst, easy workup procedure, avoid use of toxic solvent Manuscript profile
      • Open Access Article

        4 - TiO2 nanoparticles/melamine Tri sulfonic acid for biginelli syntheis under solvent-free conditions
        Mohammad Kazem Mohammadi
        TiO2 nanoparticles/melamine Tri sulfonic acid (MTSA) supported on silica gel as an efficient catalytic system for simple, one pot, solvent-free and environmentally benign process for synthesis of dihydropyrimidines via Biginelli reaction at 110 °C is described. It w More
        TiO2 nanoparticles/melamine Tri sulfonic acid (MTSA) supported on silica gel as an efficient catalytic system for simple, one pot, solvent-free and environmentally benign process for synthesis of dihydropyrimidines via Biginelli reaction at 110 °C is described. It was found that the catalyst is reusable and exhibited remarkable activity. The catalyst can be easily separated and reused several times without appreciable loss of activity. The availability and recoverability of the catalytic system with easy operation and work up make this catalytic system attractive for organic synthesis. Manuscript profile
      • Open Access Article

        5 - SYNTHESIS OF 1,8-DIOXO-OCTAHYDROXANTHENES WITH THIAMINE CHLORIDE IN ECO-FRINDLY AND SOLVENT FREE CONDITION
        Bahram Pourhasan Mohammad Mahmudi Hashemi Ali Ezabadi
        A novel, simple and environmentally friendly method is reported for the preparation of 1,8-dioxo-octahydroxanthene derivatives by the reaction of dimedon with various aromatic aldehydes, using thiamine chloride as a recyclable catalyst under solvent-free conditions. Thi More
        A novel, simple and environmentally friendly method is reported for the preparation of 1,8-dioxo-octahydroxanthene derivatives by the reaction of dimedon with various aromatic aldehydes, using thiamine chloride as a recyclable catalyst under solvent-free conditions. This procedure has following benefits; simple workup, moderate reaction times, good yields, and completely compatible with environment. Manuscript profile
      • Open Access Article

        6 - Chemical Composition of the Essential Oil Salvia Officinal from Shiraz Greenhouse
        Fatemeh Ranjbar Mohammad Mehdi Ghanbari Seyed shahram Mosaheb Mohammad Sadegh Behrooz
        The genus is distributed throughout the Old World and the Americas, with three distinct regions of diversity: Central and shake the limbs and topic in folk medicine. South America (approx. 500 species), Central Asia and Mediterranean (250 species), Eastern Asia (90 spec More
        The genus is distributed throughout the Old World and the Americas, with three distinct regions of diversity: Central and shake the limbs and topic in folk medicine. South America (approx. 500 species), Central Asia and Mediterranean (250 species), Eastern Asia (90 species)various species of the genus salvia are used as Disinfectants, Epileptics Autodigestion, Reduce blood sugar donor, Carminative, Treatment of seizures, Joint pain and dizziness and migraines, Low ering blood sugar Manuscript profile
      • Open Access Article

        7 - A novel sensor based on a heterocyclic ionophore for cerium (III) analysis in real samples
        Arezoo Ghaemi Haman Tavakkoli Fariba Mehranfar
        A new polyvinyl choloride (PVC) membrane sensor for cerium (III) was prepared based on 4,13-didecyl-1,7,10,16-tetraoxa-4,13-diazacyclooctadecane (kryptofix22DD) as an ionophore. The sensor exhibites a linear concentration range of 1.0×10-6 to 1.0×10-1 M, wit More
        A new polyvinyl choloride (PVC) membrane sensor for cerium (III) was prepared based on 4,13-didecyl-1,7,10,16-tetraoxa-4,13-diazacyclooctadecane (kryptofix22DD) as an ionophore. The sensor exhibites a linear concentration range of 1.0×10-6 to 1.0×10-1 M, with a Nernstian slope of 18.0±1.0 mV/decade, and a detection limit of 9.7×10-7 M. It has a fast response time (5 s) and can be used for two months without any considerable divergence in its potential. The proposed sensor revealed high selectivity toward Ce3+ ion with respect to some alkali, alkaline earth and transition metal cations. It could be used in a wide pH range of 2.0-11.0. The sensor was successfully used as an indicator electrode in potentiometric titration of Ce3+ ion with ethylenediaminetetraacetic acid (EDTA) and sodium iodide (NaI) solutions, and in determination of Ce (III) concentration in real samples Manuscript profile