بررسی فعالیت کاتالیستی نانو پوشش اگزالات مس بر روی پارامترهای ترمودینامیکی تجزیه حرارتی آمونیم پرکلرات

محورهای موضوعی : عملیات حرارتی

مرجان تحریری ¹ , محمد مهدوی ² , حسین فرخ پور ³

1 - دانشجو /دانشگاه صنعتی مالک اشتر
2 - استاد / دانشگاه صنعتی مالک اشتر
3 - استاد/دانشگاه صنعتی اصفهان

تاریخ دریافت : 1395/03/05 تاریخ پذیرش : 1396/12/21 تاریخ انتشار : 1396/12/01

کلید واژه: آمونیم پرکلرات, پوشش دهی, اگزالات مس,

چکیده مقاله :

برای بهبود فرایند تجزیه حرارتی آمونیوم پرکلرات (جهت اصلاح و بهبود سرعت سوزش پیشرانه ها)، نانو اگزالات مس بر روی آمونیوم پرکلرات به روش سل- ژل پوشش داده شد. برای بررسی فرایند پوشش دهی اگزالات مس بر روی آمونیوم پرکلرات و تغییرات رفتار تجزیه حرارتی آمونیوم پرکلرات در حضور نانو ذرات اگزالات مس به ترتیب از تصاویر میکروسکوپ الکترونی روبشی (SEM) و آنالیز حرارتی (TG/DSC) استفاده شد. نتایج بدست آمده از آنالیزهای حرارتی نشان داد که، پوشش دادن نانو ذرات اگزالات مس بر روی آمونیوم پرکلرات علاوه بر کاهش دمای تجزیه حرارتی از C º 422 به C º299 ، سبب ادغام پیک های تجزیه آمونیوم پرکلرات(در مقایسه با آمونیوم پرکلرات خالص) شده است. همچنین برای بررسی اثر نانو کاتالیست بر روی پارامترهای سینتیکی و ترمودینامیکی تجزیه حرارتی آمونیم پرکلرات، از روش مستقل از مدل به نام اوزاوا-فلاین-وال (OFW) استفاده شد. ازاینرو، مشاهده شد این نانو کاتالیست سبب کاهش مقادیر انرژی فعالسازی، عامل فاکتور فرکانس و پارامترهای ترمودینامیکی در درجات تبدیل مختلف به ترتیب 2/0، 4/0، 6/0 و 8/0شده است، همچنین موجب کاهش پارامترهای ترمودینامیکی در فرایند تجزیه حرارتی آمونیوم پرکلرات می شود.

چکیده انگلیسی:

To improve the process of thermal decomposition of ammonium perchlorate (for improving and modification propellant burning rate), the copper oxalate was coated by ammonium perchlorate through sol-gel method. Scanning electron microscopy (SEM) and thermal analysis(TG/DSC) were used for coating analysis of the copper oxalate on ammonium perchlorate and behavior changes of thermal decomposition of ammonium perchlorate in the presence of nano copper oxide made of nano copper oxalate respectively. The results of catalytic thermal decomposition of ammonium perchlorate shown that the cover of copper oxalate nanoparticles has a good effect on the thermal decomposition of ammonium perchlorate and the thermal decomposition temperature of ammonium perchlorate reduced from 422 ºC to 299 ºC. In addition, the thermal decomposition peaks of ammonium perchlorate (compared to thermal decomposition of pure ammonium perchlorate) were integrated. In order to evaluation of the effect of nano-catalyst on the thermodynamic and kinetic parameters one of the model-free methods as Ozawa - Flynn - Wall (OFW) equation was used. As result, it was observed that nano-catalyst reduced the activation energy, the frequency factor and thermodynamic parameters in different conversion rates 0.2, 0.4, 0.6 and 0.8, respectively.

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