مروری بر کاربرد نانو جاذبها در سیستمهای تصفیه آب و پساب
محورهای موضوعی :
آب و محیط زیست
سیده هدی رحمتی
1
,
خشایار محمدبیگی
2
,
روح الله باقری
3
,
سید مصطفی ساداتی کیادهی
4
1 - استادیار گروه مهندسی محیط زیست- منابع آب، واحد علوم و تحقیقات، دانشگاه آزاد اسلامی، تهران، ایران
2 - دانشجوی دکتری مهندسی محیط زیست، واحد علوم و تحقیقات، دانشگاه آزاد اسلامی، تهران، ایران
3 - دانشجوی دکتری مهندسی محیط زیست، واحد علوم و تحقیقات، دانشگاه آزاد اسلامی، تهران، ایران
4 - دانشجوی دکتری مهندسی محیط زیست، واحد علوم و تحقیقات، دانشگاه آزاد اسلامی، تهران، ایران
تاریخ دریافت : 1397/10/11
تاریخ پذیرش : 1398/01/27
تاریخ انتشار : 1401/04/01
کلید واژه:
تصفیه,
آب,
پساب,
نانوجاذب,
چکیده مقاله :
زمینه هدف : در دهه اخیر، تحقیقات گسترده‌ای در زمینه کاربرد نانو جذبها در صنایع آب و فاضلاب شده است. بطور کلی این نانو ذرات به نانولوله‌های کربنی، نانوجاذبهای پلیمری، زئولیتها و نانوذرات اکسیدهای فلزی تقسیم می‌شوند. نانوتیوبهای کربنی دارای سطح ویژه فعال بالایی هستند ضمن آنکه استفاده مجدد آسانی دارند. نانو ذرات اکسیدهای فلزی، دارای خاصیت انتخاب پذیری مناسب برای جذب ترکیبات سمی و فلزات سنگین هستند. نانو جاذبهای پلیمری دارای عملکرد دوگانه (پوسته داخلی جذب ترکیبات آلی، شاخه‌های خارجی جذب فلزات سنگین)، قابلیت استفاده مجدد دارند و زئولیتها دارای سطح ویژه و قابلیت جذب بالایی هستند. در این مقاله مروری ضمن بررسی نانو جاذبها، کاربردهای آنها در سیستمهای تصفیه آب و پساب، مورد مطالعه قرار گرفته است.
روش بررسی : اطلاعات و داده های تحقیق مطابق روش مقالات مروری از طریق جستجوی بانکهای مراجع مقاله ها و منابع علمی و پژوهشهای انجام شده در داخل کشور و خارج از ایران در زمینه کاربرد نانو جاذبها در سیستمهای تصفییه آب و فاضلاب، انجام شده است.
یافته ها : نتایج این پژوهش نشان می‌دهد که در ایران، تحقیقات زیادی بر کاربرد نانوجاذبهای اکسیدهای آهن و نانو لوله‌های کربنی شده است ولی در زمینه نانو ذرات نقره که داری خاصیت ضد باکتری بالایی جهت حذف ویروسها، باکتریها و قارچها از آب و پساب هستند، پژوهشهای کمتری انجام شده است.
بحث و نتیجه گیری: با توجه به توسعه و کاربردهای نانوجاذبها در زمینه سیستمهای تصفیه آب و پساب، پیشنهاد می‌شود تا در مراکز پژوهشی و علمی کشور، پژوهشهایی با دیدگاه کاربردی و صنعتی مد نظر قرار گیرد تا امکان بازیابی آب و بهینه سازی سیستم تصفیه میسر شود.
چکیده انگلیسی:
Background and Objective: In recent decade, various researches have been performed on the application of nanoparticles in the water and wastewater industries. In generally, these nanoparticles are divided to carbon nanotubes, metal oxide nanoparticles. Carbon nanotubes have a high active specific surface, while easy reuse. Metal oxide nanoparticles have the proper selectivity for absorbing toxic compounds and heavy metals. Polymeric nanoadsorbents have Bifunctional (inner shell adsorbs organics, outer branches adsorb heavy metals) and reusable. Zeolites have high specific surface and adsorption ability. In this paper has been studied a review of nanoadsorbents and their applications in water and wastewater treatment systems.
Analysis methodology: Research documents and data have been gathered based on review articles methodology by searching the reference data banks of articles and scientific resources and researches conducted inside and outside Iran in the field of nano adsorbents for water and wastewater treatment systems.
Findings: The results of this study shows that there are many research about iron oxide and carbon nanotubes, but less research is done in the field of silver nanoparticles with high antibacterial properties to remove viruses, bacteria and fungi from water and wastewater.
Discussion and Conclusions: Regard to development and applications of nanoabsorbents in the field of water and wastewater treatment systems, it is suggested that researches with an applied and industrial point of view be considered in the research and scientific centers of the country to enable the possibility of water recovery and optimization of the treatment system.
منابع و مأخذ:
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_||_
1- Mohammadi Soleimani, Ebrahim., Shabani Rochi, Zohra., (2013), Water crisis in Iran, Second International Conference on Sustainable Agriculture and Natural Resources, Tehran, Mehr Arvand Institute of Higher Education, Environmental Lovers Promotion Group and Nature Protection Association (In Persian)
2- Elhawi Nazari, Kivan., Ilati Khamene, Jamshid., (2009), Nanomaterials and water treatment: opportunities and challenges, Tehran Water and Wastewater Company - Technical Office and Engineering Services (In Persian)
3- Lu,M., Wang, J., Stoller, , Wang, T., Bao,Y., and Hao1, H., 2016. An Overview of Nanomaterials for Water and Wastewater Treatment Advances in Materials Science and Engineering, 6, (1), pp.1-10.
4- Usmani,M., and etal., 2017. Current Trend in the Application of Nanoparticles for Waste Water Treatment and Purification: A Review, Current Organic Synthesis, 14(1), pp.1-21.
5- Gehrke,I., Geiser,A., and Somborn-Schulz, A.,2015. Innovations in nanotechnology for water treatment”, Nanotechnology, Science and Applications, 1(8), pp.1–17.
6- Qu,X., Alvarez,P., Li,Q., 2013. Applications of nanotechnology in water and wastewater treatment, water research, 47(1), pp.3931-3946.
7- Saidi, Muslim., Bahramifar, Nader., Younisi, Habibullah, Review of surface absorption methods of heavy metals using nanoabsorbents, International Conference on Civil Engineering, Architecture, Urban Management and Environment in the Third Millennium, 2015, Rasht. (In Persian)
8- Ehtshami, Shekoh., Faiz Bakhsh, Ali Reza., Rustai, Ali., Introduction of various methods used to modify the surface of magnetic nanoparticles in stability and removal of pollutants, 4th National Chemistry, Petrochemical and Nano Conference, 2015, Tehran (In Persian)
9- Nobari, Siam., Khodadadi Darban, Ahmed., Methods of production and manufacturing of nanoparticles and their application in water pollution treatment and removal of heavy metals from polluted water, Second International Congress on Earth, Space and Clean Energy with a focus on natural resources management, agriculture and development Bishndar, 1395 Tehran (In Persian)
10- Rahmani, Mehri., Bakhtiari, Fereshte., Dareh Zarashki, Ismail, Nitrate removal by zeolite modified with iron oxide nanoparticles, 4th International Conference on Environmental Planning and Management, 2016, Tehran, Faculty of Environment, University of Tehran
11- Rahimi, Atefeh., Hamzeh, Yahyai., Abdulkhani, Ali., Investigation of airgel nanoparticles with emphasis on its application in water and wastewater treatment, 4th International Conference on Environmental Planning and Management, 2016, Tehran, Faculty of Environment, University of Tehran. (In Persian)
12- Moqtadarshaar, Sajjad., Qurbani, Mohsen., Isazadeh, Hossein., Investigating the effect of time and amount of adsorbent on the separation of lead ions from aqueous solution, 4th Separation Science and Engineering Conference, 2016, Babol, Noshirvani University of Technology, Babol (In Persian) )
13- Bashiri, Elaha., Carbon nanotubes are promising adsorbents in wastewater treatment, 4th Separation Science and Engineering Conference, 2016, Babol, Noshirvani University of Technology, Babol (In Persian)
14- Keshavarz Shahbaz, Mohammad Ali., Separation of heavy metals nickel and cadmium using polystyrene nano adsorbent for water treatment, 4th International Oil, Gas and Petrochemical Conference, 2016, Tehran, Industrial and Mineral Research Center (In Persian)
15- Zahidnia, Maryam, Kazi Tabatabai, Zohra, Removal of BTEX pollutant from aqueous solutions using single-walled carbon nanotubes coated with zinc oxide nanoparticles, Second International Conference on New Research Findings in Chemistry and Engineering Chemistry, 2015, Tehran, International Confederation of Inventors of the World (IFIA), Comprehensive University of Applied Sciences (In Persian)
16- Dadkhodaei, Zahra., Alipour, Vali., Sadeghi, Zahra., Salvati, Hussein. National Crisis Management, Security, Health, Environment and Sustainable Development, (2015) Tehran, Mehr Arvand Institute of Higher Education, Center for Sustainable Development Solutions (In Persian)
17- Khayati, Solmaz., Rezaei, Hasan., Investigation of the removal of heavy metals from water and wastewater by nanotechnology, the third conference and exhibition on the environment and upcoming crises (with a focus on water shortage and urban and industrial pollution), 1395. Tehran, Mah Danesh Atran Engineering Company (In Persian)
18- Masafir, Ehsan., Rezaei, Hassan., Investigation of cadmium absorption by nanoparticles in synthetic wastewater, 4th National Conference of Student Scientific Associations of Agriculture, Natural Resources and Environment, 2015, Karaj, University of Tehran Agriculture and Natural Resources Campus (In Persian)
19- Mokhtari Hosseini, Zohrabigam., Hosseinabadi, Zahra., Shnoai Zare, Tektem., Nitrate removal from aqueous solutions using adsorbents and nanoabsorbents, 8th National Conference and Specialized Exhibition of Environmental Engineering, 1395, Tehran, Anjuman Environmental Engineering of Iran (In Persian)
20- Hashemzadeh, Farzad., Hosni, Amirhossam., Ahmadpanahi, Homayun. Feasibility study of removing lead, zinc and cadmium heavy metals from water environments using multi-walled carbon nanotubes modified with chitosan, 8th National Conference and Specialized Exhibition of Environmental Engineering, 2015, Tehran, Environmental Engineering Society of Iran (In Persian)
21- Daneshvar, Majid., Rauf Hosseini, Seyed Mohammad., Treatment of mineral wastewater from heavy metals using nanomagnetic bio-absorbents, 8th National Conference and Specialized Exhibition of Environmental Engineering, 2015, Tehran, Environmental Engineering Society of Iran (In Persian)
22- Akbari Alawijeh, Mozhgan., Nasiri Sarvi, Mahdi., Ramezani Afarani, Zahra. , the use of montmorillonite nanoclay in absorbing the heavy metal cadmium from aqueous solution, the third international conference on new research achievements in chemistry and chemical engineering, 2015, Tehran, International Confederation of Inventors of the World (In Persian)
23- Naserzadeh, Yusuf; Aria Shireh Baz Tawana and Hossein Safarzadeh, Comparison of iron oxide nanoparticles and aqueous manganese oxide in terms of optimal adsorption amount in removing heavy metals from water and wastewater, 4th International Science and Engineering Conference, 2016, Italy-Rome, Ide Pardaz Directors Institute, Vira Capital (In Persian)
24- Hashemi, Mohsen., Kuroni, Mohammad Ali., Survey of nanotechnology strategies in dealing with environmental pollutants, 4th International Conference on Science and Engineering, (2015), Italy-Rome, Institute of Idea Managers, capital of Vira (In Persian)
25- Azad, Armin., Mousavi. Seyed Farhad., Kerami, Hojjat., Farzin, Saeed. , Suggestion of suitable adsorbent for urban wastewater treatment using AHP method, 6th National Conference on Water Resources Management of Iran, 2015, Kurdistan, University of Kurdistan (In Persian)
26- Shojaei, Siros., Asghari, Ali., Shojaei, Saeed., Asghari, Bahare., Chemical synthesis of zero-iron nanoparticles and purification of colored solutions, the third scientific research congress of development and promotion of agricultural sciences, natural resources and environment of Iran, 2015 , Tehran, Association for the Development and Promotion of Basic Sciences and Techniques (In Persian)
27- Sadeghi, Yasir., Qurbani, Mohsen., Rahimpour, Ahmed., Barah, Radiyeh., Application of magnetic nanoparticles with polymer coating to remove color and pollution from water, the third international conference on recent innovations in chemistry and chemical engineering, 2015 Tehran, Nikan Institute of Higher Education (In Persian)
28- Kazemishariatpanahi, Sadaf., Qadi, Arzoo., Saif Kordi, Ali Akbar., New synthesis of functionalized nano-chitosan for use in wastewater treatment of industrial factories, 3rd International Conference on Recent Innovations in Chemistry and Chemical Engineering, 2015, Tehran, Institute Nikan Higher Education (In Persian)
29- Mahmoudi, Niaz Mohammad., Surface adsorption of textile dyes from wastewater on amine copper ferrite nanoparticles, 2nd Environmental Science, Engineering and Technologies Conference, 2015, Tehran, Faculty of Environment, University of Tehran (In Persian)
30- Mohammadi Shakalgourabi, Massoud., Karamoozian, Mohammad, Seifpanahishaabani, Kiyomarth, Application of Trichoderma harzianium biological nanoabsorbent in removing malachite green pigment, Second Conference of Environmental Sciences, Engineering and Technologies, 2015, Tehran, Faculty of Environment, University of Tehran. in Persian)
31- Mohajer Maqari, Farshid., Karamouzian, Mohammad, Seifpanahishaabani, Kiyomarth, Effluent treatment by Atliabumbasina biological nanoabsorbent, 2nd Conference on Environmental Sciences, Engineering and Technologies, 1395, Tehran, Faculty of Environment, University of Tehran (In Persian)
32- Yousefi Nesab, Mohhaddeh, Qanadzadeh Gilani, Hossein, Investigation of the removal of heavy metal zinc from the water environment using synthesized bio-absorbent, Iran Water and Wastewater Science and Engineering Congress, 2015, Tehran, Iran Water and Wastewater Association (affiliated) To the Commission of Scientific Associations of Iran) - Tehran University - Country Water and Wastewater Engineering Company (In Persian)
33- Rizvani, Parisa, Taghizadeh, Mohammad Mahdi, Application of nanoclay granules to improve some properties of drinking water, First National Conference on Natural Resources and Sustainable Development in Central Zagros 2015, Shahrekord, Shahrekord University (In Persian)
34- Zare, Pegah., Ashjaran, Ali., Removal of cadmium metal with the help of nano microbial cellulose/chitosan from wastewater, National Conference on Nanostructures, Science and Nano Engineering, (2015), Kashan, Islamic Azad University Nano Science and Engineering Research Center Kashan Unit (In Persian)
35- Raees Al-Sadati, Seyedhashem., Hosseini-Bandagharai, Ahmad., Taherian, Akram., Study and review of oxidized nanotube as an absorbent in removing water hardness, Second National Conference on Environmental Health, Health and Sustainable Environment, 2014, Hamedan, Permanent Secretariat Hamaish, Shahid Muftah College (In Persian)
36- Zanganeh Asadabadi, Abolfazl., Zulfiqari, Qasim., Removal of mercury from aqueous solutions using Zn-OCMK-3 carbon nanocavity adsorbent, First International Conference and Third National Conference on Environmental Health, Health and Sustainable Environment, 2014 , Hamedan, Permanent Secretariat of the Conference (In Persian)
37- Aghajani, Mehdi., Daghiki Assal, Maryam., Turkian, Leila., Removal of heavy metal zinc from aqueous solutions using nano-silica gel functionalized with amine group and investigation of optimal absorption conditions, Second National Conference on Water, Man and Earth , 1394, Isfahan, Isfahan Tourism Developers Company (In Persian)
38- Nusrati, Saleh; Mohammad Karamozian and Kiyomarth Seif Panahi Shabani, Investigating the potential of andalusite nano-absorbent in the purification of aqueous disperse dye 60 from aqueous solutions using kinetic and equilibrium studies, the third national conference on environmental and agricultural research of Iran, 2014, Hamedan, Permanent Secretariat of the conference. Shahid Muftah College (In Persian)
39- Ankari, Mehdad., Daghiki Assal, Maryam., Turkian, Leila., Investigating the optimal conditions for the absorption of lead heavy metal from aqueous solutions using a modified nano adsorbent, the third national conference on environmental and agricultural research in Iran, 2014, Hamedan , Permanent Secretariat of the Conference, Shahid Muftah College (In Persian)
40- Mohammadi, Reza., Karamozian, Mohammad., Seifpanahishaabani, Kiyomarth., Treatment of wastewater contaminated with heavy metals with the help of magnetized diatomite mineral nano-absorbent, the first national congress of new engineering design with the approach of sustainable development and environmental protection, 2014. Semnan, Arman Roshan National Foundation (In Persian)
41- Dehghani, Mohammad Hadi; Rostami, Iman., Rostami, Elham., Study and evaluation of the efficiency of nano aluminum oxide in removing fluoride from aqueous solutions and evaluating its toxicity on Daphnia magnesia, the first national conference of new technologies in chemistry and petrochemicals, (2013), Tehran, Hamandishan Charkha Alam Company and industry
42- Hassanzadeh Tabrizi, Seyed Ali., Fabrication of CuO-ZnO-Al2O3 nanocomposite for water treatment applications, 4th National Conference on Nanotechnology from Theory to Application, (2014), Jami Institute of Higher Education, Isfahan.
43- Barari Gangraj, Seyyed Ahmed, Iszadeh, Hossein, Sadeghi, Ibrahim. , preparation of polypyrrole/iron(III) oxide nanocomposite and its application in separating lead from aqueous solution, the first national conference on environmental health, health and the environment of Bishdar, 2014, Hamedan, Hegmatane Environmental Assessors Association, Shahid Muftah College (In Persian)
44- Hassanpour, Mehri, Khazri, Seyed Mostafi, Absorption of arsenic from water by polyacrylamide under acidic conium laterite and aluminum oxide nanoparticles, the first national conference on environmental health, sustainable health and environment, 2014, Hamedan, Association of Environmental Evaluators Hegemonic Life, Shahid Muftah Faculty (In Persian)
45- Falahati, Faezeh, Baghdadi, Majid., Nitrogen and phosphorus removal from dairy waste water by graphene oxide nano adsorbent and its sludge separation by aminated magnetite magnetic nanoparticles, a case study of pasteurized milk factory in Pegah, Tehran, 7th National Conference and Specialized Exhibition of Environmental Engineering, 2014, Tehran, Faculty of Environment, University of Tehran (In Persian)
46- Sajjadi, Soudeh Al-Sadat., Sajjadi, Samaha Al-Sadat., Optimizing zeolites with zinc oxide nanoparticles to remove heavy metals from wastewater, First National Congress of Biology and Natural Sciences of Iran, 2014, Tehran, Center for Sustainable Development, Anjuman Protecting the nature of Iran (In Persian)
47- Mokhedi, Qasim., Moinpour, Farid., Removal of cadmium from aqueous solutions using magnetic nanoparticles coated with activated carbon obtained from date kernels, 4th National Conference on Health, Environment and Sustainable Development, 2013, Bandar Abbas University Azad Islami Bandar Abbas Unit (In Persian)
Yazdanbakhsh, Ahmadreza., Eslami, Akbar., Aghaiani, Ehsan., Fatahzadeh, Massoud., Removal of COD, BOD, Nitrate and Phosphate from urban sewage effluent with Fe3O4 iron oxide nanoparticles, National Conference on Solutions for the Water Crisis in Iran and the Middle East , 2014, Shiraz, Hamaish Nagar Scientific Conference Center (In Persian)
