Investigation and Evaluation of the structure, morphology, and reduction of the activity of homo and Copolymer aniline/pyrrole by tripyridyltriazine ligand

Subject Areas :

Nafiseh Hajiabdolah ¹ (Department of Chemical Engineering, Abadan Branch, Islamic Azad University, Abadan, Iran)

Received: 2022-11-14 Accepted : 2023-01-18 Published : 2023-04-01

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Abstract :

In this research, homo and copolymer electrosynthesis of Aniline/Pyrrole changed into performed at the tip of a graphite pencil in phosphoric acid containing KCl as electrolyte support. The ability of electro-synthesized homo and copolymers to reduce Fe3+ turned into compared and evaluated. Fe is a ferromagnetic material that exhibits magnetic properties in the absence of a magnetic field. Fe+3 ions are very pale due to the unauthorized mutation of the electrons, and with the reduction and conversion to Fe+2, there is a permissive electron mutation, which means that the chelates are rapidly attached to the authorized ligands and increase the color Fe (III), as an oxidant, tends towards the antioxidants found in the sample and makes contact with them and turns electrons into Fe (II) and tripyridyltriazine (TPTZ) is an electron binder in which by the electron donor antioxidant. The consequences show that the poly-aniline decreasing assets are better than the copolymer and that the copolymer is higher than the polypyrrole. The FTIR and UV-visible spectra indicated that the aniline ring increase in the polymer chain escalated the reduction. The structure and morphology of the homo and copolymer have been confirmed by SEM and FTIR.